Abstract: There are disclosed .alpha.-(1-triazolyl)-keto-derivatives of the general formula: ##STR1## in which R is alkyl, alkenyl or phenyl optionally substituted; R" is alkoxycarbonyl, alkylcarbonyl, arylcarbonyl, aminocarbonyl or cyano; R' has the meanings of both R and R".These compounds are endowed with high fungicidal activity.
Type:
Grant
Filed:
February 29, 1988
Date of Patent:
January 16, 1990
Assignee:
Montedison S.p.A.
Inventors:
Mirella Cecere, Franco Gozzo, Antonio Malandra, Luigi Mirenna
Abstract: An edge triggered RS-type flip-flop circuit is disclosed which is capable of changing its state in response to a significant signal transition applied to a currently active input (SET or RESET) and independently of the current state of the other input (RESET or SET). The device can have one or more SET and RESET inputs, as well as Clear and Preset auxiliary inputs, and for the latter inputs the flip-flop circuit will behave as an ordinary RS flip-flop.
Abstract: A register is disclosed in which an applied data signal D or its complement D is used to set or reset an output RS flip-flop under control of an applied load control signal L. The load control signal is applied to a switching circuit which controls application of the data signal D or D to the set or reset input of the output flip-flop such that the data signal is only applied for a time period sufficient to cause a change in state of the output flip-flop.
Abstract: Compounds suitable for being used as lubricants, having general formula:(I) RO--(C.sub.3 F.sub.6 O).sub.m --(CFXO).sub.n --CFX--L, or(II) R"CFXO--(C.sub.3 F.sub.6 O).sub.x (CFXO).sub.y --(C.sub.2 F.sub.4 O).sub.z --CFX--L, whereR=--CF.sub.3, --C.sub.2 F.sub.5, --C.sub.3 F.sub.7X=F, --CF.sub.3R"=F, --CF.sub.3, --C.sub.2 F.sub.5m=an integer from 3 to 100n=a finite integer, or =zero, wherefore m+n ranges from 3 to 100, provided that, if n is finite, m/n ranges from 5 to 20 and R is preferably =CF.sub.3, if n=zero, R is preferably --C.sub.2 F.sub.5 or --C.sub.3 F.sub.7x=a finite integer, or =zeroy, z=finite integers, such that x+y+z ranges from 5 to 200, while (x+z)/y ranges from 5 to 0.5, provided that when x=zero, z/y ranges from 1 to 0.5 and y+z ranges from 5 to 200 n while X is preferably F, and R"=LL=group Y-Z, where:Y=--CH.sub.2 O--, --CH.sub.2 --OCH.sub.2, --CF.sub.2, --CF.sub.
Type:
Grant
Filed:
April 11, 1988
Date of Patent:
December 26, 1989
Assignee:
Montedison S.p.A.
Inventors:
Gerardo Caporiccio, Ezio Strepparola, Mario A. Scarati
Abstract: A process for the chlorination of the benzene rings of tricyclo 8.2.2.2 hexadeca 4,6,10,12,13,15 hexane (or (2,2)-paracyclophane) having the formula (I): ##STR1## by gaseous chlorine, by operating in the presence of at least one metal chloride as a catalyst, and at least one co-catalyst having the formula V:R--OH (V)whereinR=hydrocarbon or alkylcarboxylic radical with linear or branched chain, containing from 1 to 6 carbon atoms is taught.
Type:
Grant
Filed:
September 16, 1988
Date of Patent:
December 12, 1989
Assignee:
Montedison S.p.A.
Inventors:
Raffaele Ungarelli, Maurizio A. Beretta, Loris Sogli
Abstract: Process for the hydrogenation of bis-phenols by reacting bis-phenols with hydrogen in the presence of a catalytic system consisting of palladium supported on activated carbon.
Type:
Grant
Filed:
May 4, 1988
Date of Patent:
December 5, 1989
Assignee:
Montedison S.p.A.
Inventors:
Andrea Gardano, Francesco Casagrande, Marco Foa, Guido Petrini, Riccardo Barisone, Lawrence Chapoy
Abstract: Electronic components are welded or soldered or bonded to a support by arranging said components on the surface of the support and/or in holes piercing the support, in the presence of soldering materials having binding properties, and by then putting the thus-obtained assembly in contact with a perfluoropolyether in the liquid state, said perfluoropolyether having a temperature at least equal to that at which the soldering material develops its binding properties.
Type:
Grant
Filed:
January 26, 1988
Date of Patent:
October 17, 1989
Assignee:
Montedison S.p.A.
Inventors:
Ken W. E. Johns, Stuart Briggs, Luciano Flabbi
Abstract: A method of fighting fungus infections by using compounds having the formula: ##STR1## wherein: R is H, a C.sub.1 -C.sub.4 alkyl, an alkenyl, or an alkynyl radical; n is 1 or 2;A represents a C.sub.1 -C.sub.6 alkylene bridge, an arylene or a heterocyclic bridge;X represents O, S, SO, SO.sub.2 ; andR.sup.1 is selected from the group consisting of C.sub.1 -C.sub.6 alkyl radicals, a phenyl radical, optionally substituted, polyfluoroalkyl radicals containing from 1 to 4 carbon atoms and at least 2 fluorine atoms, polyfluoroalkenyl radicals containing from 2 to 4 carbon atoms and at least 2 fluorine atoms, but excluding compounds having the formula (I) wherein A is an alkylene radical, n is 2, and R.sup.1 is a C.sub.1 -C.sub.6 alkyl radical.
Type:
Grant
Filed:
April 9, 1987
Date of Patent:
October 17, 1989
Assignee:
Montedison S.p.A.
Inventors:
Augusto Menconi, Giovanni Camaggi, Franco Gozzo, Luigi Mirenna, Carlo Garavaglia
Abstract: The present invention relates to copolyethers comprising copolymers of 7,oxa-bicyclo(2,2,1)heptane, and its alkyl-derivatives, with one or more cycloaliphatic ethers, comprising from 2 to 4 carbon atoms in their ring. These copolyethers show an anisotropic behavior in the molten state, and therefore have liquid-crystal properties.
Type:
Grant
Filed:
September 11, 1987
Date of Patent:
October 17, 1989
Assignee:
Montedison S.p.A.
Inventors:
Leonardo Fiore, Giuseppe Motroni, Mauro Maritano
Abstract: A process for the preparation of 2-carboxpyrazine 4-oxides having the formula (I) ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3, which may be the same or different, represent a hydrogen atom or an alkyl group having from 1 to 6 carbon atoms, by oxidation of the corresponding 2-carboxypyrazines. The 2-carboxypyrazines are reacted under stirring with an aqueous solution of H.sub.2 O.sub.2, at a pH ranging between 0.5 and 5, in the presence of a catalyst selected from the group consisting of tungstic acid, a isopolytungstic acid, a heteropolytungstic acid, molybdic acid, an isopolymolybidic acid, a heteropolymolybdic acid, and an alkali metal salt thereof.
Abstract: Fluorinated polyisocyanates particularly suitable for the formulation of coating paints and compositions in the electronics industry, obtained by starting from a perfluoropolyether polyol having a functionality higher than 2 and from a diisocyanate, the resulting derivative having isocyanic functions being further condensed with a polyol in order to obtain a polyisocyanate with a high degree of functionality, and containing from 1.5% to 9% by weight of --NCO groups.
Abstract: Solid components of catalysts for the (co)polymerization of ethylene, or precursors of such components are prepared by treating an (a) emulsion in a perfluoropolyether of a liquid compound of magnesium, of titanium or of another transition metal, or of solutions thereof, possibly using an electron-donor compound, with (b) a reducing and/or halogenating agent capable of forming an insoluble solid product, after which, if such a product is a precursor of the catalytic component, it is treated with a tetravalent-titanium halide, or with a halide of another transition metal.
Abstract: Process for the preparation of (2,2)-paracyclophane or derivatives thereof by the Hofmann elimination of p-methylbenzyl-trimethylammonium hydroxide or derivatives thereof, in an aqueous solution of an alkali metal hydroxide, wherein said elimination is carried out in the presence of a compound of the formula (I):(R).sub.m --A--(X).sub.n (I)wherein A represents an aromatic group, X an electron donor group, R hydrogen or an alkyl group containing from 1 to 4 carbon atoms, n is an integer from 1 to 6, and m is zero or an integer from 1 up to a value such that the sum m+n is equal to the number of substitutable positions in the aromatic group.
Abstract: High-functionality compositions based on fluorinated and silanized polyisocyanates, prepared by reacting a hydroxy-terminated perfluoropolyether having an average molecular weight ranging from 500 to 7000 and a silico-carbinol having an average molecular weight ranging from 500 to 7000, with an organic diisocyanate and a polyol having a functionality of at least 3. Varnishes containing said compositions based on fluorinated and silanized polyisocyanates, having a high functionality.
Type:
Grant
Filed:
July 1, 1987
Date of Patent:
July 25, 1989
Assignee:
Montedison S.p.A.
Inventors:
Franco Federici, Giorgio Pin, Ennio Cozzi, Aldo Trovati
Abstract: Modified polyisocyanates with biuret structure containing terminal urethane groups and having general formula: ##STR1## in which R.sub.1 is an aliphatic, cycloaliphatic or aliphatic-cycloaliphatic radical, simple or substituted, and R.sub.2 can have the same meanings as R.sub.1 or can be the radical R.sub.3 (OC.sub.n H.sub.2n).sub.x --.Process for the preparation of modified polyisocyanates having biuret structure containing terminal urethane groups having general formula (I) consisting in reacting an organic diisocyanate with water or with a compound which splits off water, in the presence of a compatibilizing agent having a hydrogen atom reactive towards the isocyanate group, as it can be determined by Zerewitinoff's method.
Type:
Grant
Filed:
December 16, 1987
Date of Patent:
June 20, 1989
Assignee:
Montedison S.p.A.
Inventors:
Eugenio Bianchin, Giovanni Longo, Gian F. Lunardon
Abstract: Process of photoetching of superficial coatings based on polymeric material comprising the irradiation of the coated surface with localized excimer laser beams having wavelengths equal to or lower than 193 nm.
Abstract: Alpha-alumina consisting essentially of solid, spherical, non-aggregated particles, having a diameter from 0.06 to 2 .mu.m, a polydispersion index below 2.0, a total porosity below 0.3 cc/g, a specific surface area from 0.7 to 80 m.sup.2 /g, and an apparent density of the particles from 3.20 to 3.94 g/cm.sup.3. The alpha-alumina is prepared by a process consisting, in that an alpha-alumina precursor, having a water content from 2 to 33% by weight, at starting temperatures ranging from room temperature to 850.degree. C., and consisting essentially of solid spherical, non-aggregated particles, having a particle diameter from 0.07 to 2.3 .mu.m and a polydispersion index of .ltoreq.2.0, is subjected to a heat-treatment at temperatures ranging from 1130.degree. to 1700.degree. C., said precursor being instantaneously brought from the starting temperature to the treatment temperature, and by carrying out the treatment during times, as generally indicated in the accompanying FIG.
Type:
Grant
Filed:
September 25, 1987
Date of Patent:
April 4, 1989
Assignee:
Montedison S.p.A.
Inventors:
Emiliano M. Ceresa, Antonio Gennaro, Paolo Cortesi
Abstract: Process for the preparation of (2,2)-paracyclophane or derivatives thereof by the Hofmann elimination of p-methylbenzyl-trimethylammonium hydroxide or derivatives thereof, in an aqueous solution of an alkali metal hydroxide, wherein said elimination is carried out in the presence of a compound of the formula (I):Y--A--(X).sub.n (I)wherein A represents an aromatic group, Y an electron donor group, X an electron acceptor group, and n is an integer from 1 to 3.
Type:
Grant
Filed:
June 26, 1987
Date of Patent:
March 28, 1989
Assignee:
Montedison S.p.A.
Inventors:
Giorgio Bornengo, Alessandro Malacrida, Stefano Campolmi, Maurizio A. Beretta
Abstract: There are described compounds exerting an antidotal activity belonging to the classes of the 2-thiazolines-2-substituted and 2-oxazolines-2-substituted, useful in the defense of agrarian cultivations from the toxic action of non-selective herbicides. Utilization and preparation methods thereof are described as well.
Type:
Grant
Filed:
February 4, 1987
Date of Patent:
March 7, 1989
Assignee:
Montedison S.p.A.
Inventors:
Ottorino Palla, Giovanni Camaggi, Franco Gozzo, Augusto Menconi, Ernesto Signorini
Abstract: A process for preparing spheroid particles of oxide compounds, having an average diameter of smaller than 3 microns. An emulsion is prepared of a hydrolyzable liquid oxide compound in a perfluoropolyether, the emulsion is reacted with water, water vapor or with a mixture, in any ratio, of water with a liquid miscible or immiscible with water so as to form an oxide hydrate which is recovered dried and calcined. Oxide compounds include oxides of Ti, Al, Zr, Si or B.
Type:
Grant
Filed:
July 27, 1987
Date of Patent:
February 28, 1989
Assignee:
Montedison S.p.A.
Inventors:
Enrico Albizzati, Emiliano M. Ceresa, Luciano Zaninetta