Patents Assigned to Rhodia Chimie
  • Patent number: 8092713
    Abstract: The invention concerns a method for marking a material characterized in that it consists in incorporating into the material: either a phosphor capable of producing, following excitation, two light emissions whereof the respective wavelengths and the emission decay times are different, or several phosphors capable of producing, following excitation, a light emission whereof the wavelength and the emission decay time are different from the wavelength and emission decay time of the other or other phosphors. The material can in particular be of the paper, board, paint, textile, ink, glass or macromolecular material type.
    Type: Grant
    Filed: July 11, 2005
    Date of Patent: January 10, 2012
    Assignee: Rhodia Chimie
    Inventors: Thierry Le-Mercier, Claude Ceintrey
  • Publication number: 20110287257
    Abstract: The invention relates to a novel process for the preparation of precipitated silica which can be used as a reinforcing filler for elastomers. The invention also relates to novel precipitated silicas in the form of powder, granules or, preferably, substantially spherical beads, these silicas being characterized in that they have a BET specific surface of between 185 and 250 m2/g, a CTAB specific surface of between 180 and 240 m2/g, and a pore distribution such that the pore volume V2 made up of the pores with a diameter of between 175 and 275 ? represents less than 50% of the pore volume V1 made up of the pores with diameters of less than or equal to 400 ?, a pore volume (Vd1), made up of the pores with a diameter of less than 1 ?m, of greater than 1.65 cm3/g, a fineness value (F.V.) of between 70 and 100 ?, and a content of fines (?f), after deagglomerability with ultrasound, of at least 50%.
    Type: Application
    Filed: December 22, 2010
    Publication date: November 24, 2011
    Applicant: Rhodia Chimie
    Inventors: Yvonick Chevallier, Philippe Cochet, Patrick Fourre
  • Publication number: 20110281731
    Abstract: The invention relates to an emulsifiable concentrate comprising an active ingredient being a dinitroaniline compound, preferably selected from the group consisting of pendimethalin, trifluralin and mixtures thereof. The emulsifiable concentrate of the invention avoids crystallization at low temperature when the concentration of the active ingredient is high. Accordingly, the emulsifiable concentrate comprises a diester co-solvent having the following formula R1OOC—(CH2)n—COOR2, wherein R1 and R2, identical or different, are C1-C10, preferably C1-C6, linear or branched, alkyl, aryl, alkaryl or arylalkyl groups, and n is an average number of from 2 to 4.
    Type: Application
    Filed: June 10, 2011
    Publication date: November 17, 2011
    Applicant: Rhodia Chimie
    Inventor: Paul Oreste Gioia
  • Publication number: 20110266501
    Abstract: The invention relates to a process for the preparation of a liquid composition of an ortho-dihydroxybenzyl compound of high purity characterized in that it consists in purifying the initial ortho-dihydroxybenzyl compound by distillation and recovering the condensed ortho-dihydroxybenzyl compound in an apparatus resistant to corrosion by the latter, and then mixing it with an organic solvent in a storage tank which is lined or made of a material which does not lead to metallic pollution. The invention also relates to a liquid composition of an ortho-dihydroxybenzyl compound of high purity comprising said compound and an organic solvent of said compound obtained according to said process.
    Type: Application
    Filed: December 2, 2010
    Publication date: November 3, 2011
    Applicant: Rhodia Chimie
    Inventor: Claude Mathieu
  • Publication number: 20110263784
    Abstract: The invention relates to a novel method of preparing silicas and to highly-structured silicas having the following characteristics: a specific surface area CTAB (SCTAB) of between 40 and 525 m2g/g; a specific surface area BET (SBET) of between 45 and 550 m2g; an object size distribution width Ld ((d84?D16)/d50), which is measured by XDC particle size analysis after deagglomeration with ultrasound, of at least 0.91; and a pore-size distribution such that ratio V(d5?d50)/V(d5?d100) is at least 0.66. The invention also relates to the use of said silicas as polymer reinforcing fillers.
    Type: Application
    Filed: June 22, 2011
    Publication date: October 27, 2011
    Applicant: RHODIA CHIMIE
    Inventors: Rémi VALERO, Julien Hernandez
  • Patent number: 8039574
    Abstract: A low viscosity polyisocyanate composition containing at least one isocyanate dimer having a uretidinedione unit is prepared from a reaction medium containing at least one isocyanate monomer in which the isocyanate groups are borne by sp3 carbon atoms. The reaction medium is heated, in the absence of a dimerization catalyst, to a temperature of at least 50° C. and not more than 200° C. for a period of not more than 24 hours.
    Type: Grant
    Filed: October 10, 2003
    Date of Patent: October 18, 2011
    Assignee: Rhodia Chimie
    Inventors: Eugènie Charriere, Jean-Marie Bernard, Denis Revelant, Stéphane Randu, Michel Carlo
  • Patent number: 8030371
    Abstract: This invention is directed to single-component alkoxy silicon sealants and methods of making the sealants. The sealants are made from a masterbatch M that includes at least one organopolysiloxane A having terminal and/or pendant alkoxylated groups and at least one mineral filler B.
    Type: Grant
    Filed: February 22, 2006
    Date of Patent: October 4, 2011
    Assignee: Rhodia Chimie
    Inventor: Marc Chaussade
  • Patent number: 8030510
    Abstract: Process for preparing alkylhalosilanes are provided. The process involve reacting an alkyl halide with a solid body formed of silicon and a catalytic system.
    Type: Grant
    Filed: June 7, 2006
    Date of Patent: October 4, 2011
    Assignee: Rhodia Chimie
    Inventors: Pascale Colin, Cristina Garcia-Escomel, Jean-Claude Masteau
  • Patent number: 8012593
    Abstract: Crosslinkable liquid silicone compostions suited, on curing, for the long-lasting protective and/or applicational coating/treatment of textile substrates, for example, for imparting softness, hydrophobicity, oleophobicity, hydrophilicity or antistatic properties thereto, comprise a formulation of (a) at least one particular polyorganosiloxane (POS) resin, (B) at least one metal alkoxide and/or polyalkoxide, or combination thereof with at least one optionally alkoxylated organosilane and/or at least one organosilicon compound bearing at least one epoxy, amino, ureido, isocyanato and/or isocyanurate substituent, (C) at least one functional coreactant therefor, (D), optionally, at least one nonreactive additive and (E), also optionally, at least one auxiliary agent other than an additive (D).
    Type: Grant
    Filed: November 5, 2007
    Date of Patent: September 6, 2011
    Assignee: Rhodia Chimie
    Inventors: Martial Deruelle, Yves Giraud
  • Publication number: 20110190415
    Abstract: The invention relates to an aqueous silicone dispersion, containing one or more polyorganosiloxanes (POSs) intended to be crosslinked or having been crosslinked by elimination of water or alcohol, according to a polycondensation mechanism. The present invention also relates to methods for preparing aqueous silicone emulsions and dispersions.
    Type: Application
    Filed: March 28, 2011
    Publication date: August 4, 2011
    Applicant: RHODIA CHIMIE
    Inventors: Nadia MARTIN, Martial DERUELLE, Patricia BEURDELEY
  • Patent number: 7985390
    Abstract: The invention relates to hydrotalcite intercalated by precipitated silica, and to the use thereof as a charge in a polymer composition. The invention also relates to polymer compositions comprising one such charge, and to finished articles based on such compositions.
    Type: Grant
    Filed: December 22, 2004
    Date of Patent: July 26, 2011
    Assignee: Rhodia Chimie
    Inventors: Michel Foulon, Laurence Stelandre
  • Patent number: 7972705
    Abstract: Silicone coating on various soft supports, for instance textiles, made of synthetic polymers (polyamide, polyester) provides an efficient method for producing water impermeable and water permeable coatings, on soft supports, said method enabling to improve permeability to water vapor of the silicones while preserving impermeability to water. The inventive method enabling this consists mainly in: coating one of the surfaces of the support with a film formed by an invert water-in-oil silicone emulsion comprising a continuous oily silicone phase phi s, crosslinkable into elastomer and including a polyorganosiloxane (POS) A crosslinkable by addition polymerization, by cationic process or free-radical process; optionally a crosslinking organosilicon compound B; and optionally at least a catalyst C; an aqueous phase phi a; a stabilizing agent; and in ensuring crosslinking of the silicone phase phi s and elimination of water.
    Type: Grant
    Filed: February 4, 2008
    Date of Patent: July 5, 2011
    Assignee: Rhodia Chimie
    Inventors: Paul Branlard, Martial Deruelle, Yves Giraud, Nadia Martin
  • Patent number: 7968005
    Abstract: The inventive white-light emitting diode is characterized in that it comprises a source emitting radiation whose wavelength band ranges from 370 to 420 nm, a first blue and red-light emitting phosphor of formula Ba3(1-x)Eu3xMg1-yMnySi2O8 (1), wherein 0 < x 0,3 and 0 < y 0,3 and a second green-light emitting phosphor. In another embodiment, said diode comprises the same source and a single phosphor whose chemical composition is Ba3(1-x)Eu3xMg1-yMnySi2O8, wherein 0 < x 0,3 et 0 < y 0,3 and which is embodied in the form of a mixture of at least Ba2SiO4, Ba2MgSi2O7 and Ba3MgSi2O8 phases. The inventive diode can be used for a lighting device.
    Type: Grant
    Filed: April 6, 2005
    Date of Patent: June 28, 2011
    Assignee: Rhodia Chimie
    Inventors: Claude Ceintrey, Thierry Le-Mercier, Etienne Wortham
  • Patent number: 7943058
    Abstract: Tagged scale-inhibiting polymers, compositions comprised thereof and preventing or controlling scale formation therewith, the tagging units being units deriving from a monomer having the formula X2C?CYY? wherein X is a hydrogen atom, or a C1-C4 alkyl radical, Y is a hydrogen atom or a C1-C4 alkyl radical, Y? is a radical having formula -L-Arom, wherein L is a covalent bond or a divalent organic linking group optionally comprising heteroatoms, and Arom is a group comprising at least two conjugated aromatic rings, said rings comprising conjugated carbon atoms, and, linked to said carbon atoms, hydrogen atoms or other substituents.
    Type: Grant
    Filed: June 25, 2004
    Date of Patent: May 17, 2011
    Assignee: Rhodia Chimie
    Inventors: Emma Hills, Pascal Chapon
  • Patent number: 7943747
    Abstract: Functionalized organosilicon compounds comprising at least one activated azo group of formula (I): [(G0)3SiO1/2]m [(G0)2SiO2/2]n [G0SiO3/2]o [SiO4/2]p [(G2)a(G1)a?(Z-CO—HN?NH—CO-A)SiO(3-a-a?)/2], for example a mixture of silane species of formula (ia): (C2H5O)3Si—(CH2)3—NH—CO—N?N—COOC2H3; with siloxane species of formulae: (2i.1a): [(CH3)3SiO1/2] [(C2H5O)2 {(CH2)3—NH—CO—N?N—COOC2H5} SiO2/2] and (2i.2a): [(CH3)3SiO1/2]2 [(C2H5O) {(CH2)3—NH—CO—N?N—COOC2H5} SiO2/2], are prepared from at least one hydrazino precursor (II) (—HN—NH—) of compound (I), by oxidizing the precursor (II) into an azo group for the compound (I) utilizing at least one oxidizing agent (Ox) and at least one vase (B) and also a supplementary reagent selected from among silanes of formula (III): (G DEG)4-p1Si (G2?)p1 [for example, (CH3)3(C2HSO)Si].
    Type: Grant
    Filed: May 17, 2006
    Date of Patent: May 17, 2011
    Assignee: Rhodia Chimie
    Inventor: Sebastien Sterin
  • Publication number: 20110105780
    Abstract: The invention concerns the preparation of sulphur-containing organosilicic compounds of general formula (I) wherein, for example: R1?C1-C15 alkyl; R2 and R3?C1-C6 alkyl; in a mean number ranging from 1.5±0.1 to 5±0.1. Said preparation is carried out by performing successively the following steps (a), (b) and (c): (a) hydrosilylation of the type: R2R3HSi-Hal+CH2?CH—CH2-Hal}Hal-R2R3Si—(CH2)3Hal; (b) alcoholysis of the type: Hal-R2R3Si—(CH2)3-Hal+R1—OH}R?O—R2R3Si—(CH2)3Hal; (c) sulphidization of the type: R?O—R2R3Si—(CH2)3Hal+M2Sx} compound of formula (I); with Hal=a halogen atom and M=alkali metal.
    Type: Application
    Filed: December 6, 2002
    Publication date: May 5, 2011
    Applicant: RHODIA CHIMIE
    Inventors: Nathalie Guennouni, Virginie Pevere, Bernard Vogin
  • Patent number: 7935386
    Abstract: An aqueous polyorganosiloxane (POS) emulsion which can easily be deposited on/applied to a fibrous substrate at high speed and at limited deposition rates, for example less than 40 g/m2. The emulsion contains (A) a POS with ?Si-vinyl units, (B) a POS with ?SiH units, (C) an adhesion promoter, (D) a catalyst, (E) at least one surfactant, (F) optionally a POS resin with ?Si-vinyl units, (G) optionally a crosslinking inhibitor, (H) optionally a pH fixing agent, (I) optionally a formulating additive, (J) optionally a filler, and (K) water. Adhesion promoter (C) is selected from protective hydrocolloids, hydroxylated silanes and/or POS carrying at least one hydroxyl group and at least one salified amino group per molecule, and mixtures thereof, and is present in the range from 0.005 to 10% by weight, based on the silicone phase. Also disclosed is the corresponding coating process and the coated substrate.
    Type: Grant
    Filed: February 1, 2008
    Date of Patent: May 3, 2011
    Assignee: Rhodia Chimie
    Inventors: Laurent Dumont, Michel Feder, Francis Lafaysse, Sylvie Robelin
  • Patent number: 7923428
    Abstract: Composition for cleaning or rinsing hard surfaces in an aqueous or aqueous/alcoholic medium comprising at least one polybetaine for contributing to said surfaces antideposition and/or antiadhesion properties with regard to soiling substances capable of being deposited on said surface.
    Type: Grant
    Filed: December 19, 2003
    Date of Patent: April 12, 2011
    Assignee: Rhodia Chimie
    Inventors: Cédric Geffroy, Ian Harrison, Marie-Pierre Labeau
  • Patent number: 7915403
    Abstract: Lactams, notably ?-caprolactam, are prepared from alkyl cyanovalerates, themselves obtained from unsaturated nitrile compounds, by contacting same, in gaseous state, with hydrogen in the presence of hydrogenation/cyclization catalysts, and then condensing the gas stream thus formed, without intermediate separation of any alkyl aminocaproate, and recovering lactam produced therefrom.
    Type: Grant
    Filed: February 14, 2006
    Date of Patent: March 29, 2011
    Assignee: Rhodia Chimie
    Inventor: Philippe LeConte
  • Patent number: 7892507
    Abstract: The processing of gases, in particular the exhaust gas of an internal combustion/diesel engine, entails catalytically oxidizing the carbon monoxide and hydrocarbons contained therein in an oxygen-rich medium, in the presence of a metal oxidation catalyst that includes a silica-containing zirconia support.
    Type: Grant
    Filed: June 27, 2006
    Date of Patent: February 22, 2011
    Assignee: Rhodia Chimie
    Inventors: Emmanuel Rohart, Stéphan Verdier, Aimin Huang