Patents Assigned to Mitsubishi Kasei Corporation
  • Patent number: 5399203
    Abstract: Disclosed herein are a method of cleaning an oil-deposited material, which comprises cleaning a material having oils deposited on the surface thereof with a cleaning agent comprising 25 to 90% by weight of at least one of compounds selected from the group consisting of pyrrolidones, .gamma.-butyrolactone and N,N-dimethylacetamide, and 10 to 75% by weight of water, then eliminating at least a portion of the deposited cleaning agent from said material to be cleaned by a physical means, and then applying water-washing with water, steam or water and steam; an apparatus for cleaning an oil-deposited materialhaving oils deposited on the surface thereof; and a cleaning agent therefor.
    Type: Grant
    Filed: April 15, 1993
    Date of Patent: March 21, 1995
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Makoto Ishikawa, Tetsuhiro Yamauchi, Kazunari Takahashi, Soichi Orita, Tetsuo Asanuma, Noboru Ueki, Masayuki Hattori, Satoshi Yamazaki
  • Patent number: 5397439
    Abstract: A method for recovering 1,4-butanediol from a hydrolysate obtained by hydrolyzing diacetoxybutane, by (1) supplying the hydrolysate to a first distillation column, distilling off substantially all the amounts of water and acetic acid as the top stream from the first distillation column, and supplying a bottom liquid to a second distillation column, (2) distilling off diacetoxybutane and hydroxyacetoxybutane as the top or upper side stream from of the second distillation column, and circulating the distillates to a hydrolysis zone, while withdrawing crude 1,4-butanediol as a lower side stream in vapor phase from the second distillation column, (3) supplying the crude 1,4-butanediol and hydrogen gas to a hydrogenation reaction zone packed with a hydrogenation catalyst, and (4) supplying the hydrogenation reaction product to a third distillation column, distilling off low boiling point components and withdrawing 1,4-butanediol as the bottom or side stream from the third distillation column.
    Type: Grant
    Filed: December 9, 1993
    Date of Patent: March 14, 1995
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Hiroaki Kandori, Ken Siraga
  • Patent number: 5397785
    Abstract: A novel 4-acylaminopyridine derivative represented by the following formula (I) is disclosed. ##STR1## The 4-acylaminopyridine derivative of the present invention is useful as a medicine for treating disturbances of memory such as senile dementia and Alzheimer's disease, since it has an action of directly activating malfunctioned cholinergic neuron.
    Type: Grant
    Filed: September 2, 1993
    Date of Patent: March 14, 1995
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Kunihiro Ninomiya, deceased, Ken-ichi Sato, Mamoru Sugano, Akihiro Tobe, Yasuhiro Morinaka, Tomoko Bessho, Haruko Harada
  • Patent number: 5395958
    Abstract: The cyclopropene derivatives of the present invention are useful as the intermediates for producing cyclopropenone derivatives exhibiting strong inhibition activity of thiol protease such as calpain, papain, cathepsin B, cathepsin H, cathepsin L and the like.
    Type: Grant
    Filed: September 27, 1993
    Date of Patent: March 7, 1995
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Ryoichi Ando, Yasuhiro Morinaka, Eiichi Nakamura
  • Patent number: 5393866
    Abstract: A method for the production of polytetramethylene ether glycol wherein polymerization of tetrahydrofuran in the presence of fluorosulfonic acid is followed by hydrolysis of the resulting polymer, characterized by(1) using the fluorosulfonic acid at 0.007-0.3 molar equivalents with respect to the tetrahydrofuran;(2) using in combination therewith fuming sulfuric acid which contains free sulfur trioxide at 0.05-1.0 molar equivalent with respect to the fluorosulfonic acid; and(3) adding said fuming sulfuric acid to the tetrahydrofuran prior to adding the fluorosulfonic acid thereto.According to the method, high quality polytetramethylene ether glycol with a low fluorine content may be obtained at a high yield without lowering the polymerization temperature. For example, PTMG may be obtained with 3 or fewer, and preferably 2 or fewer terminal fluorines per 2,000 termini of the resulting PTMG.
    Type: Grant
    Filed: November 10, 1993
    Date of Patent: February 28, 1995
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Nobuyuki Murai, Masayuki Shirato, Hiroshi Takeo, Hidetoshi Tanaka
  • Patent number: 5391549
    Abstract: A novel cinnoline derivative having an antagonistic activity against serotonin 5-HT.sub.3 receptor, its pharmaceutically acceptable salts, its N-oxide derivatives or solvates thereof, and pharmaceutical formulations containing the same for the prevention and/or treatment of various disorders such as nausea and/or emesis caused by anticancer drugs or X-ray treatment, central nervous disorders such as anxiety and/or neuropathy, gastroenteric diseases such as indigestion, chronic gastritis, digestive ulcer, irritable bowel syndromes and the like, hemicrania, cluster headache, trigeminal neuralgia, arrhythmia and the like.
    Type: Grant
    Filed: March 10, 1993
    Date of Patent: February 21, 1995
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Akira Maruyama, Shigeru Ogawa, Satoshi Yamazaki, Akihiro Tobe
  • Patent number: 5391776
    Abstract: Asteroid derivative of the general formula: ##STR1## wherein X--O-- represents a residue of steroid compound and --A-- represents --CO[NH(CHR.sup.1).sub.y --(Y).sub.p --CO].sub.m NH--, --CO--(R.sup.2).sub.x --(Z).sub.q --CO--NH--, or --CO--(CH.sub.2).sub.n --. A therapeutic agent to osteopathy comprising the above steroid derivative is also provided.
    Type: Grant
    Filed: February 10, 1993
    Date of Patent: February 21, 1995
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Hiroaki Ueno, Syuichiro Kadowaki, Akihito Kamizono, Masahiko Morioka, Akihisa Mori
  • Patent number: 5391801
    Abstract: A hydroformylation process for preparing a hydroformylated product by reacting an olefinic compound with hydrogen and carbon monoxide in the presence of a Group VIII metal catalyst, in the reaction of which there is present a phosphite compound having the formula (I), ##STR1## wherein R.sup.1 and R.sup.2 are respectively an aromatic hydrocarbon groups which may be the same or different and the aromatic hydrocarbon group has at least a hydrocarbon group on a carbon atom adjacent to a carbon atom bonded with an oxygen atom as a substituent; A.sup.1 is an n-valent organic group having an aliphatic hydrocarbon group, a cycloaliphatic hydrocarbon group or an aromatic hydrocarbon group bonded with an adjacent oxygen atom, which may respectively have a substituent; n is an integer of from 2 to 4; and the respective [--O--P(OR.sup.1)(OR.sup.2)] group may be the same or different.
    Type: Grant
    Filed: April 16, 1993
    Date of Patent: February 21, 1995
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Keiichi Sato, Yuji Kawaragi, Masaki Takai, Tooru Ookoshi
  • Patent number: 5389419
    Abstract: An optical recording medium comprising a substrate and a recording layer formed thereon for information to be written in and/or to be read out, wherein said dye-incorporated composition comprising a cyanine type dye and an azo metal chelate compound comprising an azo type compound of the following formula (I) ##STR1## (wherein A is a residue forming a hetoro ring together with the carbon atom and the nitrogen atom to which it is bonded, B is a residue forming an aromatic ring or a hetoro ring together with the two carbon atoms to which it is bonded, and X is a group having an active hydrogen), and a metal.
    Type: Grant
    Filed: March 22, 1994
    Date of Patent: February 14, 1995
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Shuichi Maeda, Satoru Imamura, Kazuo Mitsuhashi, Takako Tsukahara
  • Patent number: 5389481
    Abstract: An electrophotographic photoreceptor comprising an electrically conductive substrate and a photosensitive layer formed thereon, wherein said photosensitive layer contains an arylamine compound of the following formula (I): ##STR1## wherein X is a hydrogen atom or a group of the formula (II): ##STR2## Y is a group of the formula (III) or (IV):--O--A.sup.1 --O-- (III)--A.sup.2 --O--A.sup.3 -- (IV)wherein, the substituents are defined hereafter.
    Type: Grant
    Filed: April 11, 1994
    Date of Patent: February 14, 1995
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Atsuo Saita, Shuichi Maeda, Kohzo Ishio, Hitoshi Ono, Tetsuo Murayama
  • Patent number: 5389203
    Abstract: Disclosed herein is a paper-making additive.comprising a specified cationic polymer having an amidine structure. The cationic polymer additive for paper-making according to the present invention has 20 to 90% by mole of units represented by the formula (1) and/or (2): ##STR1## wherein R.sup.1 and R.sup.2 independently denote a hydrogen atom or a methyl group, and X- denotes an anion; and has a reduced viscosity of 0.1 to 10 dl/g as measured in a 1N saline solution of 0.1 g/dl at 25.degree. C. The additives are excellent in improving paper or pulp properties, such as freeness, filler retention and paper strength.
    Type: Grant
    Filed: September 1, 1993
    Date of Patent: February 14, 1995
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Shigeru Sawayama, Kohichi Satoh, Shin-ichi Sato, Toshiaki Sakakihara
  • Patent number: 5389480
    Abstract: An electrophotographic photoreceptor comprising an electrically conductive substrate and a photosensitive layer formed thereon, wherein the photosensitive layer contains at least one member selected from the group consisting of compounds of the formula (I), (II), and (III) as defined in the specification.
    Type: Grant
    Filed: November 19, 1993
    Date of Patent: February 14, 1995
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Hitoshi Ono, Atsuo Saita
  • Patent number: 5390217
    Abstract: A carbon fiber-reinforced carbon composite material, wherein carbon fibers are oriented substantially in the thickness direction, the ratio of the thermal conductivity in the thickness direction to the thermal conductivity in a direction perpendicular to the thickness direction is at least 2, and the thermal conductivity in the thickness direction is at least 3 W/cm.multidot..degree.C.
    Type: Grant
    Filed: April 24, 1992
    Date of Patent: February 14, 1995
    Assignees: Mitsubishi Jukogyo Kabushiki Kaisha, Mitsubishi Genshiryoku Kogyo Kabushiki Kaisha, Mitsubishi Kasei Corporation
    Inventors: Kimihiro Ioki, Kohei Okuyama, Kazuo Niwa, Hitoshi Seki, Takanori Takahashi
  • Patent number: 5387609
    Abstract: According to the present invention, there is provided an anti-solid tumor agent comprising a cembrane-type compound represented by the general formula (I) or (II): ##STR1## wherein R is a hydrogen atom or an acyl group, as an effective ingredient.
    Type: Grant
    Filed: March 9, 1992
    Date of Patent: February 7, 1995
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Yoshiharu Morita, Koichiro Hirayama
  • Patent number: 5385917
    Abstract: Carboxylic acid derivatives of the formula: ##STR1## are provided, which are useful for treatment of androgen dependent diseases.
    Type: Grant
    Filed: July 16, 1993
    Date of Patent: January 31, 1995
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Hiroaki Ueno, Masahiko Morioka, Fumiko Hatanaka
  • Patent number: 5385799
    Abstract: A toner for development of electrostatic images containing one or more compounds of formulae (I) and (II): ##STR1## where A and R each represent an aromatic ring residue, and the hydroxyl group and the amido group in the formula are bonded to the aromatic ring A at the adjacent positions, ##STR2## where A.sup.1, A.sup.2, R.sup.1 and R.sup.2 each represent an aromatic ring residue, and the hydroxyl group and the amido group in the formula are bonded to the aromatic ring A.sup.1 or A.sup.2 at the adjacent positions; and n represents an integer. The toner is highly safe and has sufficient charge properties and charge stability.
    Type: Grant
    Filed: December 21, 1992
    Date of Patent: January 31, 1995
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Hitoshi Ono, Osamu Ando, Masako Takeuchi
  • Patent number: 5382733
    Abstract: Disclosed herein is a process for preparing naphthalene or a derivative thereof, which comprises subjecting a benzene derivative having at least one substituted or non-substituted aliphatic hydrocarbon group and being capable of forming a naphthalene ring to cyclodehydrogenation in the presence of a zirconia catalyst containing chromium in an oxidized state.
    Type: Grant
    Filed: March 19, 1993
    Date of Patent: January 17, 1995
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Masayuki Otake, Akio Nakanishi
  • Patent number: 5380933
    Abstract: A method for producing an unsaturated carboxylic acid, which comprises subjecting an alkane to a vapor phase catalytic oxidation reaction in the presence of a catalyst containing a mixed metal oxide comprising, as essential components, Mo, V, Te, O and X wherein X is at least one element selected from the group consisting of niobium, tantalum, tungsten, titanium, aluminum, zirconium, chromium, manganese, iron, ruthenium, cobalt, rhodium, nickel, palladium, platinum, antimony, bismuth, boron, indium and cerium, wherein the proportions of the respective essential components, based on the total amount of the essential components exclusive of oxygen, satisfy the following formulas:0.25<r.sub.Mo <0.980.003<r.sub.V <0.50.003<r.sub.Te <0.50.003<r.sub.X <0.5wherein r.sub.Mo, r.sub.V, r.sub.Te and r.sub.X are molar fractions of Mo, V, Te and X, respectively, based on the total amount of the essential components exclusive of oxygen.
    Type: Grant
    Filed: January 28, 1994
    Date of Patent: January 10, 1995
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Takashi Ushikubo, Hiroya Nakamura, Yukio Koyasu, Shin Wajiki
  • Patent number: 5378484
    Abstract: A beverage is disclosed which contains an anti-foaming agent comprising, as an effective component, a sucrose fatty acid ester wherein the constituting fatty acid is at least one of a saturated fatty acid having from 12 to 22 carbon atoms and an unsaturated fatty acid having from 12 to 22 carbon atoms, and the average substitution degree is from 4 to 7. A method for forming the beverage is also disclosed.
    Type: Grant
    Filed: April 17, 1992
    Date of Patent: January 3, 1995
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Nobuyuki Suwa, Akio Nishimura, Susumu Miyama, Shinji Katoh
  • Patent number: 5378810
    Abstract: The present invention provides a GTP binding protein containing the following amino acid sequence, with a molecular weight of about 22K dalton and having GTP binding activity which is inhibited by N-ethyl-maleimide and GTP hydrolyzing activity:Thr-Ile-Glu-Asp-Ser-Tyr, and a method for the production of a GTP binding protein, which comprises introducing a DNA fragment containing DNA that encodes the GTP binding protein into a cloning site present at the downstream to a promoter of an expression vector, then introducing the expression vector thus constructed into a host, culturing said host, thereby expressing and accumulating the GTP binding protein and then collecting thereof.
    Type: Grant
    Filed: September 21, 1992
    Date of Patent: January 3, 1995
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Yoshimi Takai, Jun Kondo, Yasushi Matsui, Yutaka Teranishi, Rie Matsui