Patents Assigned to Rhovyl
  • Patent number: 5068113
    Abstract: The fibrous polymeric material based on polyvinyl chloride contains at least one antiseptic mercury derivative distributed in its polymeric structure in the form of a substantially molecular and practically non-releasable dispersion.The preferred mercury derivatives have the following general formula: ##STR1## in which Y is H or HgX. If the concentration of the derivative is equal to at least 0.5% by weight, relative to the chlorofiber, the latter has a permanent antiseptic character.This material is obtained by incorporating the above-mentioned derivative into the collodion when the chlorofiber is spun.
    Type: Grant
    Filed: September 20, 1989
    Date of Patent: November 26, 1991
    Assignees: Institut Textile de France, Rhovyl
    Inventors: Michel Bourgeois, Roger Chatelin, Daniel Wattiez, Michel Sotton, Francois Belet, Georges Achard
  • Patent number: 4780368
    Abstract: The present invention relates to filaments based on a mixture of atactic polyvinyl chloride and postchlorinated polyvinyl chloride, and also to the process for their production.The filaments according to the present invention possess a residual shrinkage in boiling water of less than 2%, a modulus of elasticity of more than 3 kN/mm.sup.2 and a shrinkage stress, after shrinkage in an aqueous fluid medium at a temperature between 98.degree. and 130.degree. C., which is greater than or equal to 1.6.multidot.10.sup.-2 g/dtex.The filaments are obtained by spinning and stretching in a manner which is in itself known, then continuous stabilization under tension, at a temperature between 105.degree. and 125.degree. C., in the presence of steam under pressure, for 1 to 3 seconds, and then shrinkage in an aqueous fluid medium at a temperature between 98.degree. and 130.degree. C.
    Type: Grant
    Filed: February 3, 1986
    Date of Patent: October 25, 1988
    Assignee: Rhovyl
    Inventors: Georges Achard, Pierre Chion, Jacques Menault
  • Patent number: 4707319
    Abstract: Yarns and fibers based on atactic polyvinyl chloride possess a residual shrinkage in boiling water of less than 3%, a modulus of elasticity which is greater than or equal to 2 kN/mm.sup.2, an orientation index of the crystalline zones which is greater than or equal to 70%, an orientation index of the mesomorphic zones which is greater than or equal to 8%, and an orientation index of the amorphous zones which is greater than or equal to 5%. They are obtained by spinning and stretching in a known manner, then stabilization under tension at a temperature between 105.degree. and 130.degree. C., in the presence of steam under pressure, for 1 to 3 seconds, and then shrinkage in an aqueous fluid medium at a temperature between 98.degree. and 130.degree. C.
    Type: Grant
    Filed: May 23, 1986
    Date of Patent: November 17, 1987
    Assignee: RHOVYL
    Inventors: Georges Achard, Gilbert Anouilh, Jacques Menault
  • Patent number: 4681594
    Abstract: The invention relates to a process for continuous dyeing of filaments based on atactic polyvinyl chloride in the course of their production.The undrawn filaments are impregnated with a composition containing at least one plastosoluble dye while they have a density of between 1.3 and 1.4 g/cm.sup.3, are fixed continuously in the presence of steam under pressure at a temperature of between 100.degree. and 120.degree. C. for 2 to 20 seconds, are drawn in a known manner, are then fixed under tension in the presence of steam under pressure at a temperature of between 100.degree. and 130.degree. C. for 1 to 20 seconds, and are then oiled and shrunk in a known manner.Such a process permits quick dyeing, on an industrial scale, with good color fastness.
    Type: Grant
    Filed: March 11, 1986
    Date of Patent: July 21, 1987
    Assignee: Rhovyl
    Inventors: Pierre Chion, Jacques Menault
  • Patent number: 4681595
    Abstract: The present invention relates to a process for continuous dyeing of filaments based on atactic polyvinyl chloride in the course of production.It comprises, in succession, the phases of drawing, impregnation of the filaments by padding while, at the time of the impregnation, the filaments have a density of between 1.3 and 1.4 g/cm.sup.3 (the filament roving having a water content of 10 to 30% by weight), of stabilization under tension in the presence of steam under pressure at a temperature between 100.degree. and 130.degree. C. for 2 to 20 seconds, and then oiling and shrinking in a known manner.Dyeing carried out in this manner is quick and makes it possible to produce colors having good fastness.
    Type: Grant
    Filed: March 25, 1986
    Date of Patent: July 21, 1987
    Assignee: Rhovyl
    Inventors: Pierre Chion, Jacques Menault
  • Patent number: 4529768
    Abstract: The present invention relates to new homogeneous solutions based on polyvinyl chloride, which can be shaped, the process for their preparation and the shaped articles obtained.For a polymer concentration of 15 to 35%, the solutions have an effective viscosity of between 15 and 2,000 poises in a solvent medium which has, at ambient temperature, a solubility parameter of between 8 and 11 and a dielectric constant of between 5 and 25, and which gives, with polyvinyl chloride, a variation in effective viscosity with temperature, represented by a curve d.rho./d.theta., which passes through a maximum absolute value. They are obtained by heating a composition of polyvinyl chloride in the solvent medium to a temperature which is at least 25.degree. C. higher than the average temperature corresponding to the maximum of the curve d.rho./d.theta..
    Type: Grant
    Filed: March 18, 1983
    Date of Patent: July 16, 1985
    Assignee: Rhovyl
    Inventors: Georges Achard, Jacques Menault, Roger Thouvenot
  • Patent number: 4508778
    Abstract: The present invention relates to yarns and fibers based on atactic polyvinyl chloride. They possess a residual shrinkage in boiling water of less than 3%, a modulus of elasticity which is greater than or equal to 2 kN/mm.sup.2, an orientation index of the crystalline zones which is greater than or equal to 70%, an orientation index of the mesomorphic zones which is greater than or equal to 8%, and an orientation index of the amorphous zones which is greater than or equal to 5%. They are obtained by spinning and stretching in a known manner, then stabilization under tension at a temperature between 105.degree. and 130.degree. C., in the presence of steam under pressure, for 1 to 3 seconds, and then shrinkage in an aqueous fluid medium at a temperature between 98.degree. and 130.degree. C.
    Type: Grant
    Filed: August 12, 1983
    Date of Patent: April 2, 1985
    Assignee: Rhovyl
    Inventor: Georges Achard