Abstract: An all-wet process for reclaiming the lead content of impure electrode paste or slime from discarded lead batteries and/or lead minerals, in form of high purity lead compound, comprises a) suspending the impure lead containing material in a lead sulphate dissolving aqueous solution of a salt belonging to the group composed of the acetates of sodium, potassium and ammonium; b) adding to the suspension sulphuric acid in an amount sufficient to convert all lead oxides to lead sulphate soluble in the acetate salt solution and slowly adding to the suspension either hydrogen peroxide or a sulphite or bubbling sulphurous anhydride through it, in a measure adapted to reduce any lead dioxide to lead oxide converted eventually to soluble lead sulphate by the sulphuric acid; c) separating a limpid acetate salt solution containing dissolved lead sulphate from a solid phase residue including all undissolved compounds and impurities; d) adding to the separated solution of lead sulphate either carbonate or hydroxide of the
Type:
Application
Filed:
July 30, 2009
Publication date:
July 26, 2012
Applicant:
Millbrook Lead Recycling Technologies Limited
Abstract: Wet process of low environmental impact recovers the lead content of an electrode slime and/or of lead minerals in the valuable form of high purity-lead carbonates that are convertible to highly pure lead oxide by heat treatment in oven at relatively low temperature, perfectly suited for making active electrode pastes of new batteries or other uses.
Type:
Grant
Filed:
January 15, 2008
Date of Patent:
April 3, 2012
Assignee:
Millbrook Lead Recycling Technologies Limited
Abstract: An outstandingly low environmental impact wet process recovers the lead content of an electrode slime and/or of lead minerals in the valuable form of high purity lead oxide or compound convertible to highly pure lead oxide by heat treatment in oven at relatively low temperature, perfectly suited for making active electrode pastes of new batteries or other uses.
Type:
Grant
Filed:
November 3, 2009
Date of Patent:
August 16, 2011
Assignee:
Millbrook Lead Recycling Technologies Limited
Abstract: A process for recovery of the silica present in the separators located between the elements of lead-acid batteries characterized in that it comprises the following operations: a) washing the heavy plastics to remove the lead compounds and other foreign bodies, b) separating the plastics from the washing solution, c) lead recovery and regeneration of the washing solution, d) rinsing of the plastics, e) drying of the plastics, f) separation of the granular plastics from the thin plastics (polyethylene with silica filler, PVC, fabrics) by drawing them up in a flow of air making use of the shape effect, g) separation of the PVC and fabrics from the polyethylene with silica filler through fragmentation, h) pyrolysis of the polyethylene with silica filler, i) cracking of the pyrolysis gases and vapours in order to reduce their molecular weight and render them more suitable for handling and combustion to provide the heat necessary for pyrolysis, j) oxidation of the pyrolysis residue to remove carbonaceous residues a
Type:
Grant
Filed:
February 3, 2005
Date of Patent:
August 10, 2010
Assignee:
Millbrook Lead Recycling Technologies Limited
Abstract: An outstandingly low environmental impact wet process recovers the lead content of an electrode slime and/or of lead minerals in the valuable form of high purity lead oxide or compound convertible to highly pure lead oxide by heat treatment in oven at relatively low temperature, perfectly suited for making active electrode pastes of new batteries or other uses.
Type:
Application
Filed:
November 3, 2009
Publication date:
February 25, 2010
Applicant:
Millbrook Lead Recycling Technologies Limited
Abstract: Wet process of low environmental impact recovers the lead content of an electrode slime and/or of lead minerals in the valuable form of high purity-lead carbonates that are convertible to highly pure lead oxide by heat treatment in oven at relatively low temperature, perfectly suited for making active electrode pastes of new batteries or other uses.
Type:
Application
Filed:
January 15, 2008
Publication date:
February 11, 2010
Applicant:
Millbrook Lead Recycling Technologies Limited