Abstract: To determine the carbon black distribution two measurements of spectral intensities of separately produced plasmas are carried out with different time delays relative to a particular laser pulse, the time delay for the second measurement for determining the spectral line intensities of a reference element carbon (I.sub.C,) and at least one analysis element (I.sub.A.n,) being smaller than for the first measurement; for determining the spectral line intensities of the reference element (I.sub.C) and the other analysis elements (I.sub.A.n).Evaluation of the measurements is performed by reference to calibration information based on reference measurements, which information shows the magnitude of the concentration ratio of the other analysis elements or the at least one analysis element to the reference element (c.sub.A.n /c.sub.C or c.sub.A.n /c.sub.R) as a function of the appurtenant intensity ratio values.