Abstract: A method to prepare functional polyester polyols by using micro-reaction device, wherein mixing ?-caprolactone/?-valerolactone monomer with mercapto alcohol evenly with appropriate organic solution under moistureless conditions, and continuously transferring the prepared mixing solution into a micro-reaction device supported with an immobilized enzyme for polymerization to synthetize a poly (?-caprolactone/?-valerolactone). Compared with the prior art, the present invention achieves a continuous production by using immobilized lipase Novozyme435 as a catalyst.

Abstract: The present disclosure provides a blue luminescent material, and the blue luminescent material is a tertradentate platinum complex having a chemical structure of Formula I comprising a pyridoimidazole carbene platinum structure. The blue luminescent material of the present disclosure may be used in OLED devices and apparatus as a dopant material and emits blue light having a wavelength of 450-490 nm. The present disclosure provides a design route for a material by introducing a pyridoimidazole-type carbene into the ligand of a platinum complex. Since the carbene structure has suitable triplet energy and its carbon-platinum bond is more stable than the nitrogen-platinum bond, the entire spectrum can become narrower, which will promote development of blue luminescent material and improve performances of the devices.

Abstract: The disclosure relates to a hybrid aqueous rechargeable battery, wherein the battery comprises a positive electrode and a negative electrode, and wherein the positive electrode and the negative electrode are in aqueous electrolytes with different pHs respectively. The hybrid aqueous rechargeable battery has a working voltage at least 0.6 V higher than the conventional aqueous lithium batteries and a theoretical energy density at least 60 Wh/kg higher. The hybrid aqueous rechargeable battery can be used for storage and discharge of electricity, etc.

Abstract: It discloses cement grinding aids prepared with waste antifreeze which comprises the following components in parts by weight: 20-75 parts of pretreated waste antifreeze, 5-40 parts of alkanolamine, 1-5 parts of acid solution, 3-12 parts of saccharide and 15-50 parts of water. The pretreated waste antifreeze is prepared by adding an alkaline solution into waste antifreeze to regulate the pH value, adding a flocculant, and stirring and standing; separating upper-layer oil, and then filtering to remove flocculent precipitates, thus obtaining a clear mixed solution.

Abstract: The Invention discloses a preparation method for a triptyl polymer separation membrane, wherein, it comprises the following steps: take triptycene compound containing active group, dichloride compound and diamino compound containing ether bond as monomers, and conduct polymerization in aprotic organic solvent in the presence of acid-binding agent; pour the obtained polymer solution into deionized water for precipitation after the reaction, filter out precipitates and wash with methanol and dry to get triptyl polymer; dissolve the triptyl polymer in aprotic organic solvent to produce a membrane-casting solution, apply the solution on support and dry to get a triptyl polymer separation membrane. The Invention solves the problem that the reticular polymer material is insoluble, and breaks the restriction for application of such material in separation membrane due to its insoluble and aging features.

Abstract: It relates to the field of synthetic macromolecular chemistry, and discloses a method for one-step synthesis of thiol-functionalized polyester polyols by organic catalysis. This method uses lactone monomer as reaction raw material, thiol-alcohol as initiator, and diphenyl phosphate as organic catalyst to catalyze and synthesize the thiol-functionalized polyester polyols. The present invention provides a method which is simple, inexpensive, easily controllable and environmentally friendly to prepare thiol-functionalized polyester polyols with the easily available and controllable catalyst. The method can selectively catalyze the ring opening polymerization of lactone to prepare thiol-functionalized polyester polyols using the organic catalyst.

Abstract: It discloses cement grinding aids prepared with waste antifreeze which comprises the following components in parts by weight: 20-75 parts of pretreated waste antifreeze, 5-40 parts of alkanolamine, 1-5 parts of acid solution, 3-12 parts of saccharide and 15-50 parts of water. The pretreated waste antifreeze is prepared by adding an alkaline solution into waste antifreeze to regulate the pH value, adding a flocculant, and stirring and standing; separating upper-layer oil, and then filtering to remove flocculent precipitates, thus obtaining a clear mixed solution.

Abstract: Disclosed is a method for manufacturing a vertically-growing open carbon nanotube thin film. The method comprises: grinding the surface of a ceramic film by using metallographical sandpaper, performing ultrasonic cleaning by using acetone and performing boiling with water, and performing drying to obtain a ceramic film substrate; dissolving a catalyst ferrocene in a carbon source dimethylbenzene in an ultrasonic manner, and adding a carbon nanotube growth promoting agent thiophene to form a mixed solution; putting the ceramic film substrate in a tubular furnace reactor, introducing nitrogen, and slowly injecting the mixed solution at a constant speed to perform a high-temperature vapor deposition reaction; and further performing plasma etching and nitric acid reflux heating treatment to open closed ends of carbon nanotubes, and removing catalyst particles on the carbon nanotube thin film to obtain the open carbon nanotube thin film that is highly vertically aligned.

Abstract: It discloses a chemical regeneration method of oxidized coenzyme NAD(P)+ which is under an oxygen or air atmosphere condition, adding a catalytic amount of bridged flavin, and oxidizing NAD(P)H to obtain NAD(P)+. The catalyst for regeneration of cofactor is cheap and easily available small organic molecule having no noble metal; this regeneration system can regenerate NADH and NADPH; this regeneration system has a wide pH range and temperature range, being applicable to various oxidation reactions catalyzed by nicotinamide-dependent oxidoreductase.

Abstract: A chemical additive for calcium sulphoaluminate-modified Portland cement comprises the following substances: (a) at least one alkanolamine borate; (b) at least one organic alcohol; and (c) at least one saccharide or a derivative thereof; and the substances and water are sequentially mixed and stirred to obtain the chemical additive for calcium sulphoaluminate-modified Portland cement. The chemical additive for calcium sulphoaluminate-modified Portland cement provided by the invention has better effects of regulating the setting time of the calcium sulphoaluminate-modified Portland cement and improving the 3d/28d strength increase rate, and also has a grinding aid effect when being added during grinding.

Abstract: Provided is a method for preparing a bulk C—AlN composite aerogel with high strength and high temperature resistance, which includes: evenly stirring aluminum chloride crystals, water, ethanol and epoxy propane, to obtain a clear aluminum oxide sol solution, then adding formaldehyde and resorcinol to the solution and performing even stirring, to obtain an RF/Al2O3 composite aerogel sol solution, leaving the gel to stand, treating the sample by using a supercritical CO2 drying method, and finally heat-treating the sample at a high temperature under the condition of nitrogen, to obtain the bulk C—AlN composite aerogel with high strength and high temperature resistance. The composite aerogel prepared by using this method has advantages of high integrity, high specific surface area, intact structure, low heat conductivity, low density, and high strength.

Abstract: It discloses a vanadium-titanium compound material with high thermal stability and high activity and a preparation method thereof. The vanadium-titanium compound material is mainly composed of vanadium oxide and titanium oxide, where the content of vanadium oxide is 0.5% to 30% by mass of the vanadium-titanium compound material, and the crystal form of titanium oxide in the vanadium-titanium compound material is one of anatase and TiO2(B) or a mixture thereof.

Abstract: The present invention discloses a ?-polylysine hydrogel and the preparation method and application of the as-described ?-polylysine hydrogel. The polylysine hydrogel is non-toxic to a recipient, and has biodegradability and biocompatibility. The wound tissue healing material prepared by the present invention can be used in wound tissue adhesion in an efficient, stable, safe manner.

Abstract: This invention discloses a method for preparing an antibacterial and dust-removal membrane. The method comprises the following steps: depositing a layer of nano-ZnO on the immersed membrane surface as the seed crystal with the atomic layer deposition instrument (ALD instrument); vertically immersing the membrane covered with nano-ZnO layer in a hydrothermal reactor filled with crystal growth solution, heating it for a period of time, taking the membrane out and cooling it to the room temperate, and removing it from the substrate; finally, heating this membrane in a drier, and purging it with nitrogen to remove the paraffin within the membrane pore to obtain the porous membrane with nano-ZnO arrays growing on the surface.

Abstract: A chemical additive for calcium sulphoaluminate-modified Portland cement comprises the following substances: (a) at least one alkanolamine borate; (b) at least one organic alcohol; and (c) at least one saccharide or a derivative thereof; and the substances and water are sequentially mixed and stirred to obtain the chemical additive for calcium sulphoaluminate-modified Portland cement. The chemical additive for calcium sulphoaluminate-modified Portland cement provided by the invention has better effects of regulating the setting time of the calcium sulphoaluminate-modified Portland cement and improving the 3d/28d strength increase rate, and also has a grinding aid effect when being added during grinding.

Abstract: This invention discloses a method for preparing an antibacterial and dust-removal membrane. The method comprises the following steps: depositing a layer of nano-ZnO on the immersed membrane surface as the seed crystal with the atomic layer deposition instrument (ALD instrument); vertically immersing the membrane covered with nano-ZnO layer in a hydrothermal reactor filled with crystal growth solution, heating it for a period of time, taking the membrane out and cooling it to the room temperate, and removing it from the substrate; finally, heating this membrane in a drier, and purging it with nitrogen to remove the paraffin within the membrane pore to obtain the porous membrane with nano-ZnO arrays growing on the surface.

Abstract: A portable rapid detection device for heavy metal ions includes a card electrode and a thin-layer flow cell, wherein a three-electrode system of the card electrode is inserted in a micro-channel of the thin-layer flow cell; and heavy metal ions are detected by using an anodic stripping voltammetry (ASV), a solution to be detected flows by the surface of a working electrode in the micro-channel, and heavy metals are enriched and stripped on the surface thereof.

Abstract: It discloses a chemical regeneration method of oxidized coenzyme NAD(P)+ which is under an oxygen or air atmosphere condition, adding a catalytic amount of bridged flavin, and oxidizing NAD(P)H to obtain NAD(P)+. The catalyst for regeneration of cofactor is cheap and easily available small organic molecule having no noble metal; this regeneration system can regenerate NADH and NADPH; this regeneration system has a wide pH range and temperature range, being applicable to various oxidation reactions catalyzed by nicotinamide-dependent oxidoreductase.

Abstract: A method for preparing caprolactam by using a microreactor under Lewis acid catalysis, wherein a hydroxyl group in a cyclohexanone oxime is activated to obtain a cyclohexanone oxime sulfonates intermediate, then rearranged under Lewis acid catalysis to prepare the caprolactam. The method of this invention has a simple process and a high operation safety and selectivity, the reaction condition is mild, an efficient reaction can take place even at room temperature, the reaction time is short, the conversion of the cyclohexanone oxime can reach 100% within a short time, the selectivity of the caprolactam can reach 99%, the energy consumption is greatly reduced in the premise of maintaining a high yield, and the production cost is reduced, being an efficient and green and environmentally friendly method of for synthesizing the caprolactam.

Abstract: A portable rapid detection device for heavy metal ions includes a card electrode and a thin-layer flow cell, wherein a three-electrode system of the card electrode is inserted in a micro-channel of the thin-layer flow cell; and heavy metal ions are detected by using an anodic stripping voltammetry (ASV), a solution to be detected flows by the surface of a working electrode in the micro-channel, and heavy metals are enriched and stripped on the surface thereof.