Abstract: A polymer production process comprising reacting a compound represented by the following formula (1) in the presence of a binuclear metal complex represented by the following formula (2). R4-nMHn??(1) (in the formula (1), R is a monovalent organic group, M is a silicon atom or a germanium atom, and n is 2 or 3.) [CpM(?-CH2)]2??(2) (in the formula (2), Cp is a cyclopentadienyl-based ligand, M is a metal atom selected from Rh and Ir, and the bond between M's is a double bond.
Type:
Application
Filed:
July 9, 2009
Publication date:
July 28, 2011
Applicants:
National Univ. Corp. Kanazawa University, JSR CORPORATION, JAPAN SCIENCE AND TECHNOLOGY AGENCY
Abstract: A polysilane production process comprising reacting a specific silane compound typified by a cyclic silane compound represented by the following formula (2) in the presence of a binuclear metal complex represented by the following formula (4). SijH2j??(2) (in the formula (2), j is an integer of 3 to 10.) [CpM(?-CH2)]2??(4) (in the formula (4), Cp is a cyclopentadienyl-based ligand, M is a metal atom selected from Rh and Ir, and the bond between M's is a double bond.
Type:
Application
Filed:
July 9, 2009
Publication date:
June 30, 2011
Applicants:
JAPAN SCIENCE AND TECHNOLOGY AGENCY, National Univ. Corp. Kanazawa University, JSR CORPORATION