Abstract: Provided are a black mixed oxide that contains chromium per se of any valency as a main component, and fails to contain cobalt as the main component material, and has a high safety, an excellent color tone and economical efficiency, and a method for producing the same, and various products using the black mixed oxide material. The mixed oxides comprise oxides containing La, Mn and Cu as main components but containing neither Cr nor Co as a main component, wherein the contents of La, Mn and Cu in the mixed oxides satisfy the following ratios, as oxide equivalent amount with respect to 100% by weight of the oxide equivalent amount: the La content as La2O3 being 35-70 wt %; the Mn content as MnO2 being 25-60 wt %; and the Cu content as CuO being 0.5-10 wt %.
Type:
Grant
Filed:
June 7, 2018
Date of Patent:
September 1, 2020
Assignees:
Nakashima Sangyo Co., Ltd., Okuno Chemical Industries Co., Ltd.
Abstract: Provided are a black mixed oxide that contains chromium per se of any valency as a main component, and fails to contain cobalt as the main component material, and has a high safety, an excellent color tone and economical efficiency, and a method for producing the same, and various products using the black mixed oxide material. The mixed oxides comprise oxides containing La, Mn and Cu as main components but containing neither Cr nor Co as a main component, wherein the contents of La, Mn and Cu in the mixed oxides satisfy the following ratios, as oxide equivalent amount with respect to 100% by weight of the oxide equivalent amount: the La content as La2O3 being 35-70 wt %; the Mn content as MnO2 being 25-60 wt %; and the Cu content as CuO being 0.5-10 wt %.
Type:
Application
Filed:
June 7, 2018
Publication date:
April 30, 2020
Applicants:
Nakashima Sangyo Co., Ltd., Okuno Chemical Industries Co., Ltd.
Abstract: A lithium-lanthanum-titanium oxide sintered material has a lithium ion conductivity 3.0×10?4 Scm?1 or more at a measuring temperature of 27° C., the material is described by one of general formulas (1?a)LaxLi2-3xTiO3-aSrTiO3, (1?a)LaxLi2-3xTiO3-aLa0.5K0.5TiO3, LaxLi2-3xTi1-aMaO3-a, Srx-1.5aLaaLi1.5-2xTi0.5Ta0.5O3 (0.55?x?0.59, 0?a?0.2, M=at least one of Fe or Ga), amount of Al contained is 0.35 mass % or less as Al2O3, amount of Si contained is 0.1 mass % or less as SiO2, and average particle diameter is 18 ?m or more.
Type:
Grant
Filed:
April 22, 2013
Date of Patent:
July 18, 2017
Assignees:
TOHO TITANIUM CO., LTD., NAKASHIMA SANGYO CO., LTD., THE GAKUSHUIN SCHOOL CORPORATION
Abstract: A lithium-lanthanum-titanium oxide sintered material has a lithium ion conductivity 3.0×10?4 Scm?1 or more at a measuring temperature of 27° C., the material is described by one of general formulas (1-a)LaxLi2-3xTiO3-aSrTiO3, (1-a)LaxLi2-3xTiO3-aLa0.5K0.5TiO3, LaxLi2-3xTi1-aMaO3-a, and Srx-1.5aLaaLi1.5-2xTi0.5Ta0.5O3 (0.55?x?0.59, 0?a?0.2, M=at least one of Al, Fe and Ga), and concentration of S is 1500 ppm or less. The material is obtained by sintering raw material powder mixture having S content amount of 2000 ppm or less in the entirety of raw material powders for mixture, that is, titanium raw material, lithium raw material, and lanthanum raw material.
Type:
Grant
Filed:
July 12, 2013
Date of Patent:
July 4, 2017
Assignees:
TOHO TITANIUM CO., LTD., NAKASHIMA SANGYO CO., LTD., THE GAKUSHUIN SCHOOL CORPORATION
Abstract: A lithium-lanthanum-titanium oxide sintered material has a lithium ion conductivity 3.0×10?4 Scm?1 or more at a measuring temperature of 27° C., the material is described by one of general formulas (1?a)LaxLi2-3xTiO3-aSrTiO3, (1?a)LaxLi2-3xTiO3-aLa0.5K0.5TiO3, LaxLi2-3xTi1-aMaO3-a, Srx-1.5aLaaLi1.5-2xTi0.5Ta0.5O3 (0.55?x?0.59, 0?a?0.2, M=at least one of Fe or Ga), amount of Al contained is 0.35 mass % or less as Al2O3, amount of Si contained is 0.1 mass % or less as SiO2, and average particle diameter is 18 ?m or more.
Type:
Application
Filed:
April 22, 2013
Publication date:
April 9, 2015
Applicants:
Toho Titanium Co., Ltd., NAKASHIMA SANGYO CO., LTD., THE GAKUSHUIN SCHOOL CORPORATION