Abstract: Disclosed is a combustion method in which heated flue gas heats a regenerator through which a mixture of fuel and flue gas containing NOx is passed to undergo endothermic reactions that produce syngas and destroy NOx.

Abstract: A novel system for operating a hydrogen storage cavern is provided. Particularly, the system involves storing high purity hydrogen into a salt cavern without seepage or leakage of the stored hydrogen through the salt cavern walls, by confining the high purity hydrogen gas within the storage cavern under certain pressure conditions.

Abstract: A valve integrated pressure regulator (VIPR) device is provided that includes a gas flow valve arrangement, a shroud and digital gauge display that can be attached or coupled to a gas cylinder, and which can monitor the amount or pressure of the gas in the gas cylinder. Features of the disclosed valve integrated pressure regulator device include an electronic control, electronic alarm and the electronic display that are powered by a battery that may be disposed within the shroud. The battery and/or electronic control are accessible via a removable access panel disposed on the front surface of the shroud.

Abstract: A method and apparatus for argon recovery in which an impure argon stream is separated from air within a cryogenic air separation unit having an argon rejection column and a reflux type argon condenser disposed internally within the lower pressure column. An impure argon stream is subsequently recovered from the argon rejection column and purified within an integrated adsorbent based argon refining and purification subsystem to produce product grade argon. The waste stream from the adsorbent based argon refining and purification subsystem is recycled back to the argon rejection column so as to improve the argon recovery.

Abstract: Disclosed are articles useful as the body of a container for containing gas under pressure, and containers which comprise the articles to which are affixed valves to control the flow of gas out of the container, wherein the articles comprise a hollow container body, having an external surface and having an opening through which gas can enter or leave the interior of the hollow container body; optionally but preferably a layer of fiber-reinforced polymer around the exterior of the container body, and an external layer of elastomer around and sealed to the external surface of the layer of fiber-reinforced polymer if present or else to the cylinder body.

Abstract: The present invention relates to decreasing the amount of diluent needed to convert a heavy oil to a bitumen product that can be transported by pipeline. More specifically, the invention relates to a method and apparatus for partially upgrading heavy oil into a lower viscosity bitumen product.

Abstract: A method and backup system for backing up a supply oxygen in an air separation plant in which during normal operation, a stream of oxygen-rich liquid is pumped through a main flow path, extending from a surge tank to a heat exchanger, to deliver an oxygen product. The surge tank receives the oxygen-rich liquid from a bottom region of the lower pressure column of the plant. Additionally, during normal operations, a stream of the oxygen-rich liquid is also introduced to a reserve storage tank through a backup flow path. During a transient operation, where the air separation plant has ceased operation, the surge tank is isolated and liquid is pumped from the surge tank through an auxiliary flow path to an auxiliary vaporizer to continue the supply of the oxygen product and the surge tank is replenished with oxygen-rich liquid previously stored in the reserve storage tank.

Abstract: A method of operating an oxygen transport membrane based reforming system employing one or more packs of thermally coupled panels of reformer tubes and oxygen transport membrane (“OTM”) reactors close to thermo-neutral point is provided. The method produces syngas by converting a hydrocarbon-containing feed, such as natural gas in the reformer tubes of a pack by endothermic steam reforming reactions. The heat required for endothermic reforming reactions is provided by exothermic oxidizing reactions occurring inside the OTM reactors of the pack. At a thermo-neutral point the heat released by exothermic reactions matches the heat required to support endothermic reactions and heat losses in the pack. The method modulates the flow rate of hydrocarbon-containing feed and/or steam-to-carbon ratio of the combined feed to the pack to maintain the surface temperature of oxygen transport membrane reactors below a target maximum temperature.

Abstract: Disclosed are methods and apparatus for forming frozen food products, especially frozen foamed food products wherein the products contain bubbles having a reduced average size preferably in a narrow size range or contain ice crystals having reduced size.

Abstract: A method and apparatus for separating air in which production of the liquid products can be selectively varied between high and low production rates by varying the pressure ratio across a turboexpander used in imparting refrigeration with the use of a branched flow path. The branched flow path has a system of valves to selectively and gradually introduce a compressed refrigerant air stream into either a booster compressor branch having a booster compressor to increase the pressure ratio during high modes of liquid production or a bypass branch that bypasses the booster compressor to decrease the pressure ratio during low modes of liquid production. A recycle branch is connected to the booster compressor branch to allow compressed air to be independently recycled from the outlet to the inlet of the booster compressor during turndown from the high to the low liquid mode of liquid production to prevent surge.

Abstract: Operation of a thermochemical regenerator combustion system in which fuel is fed with furnace flue gas into the regenerators to reduce the oxygen content and optionally to establish a reducing atmosphere in both cycles in which the regenerators operate.

Abstract: In a cyclic adsorptive gas purification process, an impurity laden adsorbent is regenerated by exposing it first to an unheated gas for a pre-determined time period to desorb at least some of the impurity, followed by heating the adsorbent using a flowing stream of a heated gas to desorb the remaining impurities over another pre-determined time period, further followed by cooling of the adsorbent using a flowing stream of gas for yet another pre-determined time period to make it ready for repeating the adsorptive cycle. Introducing an unheated purge stream reduces the energy requirements for the regeneration step compared to a traditional TSA process.

Abstract: A system and method for cryogenic purification of a hydrogen, nitrogen, methane and argon containing feed stream to produce a methane free, hydrogen and nitrogen containing synthesis gas and a methane rich fuel gas, as well as to recover an argon product stream, excess hydrogen, and excess nitrogen is provided. The disclosed system and method are particularly useful as an integrated cryogenic purifier in an ammonia synthesis process in an ammonia plant. The excess nitrogen is a nitrogen stream substantially free of methane and hydrogen that can be used in other parts of the plant, recovered as a gaseous nitrogen product and/or liquefied to produce a liquid nitrogen product.

Abstract: A novel composition, system and method for improving beam current during boron ion implantation are provided. In a preferred aspect, the boron ion implant process involves utilizing B2H6, 11BF3 and H2 at specific ranges of concentrations. The B2H6 is selected to have an ionization cross-section higher than that of the BF3 at an operating arc voltage of an ion source utilized during generation and implantation of active hydrogen ions species. The hydrogen allows higher levels of B2H6 to be introduced into the BF3 without reduction in F ion scavenging. The active boron ions produce an improved beam current characterized by maintaining or increasing the beam current level without incurring degradation of the ion source when compared to a beam current generated from conventional boron precursor materials.

Abstract: An argon reflux condensation system and method in which a plurality of once-through condensers are connected to an argon column of an air separation plant to condense argon-rich vapor streams for production of reflux to the argon column. Condensation of the argon-rich vapor streams is brought about through indirect heat exchange with crude liquid oxygen streams that partially vaporize and are introduced into a lower pressure column of the plant for further refinement. The flow rate of the crude liquid oxygen streams are sensed and controlled at locations in the air separation plant where the crude liquid oxygen is in a liquid state and in proportion to the size of the once-through heat exchangers. Prior to flowing into the once-through condensers, the partially vaporized crude oxygen stream enters a phase separator which separates the crude oxygen vapor from the crude liquid oxygen.

Abstract: The present invention relates to a proppant laden fracture fluid having a Mitchell quality of at least 50% and fracturing a subterranean formation therewith.

Abstract: A system and method for argon and nitrogen extraction and liquefaction from a low-pressure tail gas of an ammonia production plant is provided. The preferred tail gas of the ammonia production plant comprises methane, nitrogen, argon, and hydrogen. The disclosed system and method provides for the methane rejection via rectification and hydrogen rejection by way of a side stripper column or phase separator. The resulting nitrogen and argon containing stream is separated and liquefied in a double column distillation system.

Abstract: A system and method for argon and nitrogen extraction from a feed stream comprising hydrogen, methane, nitrogen and argon, such as tail gas of an ammonia production plant is provided. The disclosed system and method provides for nitrogen-argon rectification and the methane rejection within a column system comprised of at least one distillation column. Nitrogen and argon are further separated and to produce liquid products. An argon stripping column arrangement is disclosed where residual argon is further removed from the methane-rich fuel gas and recycled back to the feed stream.

Abstract: A method and apparatus for argon rejection and recovery in which argon is separated from air within a cryogenic air separation plant having a divided wall argon rejection column arrangement and condensed using an argon condenser disposed internally within the lower pressure column. The divided wall argon rejection column arrangement may be an annular arrangement or a side-by-side arrangement (i.e. segmented or planar configuration). The resulting argon stream is subsequently rejected or recovered and optionally purified within an integrated adsorbent based argon refining and purification subsystem to produce product grade argon.

Abstract: An argon reflux condensation system and method in which a plurality of once-through heat exchangers are connected to an argon column of an air separation plant to condense argon-rich vapor streams for production of reflux to the argon column. Condensation of the argon-rich vapor streams is brought about through indirect heat exchange with crude liquid oxygen streams that partially vaporize and are introduced into a lower pressure column of the plant for further refinement. The flow rate of the crude liquid oxygen streams are sensed and controlled at locations in the plant where the crude liquid oxygen is in a liquid state and in proportion to the size of the once-through heat exchangers. Feed stream flow rate to the argon column is controlled in response to air flow rate to the plant and product flow rate is controlled in response to the feed stream flow rate to the argon column.