Abstract: The present invention relates to a polyphosphoric acid calcium magnesium fertilizer prepared by using phosphoric acid and phosphorus tailings as raw materials and a preparation method therefor. The polyphosphoric acid calcium magnesium fertilizer is prepared by using phosphorus tailings and phosphoric acid as raw materials. Based on P2O5, MgO and CaO, in the polyphosphoric acid calcium magnesium fertilizer: total phosphorus is 50-68%, effective phosphorus is 47-66%, total magnesium is 5-18%, effective magnesium is 4-15%, total calcium is 11-20%, effective calcium is 10-18%, and all are expressed in mass percentage. Based on P2O5, the polymerization rate of the polyphosphoric acid calcium magnesium fertilizer is ?50%. The present invention also provides a preparation method for the fertilizer. The phosphorus in the product prepared by the invention has sustained-release properties. The fertilizer is well suited for crops requiring large amounts of calcium and magnesium.

Abstract: The present invention relates to a polyphosphoric acid calcium magnesium fertilizer prepared by using phosphoric acid and phosphorus tailings as raw materials and a preparation method therefor. The polyphosphoric acid calcium magnesium fertilizer is prepared by using phosphorus tailings and phosphoric acid as raw materials. Based on P2O5, MgO and CaO, in the polyphosphoric acid calcium magnesium fertilizer: total phosphorus is 50-68%, effective phosphorus is 47-66%, total magnesium is 5-18%, effective magnesium is 4-15%, total calcium is 11-20%, effective calcium is 10-18%, and all are expressed in mass percentage. Based on P2O5, the polymerization rate of the polyphosphoric acid calcium magnesium fertilizer is ?50%. The present invention also provides a preparation method for the fertilizer. The phosphorus in the product prepared by the invention has sustained-release properties. The fertilizer is well suited for crops requiring large amounts of calcium and magnesium.

Abstract: Provided is a method for producing phosphoric acid and at the same time obtaining alpha-hemihydrate gypsum including: adding a phosphate rock powder and a part of dilute sulfuric acid into an extraction tank, carrying out an extraction reaction on same, separating a clear liquid from the obtained mixed slurry, sending the clear liquid, as a finished product phosphoric acid, into an acid storeroom, and transferring a separated solid, together with the rest mixed slurry, into a crystal transformation tank; and adding sulfuric acid and a crystal transformation agent into the crystal transformation tank, carrying out a crystal transformation reaction for 1.5-7.5 h at 60° C.-130° C., and solid-liquid separating the obtained mixed acid slurry, wherein the solid can be dried into a gypsum powder, or may be not subjected to a drying step and made into gypsum products such as gypsum boards, gypsum building blocks and gypsum members by directly adding water.

Abstract: Provided is a method for producing wet-process phosphoric acid and at the same time obtaining alpha-hemihydrate gypsum as well as high-purity and high-whiteness alpha-hemihydrate gypsum, including: mixing phosphoric acid and phosphate rock powder and performing extraction reaction; adding sulfuric acid solution to continue the reaction so that 30% to 50% of calcium ions are generated into dihydrate gypsum; transferring the dihydrate gypsum to a crystal transformation tank; adding a crystal transformation agent and controlling the crystal transformation conditions to obtain 30% to 50% of normal hemihydrate gypsum; after separation, introducing phosphoric acid extraction solution containing other 30% to 50% of calcium ions in a form of calcium dihydrogen phosphate into decalcification reaction tank; adding sulfuric acid solution diluted by washing liquid and performing decalcification reaction; controlling the crystal transformation conditions and performing crystal transformation reaction to convert the solid

Abstract: Provided is a method for producing wet-process phosphoric acid and at the same time obtaining alpha-hemihydrate gypsum as well as high-purity and high-whiteness alpha-hemihydrate gypsum, including: mixing phosphoric acid and phosphate rock powder and performing extraction reaction; adding sulfuric acid solution to continue the reaction so that 30% to 50% of calcium ions are generated into dihydrate gypsum; transferring the dihydrate gypsum to a crystal transformation tank; adding a crystal transformation agent and controlling the crystal transformation conditions to obtain 30% to 50% of normal hemihydrate gypsum; after separation, introducing phosphoric acid extraction solution containing other 30% to 50% of calcium ions in a form of calcium dihydrogen phosphate into decalcification reaction tank; adding sulfuric acid solution diluted by washing liquid and performing decalcification reaction; controlling the crystal transformation conditions and performing crystal transformation reaction to convert the solid