Patents Assigned to Mitsubishi Gas Chemical Company, Inc.
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Publication number: 20240132434Abstract: An object of the present invention is to provide a method for producing 2,4-dialkylbenzaldehyde with excellent conversion rate and yield, and excellent regioselectivity for formylation, by allowing carbon monoxide to react on a starting material containing a specific m-dialkylbenzene in the presence of hydrogen fluoride and boron trifluoride. The method for producing 2,4-dialkylbenzaldehyde according to the present invention comprises a step of allowing carbon monoxide to react on a starting material containing m-dialkylbenzene represented by formula (1) in the presence of hydrogen fluoride and boron trifluoride for formylation at least at a position (a), wherein the starting material is a dialkylbenzene containing more than 90 mol % of m-dialkylbenzene represented by formula (1), and the number of moles of boron trifluoride relative to 1 mole of m-dialkylbenzene represented by formula (1) is 0.7 mol or more and 3.Type: ApplicationFiled: October 16, 2020Publication date: April 25, 2024Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Toru SHISHIMI, Tatsuya UTAMURA, Yutaka MATSUURA, Shinichi NAGAO
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Publication number: 20240132805Abstract: A cleaning composition for semiconductor substrates, containing an alkaline compound (A), a corrosion inhibitor (B), and water, wherein the alkaline compound (A) is at least one selected from the group consisting of a quaternary ammonium hydroxide (A1) and potassium hydroxide (A2), and the corrosion inhibitor (B) is at least one selected from the group consisting of 4-substituted pyrazoles, potassium tris(1-pyrazolyl)borohydride, 2-(4-thiazolyl)benzimidazole, and halogenated-8-hydroxyquinolines.Type: ApplicationFiled: March 4, 2022Publication date: April 25, 2024Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Hiroaki TAKAKUWA, Akinobu HORITA, Takahiro KIKUNAGA
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Publication number: 20240132634Abstract: Provided are a glycidyl (meth)acrylate composition, which includes a phenolic polymerization inhibitor that is unlikely to deteriorate such that the glycidyl (meth)acrylate composition can be stably stored for a long period of time, and a method for suppressing deactivation of a phenolic polymerization inhibitor in a glycidyl (meth)acrylate resin composition. More specifically, provided are: a glycidyl (meth)acrylate composition including a glycidyl (meth)acrylate, a quaternary ammonium salt, a strong acid salt, and a phenolic polymerization inhibitor; and a method for suppressing deactivation of a phenolic polymerization inhibitor in a glycidyl (meth)acrylate composition, the method including adjusting the content of a strong acid salt in the glycidyl (meth)acrylate composition to a certain amount relative to an amount of a quaternary ammonium salt by mole.Type: ApplicationFiled: January 19, 2022Publication date: April 25, 2024Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Michihiro YURI, Kouji SUZUKI, Shu SUZUKI
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Patent number: 11965058Abstract: An oxymethylene-copolymer manufacturing method includes: polymerizing a polymerization raw material containing trioxane and a comonomer in the presence of an acid catalyst in a quantity that is 1.0×10?8 moles to 5.0×10?6 moles with respect to 1 mole of trioxane; adding a hydroxylamine compound represented by general formula (1) (in the formula, R1 and R2 are, independently of each other, a hydrogen atom or an organic group having 1-20 carbon atoms) to a reaction product obtained during the polymerizing of the polymerization raw material at 50-5000 times the quantity of the acid catalyst, in terms of the molar quantity, and mixing the hydroxylamine compound with the reaction product; and subjecting the mixture of the reaction product and the hydroxylamine compound, which is obtained during the adding of the hydroxylamine compound, to an additional melt-kneading.Type: GrantFiled: June 12, 2018Date of Patent: April 23, 2024Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Yuuta Yamamoto, Daisuke Sunaga, Takuya Okada
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Publication number: 20240124648Abstract: According to the present invention, a resin composition can be provided, which comprises a solvent represented by general formula (1) and a polycarbonate resin containing a structural unit (a) represented by general formula (A) (provided that a polycarbonate homopolymer composed only of a structural unit represented by formula (i) is excluded). (In formula (1), Ra represents a hydrogen atom or the like; Rb represents an alkyl group having 1 to 20 carbon atoms which may have a substituent, or the like; Rc to Rf independently represent a hydrogen atom or the like; and n represents an integer of 1 to 10.) (In formula (A), R1 to R8 independently represent a hydrogen atom or the like; and X represents —O— or the like.Type: ApplicationFiled: February 10, 2022Publication date: April 18, 2024Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Toshihito GOTO, Noriyoshi OGAWA
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Publication number: 20240123425Abstract: A carbon dioxide absorbent containing a polyamine compound (A) having an alicyclic hydrocarbon structure, wherein a content of the polyamine compound (A) is 60% by mass or more.Type: ApplicationFiled: December 14, 2021Publication date: April 18, 2024Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Kazuki KOUNO, Yuki KAWASHIMA
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Publication number: 20240124712Abstract: A polycarbonate copolymer which has siloxane constituent units represented by any of formulae (1-1) to (1-4) and prescribed polycarbonate constituent units.Type: ApplicationFiled: November 21, 2023Publication date: April 18, 2024Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Kazuyoshi UERA, Kohei KAMATANI, Keisuke TOMITA, Hisato AKIMOTO
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Patent number: 11960056Abstract: Provided is an optical lens formed by integrally molding a lens part that is an optically effective portion and has a light incidence/emission surface, and a lens edge part that is an optically ineffective portion and has a surface thereof except the light incidence/emission surface. The lens edge part includes a non-transparent region in part or all thereof, the lens part and the lens edge part include a thermoplastic resin, and the non-transparent region in the lens edge part contains a total of 0.1-5 mass % of one or more of a black dye and a black pigment.Type: GrantFiled: December 24, 2019Date of Patent: April 16, 2024Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Atsushi Motegi, Kentaro Ishihara, Katsushi Nishimori, Shinya Ikeda, Noriyuki Kato, Mitsuteru Kondo, Kensuke Oshima, Masahiro Kanda, Shoko Suzuki, Tatsunobu Ogata, Mitsutake Suematsu
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Patent number: 11961971Abstract: Provided is a production method for an all-solid-state battery having a solid electrolyte layer between a positive electrode layer and a negative electrode layer, the production method including: coating or impregnating the positive electrode layer and/or the negative electrode layer with a solid electrolyte solution in which a boron hydride compound serving as the solid electrolyte has been dissolved in a solvent; and removing the solvent from the coated or impregnated solid electrolyte solution and causing the solid electrolyte to precipitate on the positive electrode layer and/or the negative electrode layer.Type: GrantFiled: October 12, 2018Date of Patent: April 16, 2024Assignees: MITSUBISHI GAS CHEMICAL COMPANY, INC., NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGYInventors: Genki Nogami, Masahiro Shimada, Tomohiro Ito, Aki Katori, Keita Noguchi, Naoto Yamashita, Takashi Mukai, Masahiro Yanagida
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Publication number: 20240117277Abstract: Provided is a composition for cleaning semiconductor substrates, having high removal rate of tungsten oxide with high Ti/W etching selectivity. The composition for cleaning semiconductor substrates, comprising an oxidizing agent (A), a fluorine compound (B), a metallic tungsten corrosion inhibiter (C), and a tungsten oxide etching accelerator (D), wherein the addition ratio of the oxidizing agent (A) is from 0.0001 to 10% by mass relative to the total mass of the composition for cleaning semiconductor substrates; the addition ratio of the fluorine compound (B) is from 0.005 to 10% by mass relative to the total mass of the composition for cleaning semiconductor substrates; and the addition ratio of the metallic tungsten corrosion inhibiter (C) is from 0.0001 to 5% by mass relative to the total mass of the composition for cleaning semiconductor substrates.Type: ApplicationFiled: February 4, 2022Publication date: April 11, 2024Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Toshiyuki OIE, Tomoyuki ADANIYA
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Publication number: 20240117234Abstract: A composition for an oil or gas well formation, containing a viscoelastic surfactant; and a modified nanomaterial and a producing method of the composition, and a forming method of the oil or gas well. The modified nanomaterial optionally contains a nanocellulose. The modified nanomaterial optionally has, on its surface, a sulfate group, a sulfite group, a carboxy group, an ethylene oxide chain, an amino group, an ester group, a silane group, a tertiary ammonium group or a mixture thereof.Type: ApplicationFiled: October 7, 2020Publication date: April 11, 2024Applicant: Mitsubishi Gas Chemical Company, Inc.Inventors: Rigoberto C. ADVINCULA, Kunitoshi MIMURA, Daisuke OHNO, Masahiro SHIMADA
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Patent number: 11952460Abstract: A polycarbonate resin having a high refractive index, a low Abbe number and a high moisture and heat resistance is provided. In an embodiment, a polycarbonate resin including a structural unit represented by general formula (1) below is provided.Type: GrantFiled: July 29, 2022Date of Patent: April 9, 2024Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Munenori Shiratake, Kentaro Ishihara, Koji Hirose, Shinya Ikeda, Noriyuki Kato, Mitsuteru Kondo, Shoko Suzuki, Kensuke Oshima, Shuya Nagayama
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Patent number: 11951720Abstract: Provided is a thermoplastic resin laminate suitable for optical applications of transparent substrate materials and protective materials. The thermoplastic resin laminate includes a first layer including an amorphous polyester resin (A) as the main component, and a second layer including a (meth)acrylic resin (B) as the main component on the first layer.Type: GrantFiled: October 21, 2019Date of Patent: April 9, 2024Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Ken Taguwa, Nobuyuki Koike
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Patent number: 11945906Abstract: Provided are an epoxy resin curing agent containing an amine composition or a modified product thereof, wherein the amine composition contains bis(aminomethyl)cyclohexane (A), a compound (B) represented by the specific formula (1), and a compound (C) represented by the specific formula (2), and wherein a mass ratio of the component (B) to the component (C) [(B)/(C)] is from 0.01 to 5.0, an epoxy resin composition, and use of an amine composition for an epoxy resin curing agent.Type: GrantFiled: August 19, 2021Date of Patent: April 2, 2024Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Kousuke Ikeuchi, Kazuki Kouno, Yuma Ohno, Emi Ota, Aoi Yokoo
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Patent number: 11945791Abstract: The present invention makes it possible to provide a compound represented by formula (1) and a composition for an optical material containing this compound. (Where m+n=4, m represents an integer of from 0 to 3, and n represents an integer of from 1 to 4.) In addition, the present invention makes it possible to provide a method for producing an optical material, the method including a step for adding 0.0001-10 parts by mass of a polymerization catalyst per 100 parts by mass of the composition for an optical material, polymerizing, and curing.Type: GrantFiled: August 1, 2019Date of Patent: April 2, 2024Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Kouhei Takemura, Hiroshi Horikoshi
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Publication number: 20240100473Abstract: A carbon dioxide absorbent containing an amine compound (A) having a heterocyclic structure (X) selected from the group consisting of an oxygen-containing heterocyclic structure and a sulfur-containing heterocyclic structure, a content of the amine compound (A) being 65% by mass or more.Type: ApplicationFiled: December 20, 2021Publication date: March 28, 2024Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Kazuki KOUNO, Yuki KAWASHIMA, Ryo ASAI, Tomoaki KIRINO
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Patent number: 11939447Abstract: A thermosetting composition including a thermosetting compound and hexagonal boron nitride D, wherein the thermosetting compound contains a cyanate compound A and/or a maleimide compound B, and a modified polyphenylene ether C having a substituent with a carbon-carbon unsaturated double bond at at least one terminal, and a content of the hexagonal boron nitride D is 0.1 parts by mass or more and 25 parts by mass or less based on 100 parts by mass of the thermosetting compound.Type: GrantFiled: April 2, 2019Date of Patent: March 26, 2024Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Yoshihiro Nakazumi, Kentaro Takano
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Patent number: 11938676Abstract: Provided is a molding technique with which a molding operation is performed smoothly, preventing the production of defective products. Also provided is a molding apparatus including a nozzle, a guide member guiding a molding material to the nozzle, and a heating device, the molding apparatus being further provided with a prevention structure configured to prevent the molding material from melting during transportation through the guide member.Type: GrantFiled: August 15, 2019Date of Patent: March 26, 2024Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Nobuki Hirooka, Masao Yamawaki
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Patent number: 11939420Abstract: Provided are an epoxy resin curing agent containing an amine composition or a modified product thereof, wherein the amine composition contains bis(aminomethyl)cyclohexane (A) and a compound (B) represented by the following formula (1), and wherein the content of the component (B) based on 100 parts by mass of the component (A) is from 1.5 to 20.0 parts by mass, an epoxy resin composition, and an epoxy resin curing agent for an amine composition. In the formula (1), R1 is an alkyl group having 1 to 6 carbon atoms optionally having a hydroxy group, R2NHCH2—, where R2 represents an alkyl group having 1 to 6 carbon atoms, or a group represented by the following formula (1A), and p is a number of 0 to 2. In the formula (1A), R3 represents a hydrogen atom or NH2—.Type: GrantFiled: August 19, 2021Date of Patent: March 26, 2024Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Yuma Ohno, Kazuki Kouno, Kousuke Ikeuchi, Emi Ota, Aoi Yokoo
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Publication number: 20240092975Abstract: A bisimide phenyl ester acid dianhydride represented by the following formula (2): where R3 and R4 each independently represents a hydrogen atom or an organic group having 1 to 10 carbon atoms; each m is independently an integer of 1 to 4; and each A independently represents an aromatic ring or an alicyclic ring.Type: ApplicationFiled: November 8, 2023Publication date: March 21, 2024Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Tatsuya HIKICHI, Daiki WAKAHARA, Nobuyoshi OHNISHI