Patents Assigned to Repsol S.A.
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Patent number: 11912812Abstract: The present invention relates to new stable modified polymer polyol dispersions. The modified polymer polyols of the present invention comprise at least one polyol and a stable dispersion of polymeric particles in the at least one polyol. There are also disclosed processes for the preparation of the herein described modified polymer polyols, and processes for preparing polyurethane materials containing them.Type: GrantFiled: December 17, 2020Date of Patent: February 27, 2024Assignee: REPSOL, S.A.Inventors: César Muñoz De Diego, José Román Galdámez Peña, Victoria Isabel Blasco Garcés, Olivier Lemoine
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Publication number: 20240059977Abstract: The present invention relates to a process for treating a plastics pyrolysis oil, comprising: a) hydrogenation of said feedstock in the presence of at least hydrogen and of at least one hydrogenation catalyst at an average temperature of between 140 and 340° C., the outlet temperature of step a) being at least 15° C. higher than the inlet temperature of step a), to obtain a hydrogenated effluent; b) hydrotreatment of said hydrogenated effluent in the presence of at least hydrogen and of at least one hydrotreatment catalyst, to obtain a hydrotreated effluent, the average temperature of step b) being higher than the average temperature of step a); c) separation of the hydrotreated effluent in the presence of an aqueous stream, at a temperature of between 50 and 370° C., to obtain at least one gaseous effluent, an aqueous liquid effluent and a hydrocarbon-based liquid effluent.Type: ApplicationFiled: December 21, 2021Publication date: February 22, 2024Applicants: IFP ENERGIES NOUVELLES, REPSOL S.A.Inventors: Wilfried WEISS, Dominique DECOTTIGNIES, Jérôme BONNARDOT, Iñigo RIBAS SANGÜESA, Lidia ESCUDERO CASTEJON
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Patent number: 11885032Abstract: The present invention relates to an electrochemical device and a method for operating the electrochemical device for inducing specific behaviours in its chemical kinetics by supplying externally selected random (stochastic) voltage perturbations while the electrochemical system is operating in a non-oscillatory regime.Type: GrantFiled: December 19, 2018Date of Patent: January 30, 2024Assignee: REPSOL, S.A.Inventors: María Dolores Hernández Alonso, Valentín Ruíz Santa Quiteria, Juan Pérez Mercader
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Publication number: 20230287283Abstract: The present invention relates to a process for treating a plastics pyrolysis oil, comprising: a) the selective hydrogenation of said feedstock to obtain a hydrogenated effluent; b) hydrotreatment of said hydrogenated effluent to obtain a hydrotreatment effluent; c) a first step of hydrocracking of said hydrotreated effluent to obtain a first hydrocracked effluent; d) separation of the hydrocracked effluent in the presence of an aqueous stream, to obtain a gaseous effluent, an aqueous liquid effluent and a hydrocarbon-based liquid effluent; e) fractionation of the hydrocarbon-based liquid effluent to obtain at least one gas stream and at least one naphtha cut and a heavier cut; f) a second step of hydrocracking of the heavier cut to obtain a second hydrocracked effluent; g) recycling of at least a portion of said second hydrocracked effluent into the separation step d).Type: ApplicationFiled: July 26, 2021Publication date: September 14, 2023Applicants: IFP Energies nouvelles, REPSOL S.A.Inventors: Wilfried WEISS, Jérôme BONNARDOT, Iñigo RIBAS SANGÜESA
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Publication number: 20230272292Abstract: The present invention relates to a process for treating a plastics pyrolysis oil, comprising: a) selective hydrogenation of said feedstock in the presence of at least hydrogen and of at least one selective hydrogenation catalyst; b) hydrotreatment of said hydrogenated effluent in the presence of at least hydrogen and of at least one hydrotreatment catalyst, to obtain a hydrotreated effluent; c) hydrocracking of said hydrotreated effluent in the presence of at least hydrogen and of at least one hydrocracking catalyst, to obtain a hydrocracked effluent; d) separation of the hydrocracked effluent in the presence of an aqueous stream, at a temperature of between 50 and 370° C., to obtain at least one gaseous effluent, an aqueous liquid effluent and a hydrocarbon-based liquid effluent.Type: ApplicationFiled: July 26, 2021Publication date: August 31, 2023Applicants: IFP Energies nouvelles, REPSOL S.A.Inventors: Wilfried WEISS, Jérôme BONNARDOT, Iñigo RIBAS SANGÜESA
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Patent number: 11685694Abstract: Disclosed is a rapid, reproducible solution-based method to synthesize solid sodium ion-conductive materials. The method includes: (a) forming an aqueous mixture of (i) at least one sodium salt, and (ii) at least one metal oxide; (b) adding at least one phosphorous precursor as a neutralizing agent into the mixture; (c) concentrating the mixture to form a paste; (d) calcining or removing liquid from the paste to form a solid; and (e) sintering the solid at a high temperature to form a dense, non-porous, sodium ion-conductive material. Solid sodium ion-conductive materials have electrochemical applications, including use as solid electrolytes for batteries.Type: GrantFiled: November 16, 2019Date of Patent: June 27, 2023Assignees: International Business Machines Corporation, Repsol, S.A.Inventors: Younes Ansari, Young-hye Na, Khanh Nguyen, Francisco José Alía Moreno-Ortiz
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Patent number: 11682807Abstract: A metal-oxygen battery includes a catholyte with: (i) carbon black; and, (ii) at least one of graphite and graphene, wherein said at least one of graphite and graphene constitutes between 0 wt % and 30 wt % of the total carbon in the catholyte.Type: GrantFiled: November 19, 2019Date of Patent: June 20, 2023Assignees: International Business Machines Corporation, Repsol, S.A.Inventors: Younes Ansari, Young-Hye Na, Francisco José Alia Moreno-Ortiz
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Patent number: 11629590Abstract: A method is described for estimating either flowback or the reservoir fluids production rate from either one individual inlet or the contribution from several inlets separated by intervals in a wellbore located in an oil and/or gas reservoir. The wellbore may include a casing with a plurality of magnetic irregularity elements, such as casing collars, to generate magnetic perturbations within the casing. In the method, one or more sensor elements are delivered in such a way that the flow drags them while the sensor elements record in time the magnetic perturbations generated by the magnetic irregularity elements. The known location of the magnetic irregularity elements and the reading of perturbations enables estimating the velocity of the sensor element(s) along the path direction of the casing, to determine the velocity of the fluid.Type: GrantFiled: April 5, 2019Date of Patent: April 18, 2023Assignee: REPSOL, S.A.Inventors: Ricardo Cesar Bezerra De Melo, Ramy Nabil Eid
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Patent number: 11519897Abstract: The present invention is related to computer implemented method for characterizing a target fluid of a hydrocarbon reservoir under uncertainty providing a set of fluid properties from a limited amount of information.Type: GrantFiled: March 27, 2018Date of Patent: December 6, 2022Assignee: Repsol, S.A.Inventors: José Luís Peña Díez, Daniel Merino García, Verónica Benito Iglesias, Paula Sanz Sanz
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Patent number: 11414988Abstract: The present invention relates to a method of estimating the region of damage due to collapse in the wall of a well during the drilling operation, normally using drilling fluid, where said well can, for example, be intended either for the injection or else for the production of a gas or oil reservoir. Other uses can be found in mining and in civil engineering work. This method is characterized by a set of analytical steps that allow establishing, for example, optimal drilling parameters so as to allow the fastest possible drilling speed that is also safe enough to allow is charging the collapse material without jamming the drilling tool. This method likewise allows assessing both the width and depth of damage in the wall of the well.Type: GrantFiled: April 3, 2018Date of Patent: August 16, 2022Assignee: REPSOL, S.A.Inventors: Jose Alvarellos Iglesias, José María Segura Serra, Marta Dueñas Díez, Enric Ibañez Martinez, Lakshmikantha Mookanahallipatna Ramasesha, Almudena Díaz Aguado
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Patent number: 11319401Abstract: The present invention refers to a method for the preparation of a polymer polyol which comprises: (i) preparing an intermediate in a first reactor by polymerizing a mixture comprising: (a) a base polyol in an amount from 60 to 100 wt % of the total amount of base polyol, (b) at least one ethylenically unsaturated monomer, (c) an acylperoxide radical initiator in an amount from 50 to 90 wt % of the total amount of acylperoxide radical initiator, and (d) a preformed stabilizer in an amount from 70 to 100 wt % of the total amount of preformed stabilizer or a macromer in an amount of from 70 to 100 wt % of the total amount of macromer; (ii) polymerizing in a second reactor a mixture comprising the intermediate prepared in step (i), the balance acylperoxide radical initiator proportion, the balance preformed stabilizer or macromer proportion and the balance base polyol proportion; wherein the at least one ethylenically unsaturated monomer is added only to the first reactor.Type: GrantFiled: February 24, 2021Date of Patent: May 3, 2022Assignee: REPSOL, S.A.Inventors: Juan Pedro Pérez Valencia, José Antonio Carazo Angulo
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Patent number: 11137514Abstract: One aspect includes a method for determining a drilling plan for new wells in a reservoir. The method includes categorizing the new wells into at least a first new well and a second new well, such that a drilling location for at least the first new well must be determined imminently, but a drilling location for at least the second new well can be determined at a later time. The method further includes determining potential drilling locations for the second new well, determining the drilling location for the first new well based at least in part on the determined potential drilling locations for the second new well, and outputting the drilling plan comprising the determined drilling location for the first new well and the determined potential drilling locations for the second new well.Type: GrantFiled: January 15, 2018Date of Patent: October 5, 2021Assignees: International Business Machines Corporation, REPSOL, S.A.Inventors: David Echeverria Ciaurri, Sonia Mariette Embid Droz, Eduardo Goncalves Dias De Barros, Ruben Rodriguez Torrado
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Patent number: 11119248Abstract: The present invention is related to a method for estimating the fractured volume in a reservoir domain, said fractured volume generated by injecting a high pressure fluid into the reservoir domain. The high pressure fluid generates new fractures allowing a more effective drainage of porous rocks, generally identified as geological material, containing oil or gas. As a result, the effective reservoir volume increases. According to embodiments of the invention, the method provides a dynamic estimation of the fractured volume taking into account the evolution of the rock and the fractures. In other embodiment, the evolution of the fractured volume is estimated by generating an envelope surrounding the induced fractures allowing a better estimation of the fractured volume.Type: GrantFiled: August 20, 2018Date of Patent: September 14, 2021Assignees: REPSOL, S.A., UNIVERSIDAD POLITÉCNICA DE CATALUÑAInventors: Lakshmikantha Mookanahallipatna Ramasesha, José Alvarellos Iglesias, José María Segura Serra, Ignacio Carol Vilarasau, Daniel Garolera Vinent, Pere Prat Catalan
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Publication number: 20210043939Abstract: It is provided a lithium metal anode coated with a protective monolayer disposed on at least a portion of the lithium metal anode, the protective monolayer consisting of a polymer; at least one inorganic particle selected from the group consisting of Al2O3, MnO, MnO2, SiO2, TiO2, ZnO, ZrO2, Fe2O3, CuO, a silicate, an aluminosilicate, a borosilicate, and an oxysalt, or any one of the mentioned inorganic particles which are functionalized; wherein the protective monolayer has a thickness from 0.01 to 10 ?m, the inorganic particles have an average diameter from 1 to 500 nm, and the at least one inorganic particle is in an amount of 0.01 to 30 wt % related to the amount of polymer. It is also provided a method for the preparation of the protected anode, as well as a lithium metal battery comprising it.Type: ApplicationFiled: February 4, 2019Publication date: February 11, 2021Applicant: REPSOL, S.A.Inventors: Rodrigo PARIS ESCRIBANO, Juan NICOLÁS AGUADO, Eneko AZACETA MUÑOZ, José Alberto BLAZQUEZ MARTÍN, Olatz LEONET BOUBETA, Idoia URDAMPILLETA GONZALEZ, Oscar MIGUEL CRESPO
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Patent number: 10903018Abstract: A photoelectrode for a photoelectrochemical cell is disclosed. The photoelectrode comprises a back-contact solar cell comprising emitter and collector contacts being spaced apart by first openings. The emitter and collector contacts are respectively collected in an emitter busbar and a collector busbar. The photoelectrode further comprises a contact passivation layer to separate the emitter and collector contacts from the electrolyte when in use. The contact passivation layer further comprises second openings in correspondence with the first openings. The photoelectrode further comprises a resin layer covering the openings and a portion of the contact passivation layer such that in use only charge carriers from the emitter contacts traverse the contact passivation layer in its way to the electrolyte while charge carriers from the collector contacts are collected in the collector busbar. An electrocatalyst layer is further provided covering respectively the resin layer and/or the contact passivation layer.Type: GrantFiled: December 22, 2016Date of Patent: January 26, 2021Assignees: REPSOL, S.A., ENAGAS SERVICES SOLUTIONS, S.L.U.Inventors: German Penelas Perez, Maria Dolores Hernandez Alonso, Teresa Andreu Arbella, Juan Ramon Morante Lleonart, Carles Ros Figueras, Nina Magali Carretero Gonzalez, Eric Calle Martin, Pablo Ortega Villasclaras, Ramon Alcubilla Gonzalez
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Patent number: 10894861Abstract: A polyether carbonate polyol with a nominal functionality of 3 or more includes an equivalent molecular weight between 20,000 and 500,000 Da, and content of between 0.5 wt % and 35 wt % of CO2 based on the total weight of the polyether carbonate polyol. The polyether carbonate polyol has adhesive and impact modifying properties.Type: GrantFiled: October 18, 2017Date of Patent: January 19, 2021Assignee: REPSOL, S.A.Inventors: José Román Galdämez Peña, María Dolores Blanco Gonzälez, Sonia Segura Fernández, Laura Marín Perales, Carolina Ruiz Orta, Ana Isabel Real Guerrero, Mónica García Ruiz
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Patent number: 10870792Abstract: The present invention relates to the use of ultra-high-molecular-weight polyolefin particles as proppants for treating subterranean formations, as well as to compositions comprising said particles and to fracturing methods employing said particles.Type: GrantFiled: February 25, 2016Date of Patent: December 22, 2020Assignee: REPSOL, S.A.Inventors: Manuel López Reyes, Ricardo César Bezerra De Melo, Jacobo Canal Vila, Itziar Martínez Cebrián, Richard Llewellyn Lolley Bowen, Ana Isabel Montenegro García
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Patent number: 10794155Abstract: The invention is a method for exploiting a subterranean formation including hydrocarbons with at least one lithologic facies of the formation having undergone at least one diagenetic phase over geological times. From at least one sample of rock obtained from the formation, from measured production data relating to the formation and from a meshed representation representative of the formation, each mesh of the meshed representation is determined including at least one indicator relating to the distribution of the facies present in the mesh. The method comprises a step of history matching in which at least one of the adjustment parameters is the diagenetic state of the identified facies.Type: GrantFiled: November 29, 2017Date of Patent: October 6, 2020Assignees: IFP ENERGIES NOUVELLES, REPSOL S.A.Inventors: Mickaele Le Ravalec, Mickael Barbier, Maria Fernanda Leon Carrera, Brigitte Doligez
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Publication number: 20200270653Abstract: The invention relates to mutant thiolases capable of producing branched compounds which are considered of particular interest in industry. The invention also relates to method for obtaining said branched product.Type: ApplicationFiled: December 29, 2016Publication date: August 27, 2020Applicant: REPSOL, S.A.Inventors: Vicente BERNAL SÁNCHEZ, Pamela TORRES SALAS, Antonio MORREALE DE LEÓN, Víctor BARRERA BURGOS, María del Mar GONZÁLEZ BARROSO, Fernando LÓPEZ GALLEGO, Federico GAGO BADENAS, Pedro Alejandro SÁNCHEZ MURCIA
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Publication number: 20200233851Abstract: A resource exploitation management system, method and a computer program product therefor. A description of new geological evidence for a geological resource is received, e.g., as one or more triples describing the evidence. Keywords in the description are matched against keywords in representations in a geological resource database. Geological relations are inferred from the descriptions and matched against predefined geological relations from the geological resource database. Consistent triple matches are merged with the geological resource database. The confidence level for merged matches is updated in the geological resource database.Type: ApplicationFiled: January 17, 2019Publication date: July 23, 2020Applicants: REPSOL, S. A., International Business Machines CorporationInventors: Sonia Mariette Embid Droz, Cristina Ibanez-Llano, Giorgio De Paola, Ruben Rodriguez Torrado, Akiko Suzuki, Mustafa Canim, Yuan-Chi Chang, Robert Farrell, Sharon M. Trewin