Patents Assigned to L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes
  • Patent number: 11999678
    Abstract: The invention relates to a process and a plant for producing methanol in which a compressed make-up gas stream which contains at least one carbon oxide and hydrogen is combined with a residual gas to afford a synthesis gas stream and reacted to afford methanol. According to the invention the residual gas stream and the make-up gas stream are combined using a jet pump, wherein the compressed make-up gas stream is supplied to the jet pump as motive medium via its motive media connection at a pressure p1 and the residual gas stream is supplied to the jet pump as suction medium via its suction port at a pressure p3 and wherein the synthesis gas stream is discharged from the jet pump via its pressure port at a pressure p2 and subsequently supplied to the synthesis stage and wherein p1>p2>p3.
    Type: Grant
    Filed: December 13, 2022
    Date of Patent: June 4, 2024
    Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Marc Wagner, Timm Schuhmann, Frank Castillo-Welter, Tobias Oelmann
  • Patent number: 12000541
    Abstract: Plant and method for storing and distributing pressurized liquefied cryogenic fluid, comprising a liquefied gas source and a distribution member, comprising a first fluid inlet connected to the liquefied gas source and a second end intended to be connected to a user of the pressurized liquefied gas supplied by the distribution member, the source comprising a first liquefied gas store configured to store and supply the liquefied gas to the distribution member at a first determined pressure, the source comprising a second liquefied gas store configured to store the liquefied gas at a second determined pressure which is lower than the first pressure, the plant comprising a connecting pipe having a valve assembly connecting the first and second liquefied gas stores, the plant comprising a filling pipe having a valve assembly and having a first end connected to the second liquefied gas store and a second end intended to be connected to a mobile store for supplying liquefied gas to fill the source.
    Type: Grant
    Filed: December 11, 2020
    Date of Patent: June 4, 2024
    Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventor: Jean-Marc Bernhardt
  • Patent number: 11999622
    Abstract: In a process for separating a mixture containing carbon monoxide, hydrogen and carbon dioxide, the mixture cooled in a heat exchanger is contacted by a stream of liquid methanol at a temperature below ?40° C. to produce carbon dioxide enriched methanol and a carbon dioxide depleted gas relative to the cooled mixture, the carbon dioxide depleted gas is cooled in the heat exchanger and is sent to a separation unit to produce a carbon monoxide enriched stream and a hydrogen enriched stream and the streams enriched in carbon monoxide and hydrogen are heated in the heat exchanger by exchanging heat with the mixture.
    Type: Grant
    Filed: January 11, 2021
    Date of Patent: June 4, 2024
    Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Erwan Le Guludec, Antoine Hernandez, Guillaume Teixeira, Benoit Davidian, Matthias Linicus
  • Patent number: 11992804
    Abstract: A single compressor is used to separately compress permeate from cascaded first and second gas separation membrane-based separation units and residue from a fourth gas separation membrane-based separation unit in order to avoid too high a CO2 partial pressure in the compressed permeate. After the permeates from the first and second stages are compressed, the compressed stream is fed to a third gas separation membrane-based separation unit.
    Type: Grant
    Filed: December 31, 2021
    Date of Patent: May 28, 2024
    Assignees: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges Claude, Air Liquide Advanced Technologies U.S. LLC
    Inventors: Sandeep Karode, Paul Terrien, Cyril Defaye
  • Patent number: 11988446
    Abstract: A method and apparatus for producing high-purity nitrogen and low-purity oxygen using three-column rectification are provided, in which: nitrogen and oxygen undergo rectification in different columns, with high-purity nitrogen and low-purity oxygen being separated out of air simultaneously, thereby overcoming the shortcomings of conventional low-purity oxygen production equipment, and also reducing equipment investment, lowering energy consumption, increasing product added value, and realizing a circular economy effect.
    Type: Grant
    Filed: September 8, 2021
    Date of Patent: May 21, 2024
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Alain Briglia, Huali Xie, Yongshun Zhang
  • Publication number: 20240159450
    Abstract: Refrigeration system comprising: a first cryogenic chamber defined by at least a first wall, the first cryogenic chamber being thermally connected to at least a first cold source; a second cryogenic chamber defined by at least a second wall which extends at least partially facing the first wall, the second chamber being contained inside the first chamber and thermally connected to at least a second cold source; wherein the refrigeration system comprises at least a first door made in the first wall substantially facing a second door made in the second wall, the first door and the second door being arranged in such a way that the opening of the first door allows the opening of the second door.
    Type: Application
    Filed: March 7, 2022
    Publication date: May 16, 2024
    Applicant: L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE
    Inventors: Luc GAFFET, Olivier GUIA
  • Patent number: 11982407
    Abstract: A cryogen storage vessel at an installation is filled with liquid cryogen from a liquid cryogen storage tank that has a pressure lower than that of the vessel. After headspaces of the vessel and tank are placed in fluid communication with another via a gas transfer vessel and are pressure-balanced, a pump in a liquid transfer line connected between the tank and the vessel is operated to transfer amounts of liquid cryogen from the tank to the vessel via the liquid transfer line and pump as amounts of gaseous cryogen are transferred, through displacement by the pumped cryogenic liquid, from the vessel to the tank.
    Type: Grant
    Filed: November 22, 2022
    Date of Patent: May 14, 2024
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Joshua Light, Jerry Hayes, Laurent Allidieres, Thomas Fayer, Cyril Benistand-Hector
  • Patent number: 11983001
    Abstract: A method for operating a water treatment plant, wherein the plant is equipped with an apparatus for injecting a gas containing oxygen into an effluent, the method comprising a phase of detecting anomalies in the operation of the apparatus, wherein the phase of detecting anomalies comprises an implementation of the following steps: providing data representative of the operating state of the apparatus; and providing a system for acquiring and processing said data.
    Type: Grant
    Filed: February 12, 2020
    Date of Patent: May 14, 2024
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventor: Thomas Bourgeois
  • Patent number: 11976873
    Abstract: A cryogenic cooler includes a cold region, a heat-transfer fluid circuit, the cold region being positioned in the circuit, and an application heat exchanger configured to exchange calories with a device to be cooled. The cooler includes at least one passive non-return valve fluidly connected to the cold region, the heat exchanger having at least one first fluid inlet positioned downstream of the non-return valve in the flow direction of the heat-transfer fluid, the heat-transfer fluid circulating from the end of the cold region.
    Type: Grant
    Filed: June 26, 2020
    Date of Patent: May 7, 2024
    Assignee: L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE
    Inventors: James Butterworth, Clément Chassaing
  • Patent number: 11976879
    Abstract: A combined plant for cryogenic separation and liquefaction of methane and carbon dioxide in a biogas stream, including a mixing means, a compressor, a first exchanger, a distillation column, a second exchanger, a separating means, an expanding means, and a separator vessel. Wherein, the mixing means is configured such that the recycle gas is the overhead vapour stream, and the first exchanger and the expanding means are combined.
    Type: Grant
    Filed: June 9, 2022
    Date of Patent: May 7, 2024
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes
    Inventor: Jorge Ernesto Tovar Ramos
  • Patent number: 11976878
    Abstract: A system and method for cooling an oxygen stream by heat exchange with a warming supply nitrogen stream having of a heat exchanger having at least a Zone A and a Zone B, the system having indirect heat exchange between a gaseous oxygen stream, and a high-pressure liquid nitrogen stream split into at least a first portion which passes through a Zone A, and a second portion which passes through a Zone B during a first phase of operation. And a high-pressure liquid nitrogen stream passing through Zone A, thereby producing a high-pressure nitrogen vapor stream, which passes through an expansion turbine, thereby producing an expansion turbine outlet stream which then passes through Zone B, during a second phase of operation, thereby producing a liquid oxygen stream.
    Type: Grant
    Filed: April 5, 2022
    Date of Patent: May 7, 2024
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Michael A. Turney, Alain Guillard
  • Publication number: 20240138370
    Abstract: The invention relates to a method for rearing animals and in particular poultry or pigs that comprises supplying the animals with drinking water in order to water the animals, injecting oxygen and CO2 into the drinking water, before the drinking water reaches the animals, according to one of the following modes: two injections, one of CO2 and one of oxygen, are carried out simultaneously into the drinking water, or one injection, a mixture of oxygen and CO2, is carried out into the drinking water.
    Type: Application
    Filed: January 17, 2022
    Publication date: May 2, 2024
    Applicants: L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE, AIR LIQUIDE FRANCE INDUSTRIE
    Inventors: Dominique IBARRA, Phillippe CAMPO, Franck COUSIN, Pauline LE DRU
  • Patent number: 11964107
    Abstract: The invention concerns a gas delivery system (1, 2) for providing gaseous Nitric Oxide (NO) to a patient comprising a medical ventilator (2) providing a respiratory gas, such as air, to a patient breathing circuit (3) having an inspiratory limb (31) with a flow sensor (100) and an NO injection module (110), and a NO-delivery device (1) for providing a NO-containing gas to the NO injection module (110) of the inspiratory limb (31), said NO delivery device (1) including a control unit (130) and a differential pressure sensor (104). The medical ventilator (2) can be a High Frequency Oscillatory (HFO) ventilator.
    Type: Grant
    Filed: April 2, 2021
    Date of Patent: April 23, 2024
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventor: Thierry Boulanger
  • Patent number: 11965624
    Abstract: Apparatus for compressing cryogenic fluid in at least one compression stage comprising at least one piston and at least one sleeve delimiting at least one compression chamber, a shaft that is able to move in translation along a longitudinal axis (A), the shaft being connected to the piston(s) or sleeve(s) and being able to move with an alternating movement in two opposite directions to ensure phases of compression and intake of fluid into the at least one compression chamber by moving the at least one piston and the at least one sleeve in a relative manner, characterized in that the shaft comprises a portion of reduced cross section in the longitudinal direction (A), said portion of reduced cross section separating two adjacent parts of the shaft, the shaft also comprising at least one linking element made of material that is less thermally conductive than the constituent material of the shaft, in particular a composite material, said at least one linking element having two ends connected respectively to the
    Type: Grant
    Filed: April 23, 2021
    Date of Patent: April 23, 2024
    Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude Et l'Exploitation des Procedes Georges Claude
    Inventors: Guillaume Petitpas, Cyril Benistand-Hector
  • Patent number: 11965694
    Abstract: In a process of the separation of a mixture of carbon monoxide, hydrogen and methane, the mixture is sent to a scrubbing column, a bottom liquid withdrawn at the bottom of the scrubbing column is depleted in hydrogen with respect to the mixture and is sent to a stripping column, a bottom liquid from the stripping column is sent to a separation column and a liquid enriched in methane withdrawn from the bottom of the separation column is vaporized in order to form a final product.
    Type: Grant
    Filed: July 24, 2019
    Date of Patent: April 23, 2024
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Manon Cortale, Bertrand Demolliens, Antoine Hernandez, Guillaume Teixeira
  • Patent number: 11959702
    Abstract: An air separation device can include: a first compressor and a second compressor for compressing feed air; a first refrigerator and a second refrigerator for cooling the feed air; a pre-purification unit for pre-purifying the feed air; a flow rate measuring unit for measuring the flow rate of the feed air; a main heat exchanger for subjecting the feed air to heat exchange; a purification portion into which the feed air led out from the main heat exchanger is fed, and which separates and purifies product nitrogen and/or product oxygen from the feed air; and a compressor control unit for controlling the feed quantity of the feed air in accordance with an increase or decrease in the production quantity of product nitrogen and/or product oxygen.
    Type: Grant
    Filed: March 4, 2021
    Date of Patent: April 16, 2024
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Takuya Kaneda, Tsuyoshi Sugitani
  • Publication number: 20240117285
    Abstract: Raw biogas from an anaerobic digester is fed to a membrane separation unit that produces methane rich biomethane and a CO2 rich permeate that is recycled to the anaerobic digester where it is mixed with the digestate.
    Type: Application
    Filed: October 6, 2022
    Publication date: April 11, 2024
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges Claude
    Inventors: Sudhir KULKARNI, Min Ho MAENG, Shu FANG
  • Publication number: 20240117911
    Abstract: Self-closing emergency release and coupling device for the transport of cryogenic fluid comprising two pipes extending in a longitudinal direction and each comprising, at a connection end, a valve mechanism configured to automatically close the pipe when the connection ends are separated and to open the pipe when the connection ends are coupled, the device further comprising a tube arranged around each pipe and defining a vacuum space for thermally insulating the pipeline, the device is characterized in that it further comprises a chamber disposed around the valve mechanism and delimited by a wall assembly located between the outer tube and the transport pipe, the volume of the insulation chamber being independent of the vacuum space between the outer tube and the transport pipe.
    Type: Application
    Filed: January 17, 2022
    Publication date: April 11, 2024
    Applicant: L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE
    Inventors: Gaetan COLEIRO, Yan PENNEC
  • Publication number: 20240116009
    Abstract: Composite hollow fiber gas separation membranes with improved permeance and separation layer adhesion are manufactured by providing dipping a hollow fiber membrane substrate in a pre-coat layer coating composition followed by drying to thereby provide a pre-coated substrate and dipping the pre-coated substrate in a separation layer coating composition followed by drying to thereby provide the composite hollow fiber gas separation membranes. The pre-coating composition includes a first polymer dissolved in a first solvent and the separation layer composition includes a second polymer dissolved in a second solvent. The first and second polymers are the same or different, each of the first and second polymers is at least 1 wt % soluble in a same third solvent, the first and second solvents are the same or different, the first and third solvents are the same or different, and the second and third solvent are the same or different.
    Type: Application
    Filed: October 10, 2022
    Publication date: April 11, 2024
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Junyi LIU, Sudhir KULKARNI, Raja SWAIDAN, Megha SHARMA
  • Patent number: 11952270
    Abstract: A method and system for purification of helium and CO2 from a stream containing at least Helium, CO2, nitrogen or methane uses a combination of cryogenic, membrane and adsorption technologies.
    Type: Grant
    Filed: October 5, 2021
    Date of Patent: April 9, 2024
    Assignees: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude, Air Liquide Advanced Technologies U.S. LLC
    Inventors: Paul Terrien, Pierre-Philippe Guerif, Vincent Follaca, Alain Guillard, Youssef Tazi