Abstract: A four component additive package that contains a first phosphite, a second phosphite, a primary antioxidant and an optical brightener is used in combination with a polyethylene that is polymerized with a mixed catalyst system that contains two different types of catalysts. The stabilized polyethylene exhibits improved color performance.

Abstract: Compositions for forming rotationally molded (rotomolded) parts, methods for forming the rotomolded parts, and the rotomolded parts are provided. An exemplary rotomolding composition includes a virgin resin, including a polyethylene polymer, and a postconsumer recycle (PCR) resin.

Abstract: Disclosed herein are the design and construction methods for a specialized structure, or “cabinet”, to house compressed gas cylinders such that they may be kept within an ordinary building.

Abstract: Oxidative dehydrogenation catalysts for converting lower paraffins to alkenes such as ethane to ethylene when prepared as an agglomeration, for example extruded with supports comprising slurries of Nb2O5.

Abstract: This disclosure relates to an improved continuous solution polymerization process wherein production rate is increased. Process solvent, ethylene, optional comonomers, optional hydrogen and a bridged metallocene catalyst formulation are injected into a first reactor to form a first ethylene interpolymer. Optionally, process solvent, ethylene, optional comonomers, optional hydrogen and a bridged metallocene catalyst formulation are injected into a second reactor forming a second ethylene interpolymer. The first and second reactors may be configured in series or parallel modes of operation. Optionally, a third ethylene interpolymer is formed in a third reactor, wherein a homogeneous catalyst formulation or a heterogeneous catalyst formulation is employed. In solution, the first, optional second and optional third ethylene interpolymers are combined, the catalyst is deactivated, the solution is optionally passivated and following a phase separation process an ethylene interpolymer product is recovered.

Abstract: An ethylene interpolymer product comprises a first component with an undetectable level of long-chain branches and a second component with a detectable level of long-chain branches wherein said first component has a weight-average molecular weight higher than said second component. The ethylene interpolymer product is characterized as having (a) an Arrhenius type flow activation energy Ea greater than or equal to 33 kJ/mol and less than or equal to 45 kJ/mol; and (b) a number-average relaxation time tn measured at 190° C. greater than or equal to 2 ms and less than or equal to 15 ms, wherein said number-average relaxation time is calculated using zero-shear viscosity ?0 at 190° C. in kPa·s and plateau modulus Formula (I) at 190° C. in MPa, according to Formula (II). Film made from the ethylene interpolymer product may be characterized by a hot-tack peak strength from about 12 N to about 20 N and a lubricated puncture resistance from about 100 J/mm to about 150 J/mm.

Abstract: A system and method for coproduction in the production of ethylene, including contacting ethane with an oxidative dehydrogenation (ODH) catalyst in presence of oxygen in a first reactor to dehydrogenate ethane to ethylene, and contacting a first-reactor effluent with an ODH catalyst in a second reactor to form ethanol and acetaldehyde.

Abstract: A polyethylene composition including a first polyethylene which is an ethylene copolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution Mw/Mn of <2.3, a second polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 50,000 to 200,000 and a molecular weight distribution Mw/Mn of <2.3, and a third polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 70,000 to 200,000 and a molecular weight distribution Mw/Mn of <2.3, where the first polyethylene has more short chain branching than the second polyethylene or the third polyethylene.

Abstract: This disclosure relates to ethylene interpolymer products comprising a Melt Flow-Intrinsic Viscosity Index value, MFIVI, of from ?0.05 to ?0.80; a first derivative of a melt flow distribution function, formula (I) of form ??1.85 to ??1.51; an unsaturation ratio, UR, of from >0.06 to ?0.60; and a residual catalytic metal of from ?0.03 to ?5 ppm of hafnium. Ethylene interpolymer products comprise at least two ethylene interpolymers. Ethylene interpolymer products are characterized by a melt index (I2) from 0.3 to 500 dg/minute, a density from 0.855 to 0.975 g/cc and from 0 to 25 mole percent of one or more a-olefins. Ethylene interpolymer products have polydispersity, Mw/Mn, from 1.7 to 25; and CDBI50 values from 1% to 98%. These ethylene interpolymer products have utility in flexible and rigid applications.

Abstract: Provided in this disclosure are catalyst compositions. The catalyst compositions include an oxidative dehydrogenation catalyst that includes a mixed metal oxide having the empirical formula: Mo1.0V0.12-0.49Te0.05-0.17Nb0.10-0.20AlcOd wherein c is from 0 to 2.0 and d is a number to satisfy the valence of the oxide. The compositions are at least 40 wt. % amorphous as measured by XRD. The disclosure also provides methods of making the compositions.

Abstract: Provided in this disclosure is an ethylene interpolymer composition. The ethylene interpolymer composition includes a first ethylene interpolymer, a second ethylene interpolymer, and a third ethylene interpolymer. Further, the ethylene interpolymer composition has a density of at least 0.945 g/cm3; an environmental stress crack resistance (ESCR), measured according to ASTM D1693, Condition B, 10% IGEPAL CO-360, of at least 90 hours; and an Izod impact strength of at least 80 J/m, as measured according to ASTM D256.

Abstract: Mixed metal oxide catalysts having an amorphous content of not less than 40 wt. % are prepared by calcining the catalyst precursor fully or partially enclosed by a porous material having a melting temperature greater than 600° C. in an inert container including heating the catalyst precursor at a rate from 0.5 to 10° C. per minute from room temperature to a temperature from 370° C. to 540° C. under a stream of pre heated gas chosen from steam and inert gas and mixtures thereof at a pressure of greater than or equal to 1 psig having a temperature from 300° C. to 540° C. and holding the catalyst precursor at that temperature for at least 2 hours and cooling the catalyst precursor to room temperature.

Abstract: A medium pressure solution phase polymerization process is provided in which the amount of long chain branching present in an ethylene/1-octene copolymer is controlled with a bridged hafnocene polymerization catalyst in the presence of different polymerization process conditions.

Abstract: The present disclosure describes bottle closure assemblies which are made at least in part with a polyethylene composition having good processability, good organoleptic properties and good dimensional stability. The bottle closure assembly includes a cap portion, an elongated tether portion, and a retaining means portion. The retaining means portions engages a bottle neck or an upper portion of a bottle. The elongated tether portion connects at least one point on the cap portion to at least one point on the retaining means portion so as to prevent loss of the cap portion from a bottle.

Abstract: Provided in this disclosure are zirconium and hafnium complexes that contain 1) a cyclopentadienyl ligand; 2) an adamantyl-phosphinimine ligand; and 3) at least one other ligand. The use of such a complex, in combination with an activator, as an olefin polymerization catalyst is demonstrated. The catalysts are effective for the copolymerization of ethylene with an alpha olefin (such as 1-butene, 1-hexene, or 1-octene).

Abstract: A polyethylene homopolymer composition having a weight average molecular weight Mw, of from 75,000 to 95,000; an Mz of from 200,000 to 325,000; a molecular weight distribution Mw/Mn of from 6 to 12 and a melt index, I2 of from 1.5 to 2.8 grams per 10 minutes can be used to prepare films having a good balance of optical properties and resistance to moisture transmission.

Abstract: An ethylene copolymer comprising ethylene and at least one alpha olefin having from 4 to 8 carbon atoms has a density f from 0.940 to 0.960 g/cm3, a molecular weight distribution, Mw/Mn of from 9 to 12, and a Z-average molecular weight, Mz of greater than 500,000. The ethylene copolymer is made in a multi-zone reactor system under solution phase polymerization conditions and is useful in the preparation of biaxially oriented polyethylene (BOPE) films.

Abstract: This disclosure relates to ethylene interpolymer compositions and films prepared therefrom. Specifically: ethylene interpolymer products having: a dimensionless Long Chain Branching Factor, LCBF, greater than or equal to 0.001; a residual catalytic metal of from ?0.03 to ?5 ppm of hafnium, and; a dimensionless unsaturation ratio, UR, of from ??0.40 to ?0.06, wherein UR is defined by the following relationship; UR=(SCU?TU)/TU, where SCU is the amount of a side chain unsaturation per 100 carbons and TU is amount of a terminal unsaturation per 100 carbons, in said ethylene interpolymer product. The disclosed ethylene interpolymer products have a melt index from about 0.3 to about 500 dg/minute, a density from about 0.855 to about 0.975 g/cc, a polydispersity (Mw/Mn) from about 1.7 to about 25 and a Composition Distribution Breadth Index (CDBI50) from about 1% to about 98%.

Abstract: In the manufacture of extruded polymers there are a number of surface defects referred to as sharkskin, snakeskin and orange peel which all generally relate to the rheology of the polymer melt. A severe form of surface defect is “melt fracture” which is believed to result when the shear rate at the surface of the polymer is sufficiently high that the surface of the polymer begins to fracture. That is, there is a slippage of the surface of the extruded polymer relative to the body of the polymer melt. The surface generally can't flow fast enough to keep up with the body of the extrudate and a fracture in the melt occurs generally resulting in a severe loss of surface properties for the extrudate. A polymer extension process is disclosed wherein these undesirable surface defects are eliminated.

Abstract: Multilayer Films have a first skin layer that is prepared from a high density polyethylene and a second skin layer (also referred to as the sealant layer) that is prepared from a linear low density polyethylene (LLDPE) having a density of from 0.90 to 0.92 g/cc and a Dilution Index, Yd, of greater than 0°. Seals can be prepared by placing two pieces of this film against each other such that the sealant layers are in contact with each other, then applying heat to at least one high density skin layer such that heat is transmitted/conducted through the multilayer film in a sufficient amount to melt the sealant layer and form a seal. The use of LLDPE having a Dilution Index of greater than 0° has been found to improve the sealing performance of multilayer films in comparison to multilayer films where the sealant layer is a conventional LLDPE having a Dilution Index of less than 0°.