Patents Assigned to Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
  • Patent number: 5395943
    Abstract: The invention provides a method of purifying 2-alkyl-4-halo-5-formylimidazoles, which comprises dissolving an 2-alkyl-4-halo-5-formylimidazole in an aqueous solution of a sulfonating agent, adjusting the solution to pH 1-6, and removing the impurity 2-alkyl-4,5-dihaloimidazole by filtration or extraction.
    Type: Grant
    Filed: February 16, 1994
    Date of Patent: March 7, 1995
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Toshio Yamamoto, Yoshihiro Hibi, Toshimi Ogawa
  • Patent number: 5384187
    Abstract: A biodegradable resin composition including a saponified ethylene-vinyl acetate copolymer and a starch-based macromolecular substance. The saponified ethylene-vinyl acetate copolymer is one having an ethylene content of 20 to 60 mole %, a vinyl acetate saponification degree of not less than 90 mole %, a melt flow index of 1 to 100 g/10 min as measured under a load of 2160 g at 210.degree. C., and a melt viscosity ratio .eta..sub.60 /.eta..sub.5 of 0.5 to 4 where .eta..sub.60 means the melt viscosity after 60 minutes of standing at 250.degree. C. and the .eta..sub.5 means the melt viscosity after 5 minutes of standing at 250.degree. C. and a starch-based macromolecular substance. A layer of the above composition can be used to fabricate a laminate with a substrate material of a different kind, such as a photodegradable polymer.
    Type: Grant
    Filed: January 11, 1993
    Date of Patent: January 24, 1995
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Tomoyoshi Uemura, Yoshimi Akamatsu, Yuichi Yoshida, Yoshikazu Moriwaki
  • Patent number: 5373054
    Abstract: A process for agglomerating a polymer powder which comprises mixing a polymer powder with an oxyalkylene group-containing polyvinyl alcohol resin in the presence of water and drying the resulting mixture. According to the process of the present invention, it is possible to easily prepare the polymer granules having little fine powder, a narrow particle size distribution and a large average particle size.
    Type: Grant
    Filed: December 9, 1992
    Date of Patent: December 13, 1994
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Shinji Sanuki, Yoshinori Chosakon, Tsukasa Oishi
  • Patent number: 5369015
    Abstract: Disclosed is a method for producing an angiotensin converting enzyme inhibitor composition from natural materials, which composition is of use as an antihypertensive drug or diet. The method comprises heating a meat in water at a temperature not lower than 50.degree. C. to extract water-soluble protein and hydrolyzing the residue predominantly composed of water-insoluble protein with a protease.
    Type: Grant
    Filed: October 14, 1992
    Date of Patent: November 29, 1994
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Masaaki Yoshikawa, Keiichi Yokoyama, Masayasu Hasegawa, Ryouichi Yasumoto, Hiroyuki Fujita
  • Patent number: 5338502
    Abstract: A process for preparing a molded article of a hydrolyzed ethylene-vinyl acetate copolymer which includes separately melting each of a hydrolyzed ethylene-vinyl acetate copolymer and a polyolefin, admixing the melted copolymer with the melted polyolefin in a weight ratio of the hydrolyzed ethylene-vinyl acetate copolymer to the polyolefin of 30/70 to 70/30 and molding the mixture, according to which the molded article having improved flex-crack resistance, stretchability and thermoformability can be obtained with minimized deterioration of gas-impermeability.
    Type: Grant
    Filed: June 22, 1992
    Date of Patent: August 16, 1994
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Takamasa Moriyama, Hiroki Masumoto, Kuniyasu Kato
  • Patent number: 5336779
    Abstract: In producing formylimidazoles by catalytically oxidizing the corresponding 4- or 5-hydroxymethylimidazoles, the catalytic oxidation is carried out in the presence of a noble metal catalyst while oxygen or air is blown into the reaction system. In this case, it is particularly desirable that the catalytic oxidation in the presence of a noble metal catalyst be carried out in a solvent comprising an aqueous alkali or in a mixed solvent composed of an aqueous alkali and an organic solvent immiscible with water.
    Type: Grant
    Filed: September 23, 1993
    Date of Patent: August 9, 1994
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Toshio Yamamoto, Kazumasa Hirata, Shigenori Wakabayashi, Akio Katsuura
  • Patent number: 5322877
    Abstract: A resin composition including (A) a saponified ethylene-vinyl acetate copolymer having an ethylene content of 20 to 60 mole percent and a saponification degree of not less than 90 mole percent, (B) a polyolefin resin, (C) a carboxylic acid-modified polyolefin resin and (D) a lower fatty acid alkaline earth metal salt, characterized in:that the proportion of (A) relative to the total amount of (A) plus (B) plus (C) is 0.3 to 0.7 on the weight basis;that the composition contains the carbonyl group in an amount of 0.002 to 0.05 equivalent per 100 grams of the total of (B) plus (C); andthat the equivalent ratio between (D) and the carbonyl group in (C) is 0.5 to 5,and a method of producing the resin composition are provided.
    Type: Grant
    Filed: March 10, 1993
    Date of Patent: June 21, 1994
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Takamasa Moriyama, Hiroki Masumoto, Kiniyasu Kato, Mitsuo Shibutani
  • Patent number: 5319094
    Abstract: This invention provides a process for producing 2-alkyl-4-halo-5-formylimidazoles which includes halogenating 2-alkyl-5-formylimidazoles with a N-halosuccinimides in the presence of dioxane or mixture of dioxane and ethylene glycol monomethylether as solvent and in the presence of alkali metal hydrogen carbonate as catalyst, which are readily available, with good yield.
    Type: Grant
    Filed: December 31, 1992
    Date of Patent: June 7, 1994
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Takehiko Kakimoto, Toshimi Ogawa
  • Patent number: 5314807
    Abstract: A method of producing an angiotensin converting enzyme inhibitor-containing composition, which is of value as an antihypertensive agent or diet, from natural resources. According to the method, proteins are hydrolyzed with a protease elaborated by a microorganism of the genus Bacillus, Aspergillus or Rhizopus or a protease of papaya origin.
    Type: Grant
    Filed: March 27, 1992
    Date of Patent: May 24, 1994
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Masaaki Yoshikawa, Keiichi Yokoyama, Masayasu Hasegawa, Ryouichi Yasumoto, Hiroyuki Fujita
  • Patent number: 5310788
    Abstract: An improved saponified ethylene-vinyl acetate copolymer composition comprising(A) 50 to 99.5 weight % of a saponified ethylene-vinyl acetate copolymer,(B) 0.4 to 50 weight % of an ethylene copolymer having a density of 0.90.about.0.94 g/cm.sup.3, and(C) a graft polymer obtainable by grafting an ethylenically unsaturated carboxylic acid or a derivative thereof to a polyolefin resin and reacting the adduct with a polyamide oligomer or polyamide.
    Type: Grant
    Filed: April 29, 1992
    Date of Patent: May 10, 1994
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Takamasa Moriyama, Hiroshi Takida, Tomoyoshi Uemura
  • Patent number: 5308879
    Abstract: A process for producing a biodegradable resin foam, having the steps of mixing a starch polymer containing from 5% by weight to 30% by weight of water, a vinyl alcohol resin containing from 5% by weight to 30% by weight of water, a nonionic surfactant, an inorganic or organic filler, and optionally a thickening agent; optionally adjusting the water content of the mixture, to prepare a composition having from 5% by weight to 30% by weight of water on the whole, based on total weight of the composition; melting and expanding it to prepare a foam, which has a low density and fine closed cells, and shows a good surface condition in a molded body.
    Type: Grant
    Filed: August 13, 1993
    Date of Patent: May 3, 1994
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yoshimi Akamatu, Masahiro Tomori
  • Patent number: 5298334
    Abstract: An improved saponified ethylene-vinyl acetate copolymer composition comprising(A) 50 to 99.5 weight % of a saponified ethylene-vinyl acetate copolymer,(B) 0.4 to 50 weight % of an ethylene copolymer having a density of 0.90.about.0.94 g/cm.sup.3, and(C) a graft polymer obtainable by grafting an ethylenically unsaturated carboxylic acid or a derivative thereof to a polyolefin resin and reacting the adduct with a polyamide oligomer or polyamide.
    Type: Grant
    Filed: August 21, 1991
    Date of Patent: March 29, 1994
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Takamasa Moriyama, Hiroshi Takida, Tomoyoshi Uemura
  • Patent number: 5280065
    Abstract: A saponified ethylene-vinyl acetate copolymer composition comprising(A) 50 to 99.5 weight % of a saponified ethylenevinyl acetate copolymer,(B) 0.4 to 50 weight % of a polyolefin resin, and(C) a graft polymer obtainable by grafting an ethylenically unsaturated carboxylic acid or a derivative thereof to a polyolefin resin and reacting the adduct with a polyamide oligomer or polyamide, which composition satisfies the relation: M.sub.2 /M.sub.1 =not less than 2 wherein M.sub.2 and M.sub.1 are the melt flow rates of (B) and (A), respectively, under a load of 2160 g at 210.degree. C.
    Type: Grant
    Filed: January 31, 1991
    Date of Patent: January 18, 1994
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Takamasa Moriyama, Hiroyuki Honda, Hiroshi Takida
  • Patent number: 5278229
    Abstract: A polyolefin resin composition comprising(A) 50 to 99.5 weight % of a polyolefin resin,(B) 0.4 to 50 weight % of a saponified ethylenevinyl acetate copolymer, and(C) 0.1 to 15 weight % of a graft polymer obtainable by grafting an ethylenically unsaturated carboxylic acid or a derivative thereof to a polyolefin resin and reacting the adduct with a polyamide oligomer or polyamide, which composition satisfies the relation: M.sub.2 /M.sub.1 =not less than 1.5 wherein M.sub.2 and M.sub.1 are the melt flow rates of (B) and (A), respectively, under a load of 2160 g at 210 C. The present invention is predicated on the above finding.
    Type: Grant
    Filed: January 31, 1991
    Date of Patent: January 11, 1994
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Kuniyoshi Asano, Tomoyoshi Uemura, Hiroshi Takida
  • Patent number: 5266704
    Abstract: The invention provides a process for producing a 2-substituted-4-hydroxymethylimidazole easily and in good yield by means of simple equipment. This process comprises reacting hydroxymethylglyoxal, a monoaldehyde and ammonia in a sequence such that said monoaldehyde and ammonia are first reacted with each other and hydroxymethylglyoxal is then introduced into the reaction system for further reaction.
    Type: Grant
    Filed: September 3, 1992
    Date of Patent: November 30, 1993
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Takehiko Kakimoto, Toshima Ogawa
  • Patent number: 5214090
    Abstract: 1. A resin composition which comprises(A) a saponified ethylene-vinyl acetate copolymer,(B) a polyolefin resin,(C) a graft polymer obtained by grafting an ethylenically unsaturated carboxylic acid or a derivative thereof to a polyolefin resin and reacting the adduct with a polyamide oligomer or polyamide, and(D) a hydrotalcite solid solution representable by the general formula[(M.sup.2+).sub.y1 (M.sup.2+).sub.y2 ].sub.1-x M.sup.3+ (OH).sub.2 A.sub.x/n.mH.sub.2 Owherein M.sup.2+ represents at least one metal selected from among Mg, Ca, Sr and Ba, M.sup.2+ is a metal selected from among Zn, Cd, Pb and Sn, M.sup.3+ is a trivalent metal, A.sup.n- is an anion having a valence of n, and x, y1, y2 and m are respectively positive numbers satisfying the conditions 9<x.ltoreq.0.5, 0.5<y1<1, u1+y2=1, and 0.ltoreq.m<2.
    Type: Grant
    Filed: April 10, 1992
    Date of Patent: May 25, 1993
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Takamasa Moriyama, Hiroyuki Honda, Hiroshi Takida
  • Patent number: 5210159
    Abstract: A process for preparing a porous and water-absorbent resin which includes dispersing an aqueous solution containing at least one .alpha.,.beta.-unsaturated carboxylic acid monomer, its alkali metal salt or its ammonium salt in a hydrophobic organic solvent, and conducting a reversed phase suspension polymerization by using a water-soluble radical polymerization initiator, while distilling away the hydrophobic organic solvent together with water. A porous and water-absorbent resin having excellent absorbency and a remarkably improved rate of water absorption can be easily and efficiently obtained on an industrial scale.
    Type: Grant
    Filed: March 27, 1991
    Date of Patent: May 11, 1993
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Hiroshi Aoyama, Tetsuo Moriya, Susumu Kondo
  • Patent number: 5190712
    Abstract: A method for melt-molding a water-soluble vinyl alcohol polymer which includes melt-molding a water-soluble oxyalkylene group-containing vinyl alcohol copolymer under substantially anhydrous conditions and substantially without use of plasticizer, the copolymer having a vinyl alcohol unit (A), a vinyl ester unit (B) and an oxyalkylene ether unit (C) of the formulas: ##STR1## wherein R.sup.1 is an alkyl group; R.sup.2 and R.sup.3 each is a hydrogen atom or an alkyl group; R.sup.4 is a hydrogen atom, an alkyl group, a phenyl group or a substituted phenyl group; n is equal to 1 through 50; in proportions of a mol %, b mol % and c mol %, respectively, where0.1.ltoreq.c.ltoreq.20,50.ltoreq.100a/(a+b).ltoreq.100,and the oxyalkylene moiety (CHR.sup.2 --CHR.sup.3 --O--).sub.n of unit (C) accounts for 3 to 40 percent by weight of the total resin, and having a melt index of not less than 5 g/10 min. under a load of 2160 at a temperature of 210.degree. C.
    Type: Grant
    Filed: August 30, 1991
    Date of Patent: March 2, 1993
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Tsukasa Oishi, Toru Seki, Takuya Honda
  • Patent number: 5177138
    Abstract: A resin composition which comprises(A) a saponified ethylene-vinyl acetate copolymer,(B) a polyolefin resin,(C) a graft polymer obtained by grafting an ethylenically unsaturated carboxylic acid or a derivative thereof to a polyolefin resin and reacting the adduct with a polyamide oligomer or polyamide, and(D) a hydrotalcite compound representable by the general formulaM.sub.X Al.sub.y (OH).sub.2x+3y-2z (E).sub.z.aH.sub.2 Owherein M is Mg, Ca or Zn, E is CO.sub.3 or HOP.sub.4, x, y and z each independently is a positive number and a is 0 (zero) or a positive number.
    Type: Grant
    Filed: April 13, 1992
    Date of Patent: January 5, 1993
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Takamasa Moriyama, Hiroyuki Honda, Hiroshi Takida
  • Patent number: 5160475
    Abstract: A method of producing shaped articles having excellent impact resistance which includes melt-molding a composition derived from a saponified ethylene-vinyl acetate copolymer (A) by incorporating therein an ethylene-propylene copolymer elastomer (B) and a graft polymer (C) obtained by grafting an ethylenically unsaturated carboxylic acid or a derivative thereof to a polyolefin resin and reacting the resulting grafting product further with a polyamide oligomer or polyamide.
    Type: Grant
    Filed: January 31, 1991
    Date of Patent: November 3, 1992
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Kuniyoshi Asano, Tomoyoshi Uemura, Hiroshi Takida