Abstract: Polyamides, and methods of making and using polyamides, that have a difference between melting temperature (Tm) and crystallization temperature (Tc) of at most 20° C. are disclosed herein. Such polyamides can exhibit exceptionally fast crystallization kinetics making them suitable for use as engineering thermoplastics in melt processing methods such as injection molding. Particularly useful polyamides include 1,9-nonamethylene adipamide-co-1,9-nonamethylene terephthalamide copolymers.
Abstract: A polymeric material, prepared by reacting a mixture comprising a polyorganosiloxane having one or more isocyanate-reactive functional groups, polyisocyanate, and polyol, is provided. The isocyanate-reactive functional groups, typically one or two, are attached to only a single end of the polyorganosiloxane chains. The polymeric material may be used to form coatings on a substrate and to inhibit fouling on surfaces exposed to aqueous conditions.
Type:
Grant
Filed:
September 13, 2012
Date of Patent:
December 10, 2013
Assignee:
NDSU Research Foundation
Inventors:
Dean C. Webster, Abdullah Ekin, Stacy Sommer
Abstract: Amphiphilic copolymers formed from plant oil-derived vinyl ether monomers and polyethylene glycol alkyl vinyl ethers are provided. Nanoparticles coated with these amphiphilic polymers are well-suited for water remediation applications.
Type:
Application
Filed:
May 17, 2013
Publication date:
December 5, 2013
Applicant:
NDSU Research Foundation
Inventors:
Bret Ja Chisholm, AChintya Bezbaruah, Harjyoti Kalita
Abstract: A protective coating including a crosslinked polyester that is removable with a basic composition, as well as coated articles, methods of preparing a protective coating, and methods of using a protective coating.
Type:
Application
Filed:
April 19, 2013
Publication date:
November 14, 2013
Applicant:
NDSU Research Foundation
Inventors:
Tara J. Shedlosky, Gordon P. Bierwagen, Dean C. Webster, Andrew M. Huovinen
Abstract: Disclosed are methods of treating a metal to improve the metal's corrosion resistance. The method includes applying, to the surface of the metal, a coating which comprises magnesium powder and a binder. The present invention also relates to a coating composition that includes magnesium powder and a silane modified epoxy isocyanate hybrid polymer or prepolymer. The inventors have found that corrosion resistance (as determined by Prohesion™ exposure in accordance with ASTM D5894-96, which is hereby incorporated by reference) in excess of 3,000 hours on 2024 T-3 aluminum alloy can be achieved with the methods and coating compositions of the present invention.
Type:
Grant
Filed:
October 7, 2004
Date of Patent:
October 29, 2013
Assignee:
NDSU Research Foundation
Inventors:
Michael E. Nanna, Gordon P. Bierwagen, Dante Battocchi
Abstract: Alkyd resin compositions which comprise the monomer-grafting polymerization of a) an alkyd, which is an ester of a polyol having 4 or more hydroxyl groups and an unsaturated fatty acid, and b) an unsaturated monomer having a carbon-carbon double bond are disclosed. The alkyd may be a partially esterified polyol. Coating compositions of containing the alkyd resin compositions of the invention are also disclosed.
Abstract: Provided are silicon-containing films with a refractive index suitable for antireflection, articles having a surface comprising the films, and atmospheric-pressure plasma-enhanced chemical vapor deposition (AE-PECVD) processes for the formation of surface films and coatings. The processes generally include providing a substrate, providing a precursor comprising silicon, and reacting the precursor with a gas comprising nitrogen (N2) in a low-temperature plasma at atmospheric pressure, wherein the products of the reacting form a film on the substrate. An antireflection coating made by the process can have a refractive index of about 1.5 to about 2.2. Articles are provided having a surface that includes the antireflection coating.
Abstract: Disclosed are photo sensitizers that include a polyol moiety covalently bonded to a fused aromatic moiety. Also disclosed is a method for improving UV laser ablation performance of a coating, such as a cationic UV curable coating, by incorporating an oxalyl-containing additive into the cationic UV curable or other coating. Oxalyl-containing sensitizers having the formula Q-O—C(O)—C(O)—O—R1 wherein Q represents a fused aromatic moiety and R1 is an alkyl or aryl group, are also disclosed, as are oxalyl-containing oxetane resins, oxalyl-containing polyester polyols, and cationic UV curable coating formulations that include oxalyl-containing additives.
Abstract: Described herein are synthesis schemes and methods for producing silicon based nanostructures and materials, including compositions and methods for synthesis of silicon-based nanowires and composites from three-component and four-component liquid silane/polymer inks. Materials and methods for producing silicon based micro and nanofibers that can be used in a variety of applications including material composites, electronic devices, sensors, photodetectors, batteries, ultracapacitors, and photosensitive substrates, and the like.
Abstract: Functionalized cross-linked polysiloxanes, such as quaternary ammonium terminated cross-linked polyalkylsiloxanes are described herein. The functionalized cross-linked polysiloxanes may be used in an antifouling composition to prevent biological fouling in aqueous and/or marine environments.
Type:
Grant
Filed:
January 7, 2008
Date of Patent:
February 12, 2013
Assignee:
NDSU Research Foundation
Inventors:
Bret Ja Chisholm, Partha Majumdar, Shane J. Stafslien, Philip Boudjouk
Abstract: Polymers and copolymers are formed from vinylether monomers having fatty acid ester pendent groups derived from plant oils, such as soybean oil.
Abstract: A polymeric material, prepared by reacting a mixture comprising a polyorganosiloxane having one or more isocyanate-reactive functional groups, polyisocyanate, and polyol, is provided. The isocyanate-reactive functional groups, typically one or two, are attached to only a single end of the polyorganosiloxane chains. The polymeric material may be used to form coatings on a substrate and to inhibit fouling on surfaces exposed to aqueous conditions.
Type:
Grant
Filed:
June 9, 2008
Date of Patent:
October 30, 2012
Assignee:
NDSU Research Foundation
Inventors:
Dean C. Webster, Abdullah Ekin, Stacy Sommer
Abstract: The present invention provides an amphiphilic polymeric material well-suited as a coating for marine applications, such as use as a fouling-release coating on the external surfaces of ships, particularly ship hulls. Also provided are methods of making the polymeric material and methods for using the polymeric material, as well as articles and surfaces that are coated with the polymeric material.
Type:
Application
Filed:
December 3, 2010
Publication date:
October 11, 2012
Applicant:
NDSU Research Foundation
Inventors:
Bret Ja Chisholm, David Allen Christianson
Abstract: A polymer that is a polysiloxane polymer has fluoroquinolone antibiotic groups, or pharmaceutically acceptable salts thereof, attached via linkers. The linkers may be hydrolytically labile thereby providing a manner of releasing the fluoroquinolone antibiotic from the polymer.
Type:
Grant
Filed:
October 28, 2011
Date of Patent:
October 9, 2012
Assignee:
NDSU Research Foundation
Inventors:
Shane Jeremy Stafslien, Bret Ja Chisholm, Alex J. Kugel
Abstract: Polyamine cross-linked polysiloxanes, such as functionalized polysiloxane cross-linked with a polyalkylenepolyamine are described herein. The polyamine cross-linked polysiloxanes may be used in an antifouling composition to prevent biological fouling in marine environments.
Type:
Grant
Filed:
April 20, 2010
Date of Patent:
October 2, 2012
Assignee:
NDSU Research Foundation
Inventors:
Bret Ja Chisholm, Philip Boudjouk, Johnson Thomas, David Allen Christianson, Shane Jeremy Stafslien
Abstract: A novel UV-curable coating includes acrylated soybean oil, a hyperbranched acrylate, an optional adhesion promoter, and an optional renewable reactive diluent.
Abstract: Disclosed are photo sensitizers that include a polyol moiety covalently bonded to a fused aromatic moiety. Also disclosed is a method for improving UV laser ablation performance of a coating, such as a cationic UV curable coating, by incorporating an oxalyl-containing additive into the cationic UV curable or other coating. Oxalyl-containing sensitizers having the formula Q-O—C(O)—C(O)—O—R1 wherein Q represents a fused aromatic moiety and R1 is an alkyl or aryl group, are also disclosed, as are oxalyl-containing oxetane resins, oxalyl-containing polyester polyols, and cationic UV curable coating formulations that include oxalyl-containing additives.
Abstract: The present provides methods for using lipoic acid. In one embodiment, the methods include administering lipoic acid to a female subject in need thereof, wherein at least 10 milligrams lipoic acid per kilogram of body weight is administered. In another embodiment, the methods include administering to a female subject in need thereof an effective amount of lipoic acid, wherein concentration of progesterone in the blood of the subject is increased compared to the subject prior to administration of the lipoic acid. The subject may be pregnant.
Abstract: Platinum (II) terdentate or bidentate complexes with non-linear optical properties are provided. The complexes have a broadband spectral and temporal response, and strong reverse saturable absorption and two-photon absorption in the visible and the near-IR region. As such, the complexes are useful for organic light-emitting diodes and optical-switching or sensing devices.
Type:
Application
Filed:
October 21, 2011
Publication date:
April 26, 2012
Applicant:
NDSU RESEARCH FOUNDATION
Inventors:
Wenfang Sun, Bingguang Zhang, Rui Liu, Pin Shao, Zhiqiang Ji, Zhongjing Li
Abstract: Disclosed are ?-amino acids that are unsubstituted in the ? position; that are substituted in the ? position with an aryl group; that are substituted in the ? position with an aryl group; that bear two substituents in the ? position; and/or that are substituted in the ? and ? positions with groups which, together with the carbon atoms at the ? and ? positions, form a ring. Also disclosed are methods for making the above-mentioned ?-amino acids and other ?-amino acids which involve providing an ?,?-unsaturated imide; converting the ?,?-unsaturated imide to a 2-substituted-isoxazolidin-5-one; and converting the 2-substituted-isoxazolidin-5-one to a ?-amino acid.
Type:
Application
Filed:
September 20, 2011
Publication date:
March 22, 2012
Applicant:
NDSU Research Foundation
Inventors:
Mukund P. SIBI, Craig P. Jasperse, Prabagaran Narayanasamy, Sandeep R. Ghorpade