Abstract: A thermoplastic starch (TPS)/polylactic acid (PLA)/poly(butylene adipate-co-terephthalate) (PBAT) blend modified biodegradable resin is prepared by using a chain extender, and is prepared from the following raw materials: 20-30 parts by weight of TPS; 20-30 parts by weight of PLA; 40-60 parts by weight of PBAT; and 0.5-0.9 parts by weight of a chain extender KL-E. The preparation method is a two-step method: blending the TPS with the PBAT in a twin screw for granulating; mixing TPS/PBAT mixed granules with PLA granules, and dissolving the chain extender KL-E into an ethyl acetate solution. The chain extender KL-E can be uniformly distributed in PLA and TPS/PBAT mixed granules by using a spraying method, and the remaining short-chain molecules and terminal carboxyl molecules in the mixed granules can be changed into long-chain molecules.
Type:
Grant
Filed:
October 12, 2019
Date of Patent:
March 12, 2024
Assignee:
NANJING WURUI BIODEGRADABLE NEW MATERIAL RESEARCH INSTITUTE CO., LTD.
Abstract: A multi-stage modified thermoplastic starch (TPS) masterbatch is obtained by four-stage modification treatment as follows: (i) 100 parts of starch with a moisture content of 15% to 30% are added to a high-speed mixer and stirred under room temperature; (ii) Heated to 50° C. to 70° C., polybutadiene (PB), plasticizer and a chemical modifier are added. The mixture is then stirred a second time; (iii) Heated to 75° C. to 95° C., tackifier, lubricant, filler and chain extender are added. The mixture is again stirred a third time. (iv) A biodegradable resin is added at this temperature, and the resulting mixture is stirred a fourth time. After the stirring is completed, the resulting mixture is incubated at this temperature for a predetermined time, and then added to a twin-screw extruder for melt extrusion. The present invention also discloses a preparation method and use.
Type:
Grant
Filed:
July 24, 2020
Date of Patent:
August 22, 2023
Assignee:
Nanjing Wurui Biodegradable New Material Research Institute
Co., LTD.
Abstract: A thermoplastic starch (TPS)/polylactic acid (PLA)/poly(butylene adipate-co -terephthalate) (PBAT) blend modified biodegradable resin is prepared by using a chain extender, and is prepared from the following raw materials: 20-30 parts by weight of TPS; 20-30 parts by weight of PLA; 40-60 parts by weight of PBAT; and 0.5-0.9 parts by weight of a chain extender KL-E. The preparation method is a two-step method: blending the TPS with the PBAT in a twin screw for granulating; mixing TPS/PBAT mixed granules with PLA granules, and dissolving the chain extender KL-E into an ethyl acetate solution. The chain extender KL-E can be uniformly distributed in PLA and TPS/PBAT mixed granules by using a spraying method, and the remaining short-chain molecules and terminal carboxyl molecules in the mixed granules can be changed into long-chain molecules.
Type:
Application
Filed:
October 12, 2019
Publication date:
February 10, 2022
Applicant:
NANJING WURUI BIODEGRADABLE NEW MATERIAL RESEARCH INSTITUTE CO., LTD.
Abstract: A multi-stage modified thermoplastic starch (TPS) masterbatch is obtained by four-stage modification treatment as follows: (i) 100 parts of starch with a moisture content of 15% to 30% are added to a high-speed mixer and stirred under room temperature; (ii) Heated to 50° C. to 70° C., polybutadiene (PB), plasticizer and a chemical modifier are added. The mixture is then stirred a second time; (iii) Heated to 75° C. to 95° C., tackifier, lubricant, filler and chain extender are added. The mixture is again stirred a third time. (iv) A biodegradable resin is added at this temperature, and the resulting mixture is stirred a fourth time. After the stirring is completed, the resulting mixture is incubated at this temperature for a predetermined time, and then added to a twin-screw extruder for melt extrusion. The present invention also discloses a preparation method and use.
Type:
Application
Filed:
July 24, 2020
Publication date:
January 6, 2022
Applicant:
Nanjing Wurui Biodegradable New Material Research Institute Co., LTD.