Abstract: Compounds having the general formula: ##STR1## wherein X is the 2-(1,7,7-trimethylbicyclo[2.2.1]hept-2-yl)oxy, R is --(CH.sub.2).sub.p -- where p varies from 1 to 3; R' is (CH.sub.2).sub.n -- where n varies from 1 to 7; R" is hydrogen or methyl; and m is 0 to 4.

Abstract: There is provided a novel class of alkoxy silanes useful as corrosion inhibitors for metal surfaces and characterized by an alkylene group attached to silicon through a Si--C linkage. These compounds also contain nitrogen as an amine or an imine group in a linear or cyclic structure. Sulfur and/or a carbonyl or thiocarbonyl group may also be present. The invention also provides a method of inhibiting corrosion of metal surfaces by applying a coating containing or consisting of a novel silane as above described.

Abstract: High solids alkyd resin coatings are prepared by reacting at least a portion of the available hydroxyl groups on a resin with an ethylenically unsaturated monoisocyanate monomer. The new products, useful both as the major vehicle resin in high solids coatings and as a cure modifier for oxidatively curable alkyd, polyester and acrylic resins, impart improved drying and weathering properties to coatings while maintaining low paint viscosity.

Abstract: Cationic electrocoat latices, containing blocked isocyanate crosslinker and which are usually unstable toward pumping and shear forces, can be stabilized by conducting the emulsion polymerization in a solvent-water mixture containing from about 20 to 30 percent solvent. Ethanol is a preferred solvent. Preferably the crosslinker is first emulsified and then added to the emulsion polymerization system prior to or during polymerization to produce mechanically stable latex that is virtually free of grit.

Abstract: Thermosetting low temperature cure latex coating compositions are prepared by emulsion polymerization in aqueous medium from non-hydroxyl bearing acrylic monomers, acrylamide or methacrylamide and a major proportion of a vinyl unsaturated hydrocarbon. When hot or cold blended with a glycoluril cross-linker and applied to a wood substrate, the coating exhibits excellent gloss properties and MEK resistance.

Abstract: Package and tank stable, low temperature self-curing, cation-active aqueous soluble or dispersible coating compositions are prepared by copolymerizing blocked meta-isopropenyl-.alpha.,.alpha.-dimethylbenzyl isocyanate (m-TMI) with various vinyl unsaturated monomers optionally in the presence of epoxy-amine adduct. These cation-active polymers when acidified or partially acidified provide aqueous solutions or dispersions especially useful as low temperature curable vehicles in cathodic electrocoating.

Abstract: Dimethacrylate esters of a diol are linearly copolymerized by step dimerization of methacrylate groups of a dimethacrylate ester in the presence of a non-peroxide free radical initiator and a Cobalt (II) catalyst complex for chain transfer to monomer to produce a linear polyester polymer having 2,2-dimethyl-4-methylene glutarate structural units in the polymer chain.

Abstract: New siloxane-polyesters, siloxane-ethers and siloxane-ether-polyesters, useful as powder coating resins, are prepared by reacting rigid diacids, neopentyl glycol, trimellitic anhydride with up to 90 percent hydroxyl functional silicone having about two .dbd.Si(R)--OH groups per molecule where R is lower alkyl or phenyl groups and the remaining silicon valences form ring-structured siloxanes. Improved powder properties, including crystallinity and tack temperatures of 50.degree.-90.degree. C., are believed to result in part from the rigidity provided by both the specific diacids and the cyclic silicones. The siloxane resins are hard at room temperature and can be powdered by methanical grinding. Powder coatings formulated from these resins are particularly suitable for coating metal and glass substrate.

Abstract: A copper infiltrated ferrous powder metal part infiltrated with copper or a copper alloy characterized as having after infiltration a residual uninfiltrated porosity of less than about 7 volume percent and a maximum pore size of the residual uninfiltrated porosity of less than about 125 micrometers, said porosity and pore size values being taken from a worst field of view in a functionally critical area of said metal part.

Abstract: A copper-rich metal shape is produced by forming a coherent forerunner shape consisting essentially of cupreous powder, said powder containing a proportion of copper oxide sufficient for facilitating the obtaining of a high sinter density in sintered porous mass, and in a reducing atmosphere at temperature that will sinter copper present, converting said forerunner shape into a porous sintered mass virtually devoid of copper oxide. Said porous mass can be worked so virtually full density if desired.

Abstract: Water dispersed phosphated epoxy-acrylic polymers are produced by first producing an epoxy phosphate followed by in-situ polymerization of ethylenically unsaturated monomers, including carboxyl monomers, in the presence of the epoxy phosphate and utilizing at least 3% peroxide catalyst based on the weight of monomers.

Abstract: Provides new and improved water-reducible coating compositions and methods of making them. Three preferred processes are disclosed. These differ in the manner of incorporating and chemical nature of an extender polymer.Broadly, the process of the invention is one for forming an aqueous dispersion of a fluent resinous composition ofa. a mixture in an organic solvent of(i) an ionizable graft polymer of an epoxy resin and an addition polymerized resin, the addition polymerized resin being bonded to aliphatic backbone carbon atoms of the epoxy resin by carbon-to-carbon bonds, and(ii) an extender resin;b. an aqueous vehicle, andc. an ionizing agent;the ionization present from said combined components being sufficient to establish the components as a dispersion in the aqueous vehicle, and then addition polymerizing a quantity of addition polymerizable monomer, under addition polymerizing conditions, in said aqueous dispersion, the aqueous dispersion serving as a vehicle therefor.

Abstract: There is provided an improved process for producing a silica gel having improved pore volume relative to conventional silica gels which comprises the steps of gelling an aqueous alkali metal silicate with an aqueous acid, washing the resulting gel to remove salt or salts and acid, and soaking the gel in an aqueous solution of a water soluble aluminum salt to impart from 0.1% to 0.7% by weight aluminum on the dry basis to said gel, drying and reducing the particle size of the dried gel to from 2.0 to 15 microns, said particles having a pore volume in the range of 1.25 to 2.25 cm.sup.3 /gram. and a product produced by said process.

Abstract: A process for making a strip or sheet comprising dispersion strengthened metal or dispersion strengthened metal alloy which comprises rolling directly from dispersion strengthened metal powder to a green strip or sheet density of from at least 90% to 95% of theoretical density, sintering the green strip or sheet in an inert atmosphere at a temperature and for a period of time sufficient to form a rigid body; reducing the thickness of the strip or sheet by at least 25% by cold rolling or hot rolling and resintering at sintering temperature of at least about 1800.degree. F. for 40 to 75 or more minutes.

Abstract: A tamper evidencing cap for use with containers for ingestibles, medicines, and the like. The cap comprises first and second cover members connected to each other. At least one lid is hinged to the second cover member for movement between open and closed positions. Tamper evidencing means is removably connected to and between the lid and one of the cover members to prevent the lid from opening until the tamper evidencing means is removed. The cap may additionally or alternatively include a further tamper evidencing means comprising a skirt that extends from the periphery of the first cover member for engaging a side surface of the container. The skirt has a plurality of spaced apart weakened zones around its periphery.

Abstract: Polyhydroxyl silanes or siloxanes useful as vehicles for coatings applicable to metal, mineral or glass surfaces, are made by reacting a silane or siloxane having an amine terminated substituent attached to silicon with an aldonic acid lactone. Reaction occurs at temperatures below 80.degree. C. in alcohol solution under inert gas blanket. Products are water soluble and polymerizable at slightly elevated temperatures to hard, water insoluble tightly adhering films.

Abstract: An improved resistance welding electrode cap adapted to being internally cooled with a flow of coolant has a main body portion with a nose root at one end and an electrical and coolant connection projecting from the other, the area of the root being substantially smaller than that of the direct projection of the main body portion, a pronounced nose projecting from the root. The whole nose is of dispersion-strengthened copper, as is at least the main body portion. Such cap provides astonishingly improved performance for resistance welding, even of galvanized steel, and particularly of double-sided, galvanized cold-rolled steel sheet.

Abstract: A process for encapsulating materials which are difficult to fluidize in a fluidized bed reactor comprising the steps of (1) compacting said materials into a plurality of flat chips; (2) grinding said chips into particles having a small particle size; (3) forming a fluid bed of the particles of step (2) in a fluid bed spray reactor; (4) applying a spray of a melted or molten hydrogenated liquid or wax to the surface of said particles in said reactor, encapsulating said particles; withdrawing said encapsulating material from said reactor.

Abstract: A dry, edible food coating premix composition, blendable with liquid oil or shortening and water, to form a batter which, when applied to the surface of a food item such as chicken, fish, or vegetables, provides on baking the taste, and a variegated appearance and texture of a batter coated deep or pan fried such item, comprising a farinaceous material in flour form; a normally plastic or hard shortening or fat; said flour and shortening or fat being intensively mixed by impact mixing.

Abstract: An improved hydroxyl functional urethane-extended polyester is based on the condensation reaction of fumaric acid, one or more non-aromatic polyols, azelaic acid and optionally one or more non-aromatic carboxylic acids including lauric acid or stearic acid. The hydroxylated polyester urethane oligomer possesses a molecular weight below 2600 and a mole ratio of hydroxyl groups to urethane linkage of from 0.5 to 6. Gel coats prepared from these oligomers exhibit superior water resistance and improved weathering characteristics.