Abstract: Known thermal spray apparatus are modified to achieve thermal spray coatings of increased hardness. Thermal spray apparatus operate to develop a plasma stream for introduction to a nozzle, for eventual application to the surface of a substrate. Upon entering the nozzle, the plasma stream is passed through a plasma cooling zone defined by a plasma cooling passageway, to a plasma accelerating zone defined by a narrowed passageway that expands into a plasma/particle confining zone for the discharge of material from the apparatus. The narrowed passageway of the apparatus is cooled, and the powder material to be applied by the apparatus is introduced into the plasma stream along the cooled, narrowed passageway.

Abstract: An aqueous phosphoric bonding solution and coating composition slurry which are environmentally friendly in that they are generally free of molybdate or chromium. Yet the solution is stable with respect to inorganic metal particles, especially aluminum which are admixed to the bonding solution for the preparation of the coating slurry. The metal coated parts and the method of coating the parts with the coating composition are also described. The parts have very satisfactory properties.

Abstract: An aqueous phosphoric bonding solution and coating composition slurry which are environmentally friendly in that they are generally free of molybdate or chromium. Yet the solution is stable with respect to inorganic metal particles, especially aluminum which are admixed to the bonding solution for the preparation of the coating slurry. The metal coated parts and the method of coating the parts with the coating composition are also described. The parts have very satisfactory properties.

Abstract: The oxidation and corrosion resistance of a nickel-base alloy are enhanced by a process which includes first enriching the surface of an alloy substrate with platinum, as by electrolytic deposition, and then simultaneously diffusing aluminum and silicon from a molten state into the platinum-enriched substrate. The invention further provides coatings and coated substrates with enhanced oxidation and corrosion resistance.

Abstract: A silicon-enriched aluminide coating for a superalloy article has a composite microstructure including a plurality of bands of silicon rich phases (S.sub.1, S.sub.2, S.sub.3) and a plurality of bands of aluminum rich phases (A.sub.1, A.sub.2, A.sub.3), these bands being spaced apart through the thickness of the coating. The composite microstructure is created by depositing a slurry containing both silicon and aluminum in elemental or pre-alloyed form on the article and heating the coated article above the melting temperature of aluminum to cure the coating, the depositing and curing steps being repeated at least once before diffusion heat treating the resulting layers. Thereupon, all the above process steps are repeated at least once.

Abstract: Known thermal spray apparatus are modified to achieve rough thermal spray coatings. Thermal spray apparatus operate to develop a plasma stream for introduction to a nozzle, for eventual application to the surface of a substrate. Upon entering the nozzle, the plasma stream is passed through a plasma cooling zone defined by a plasma cooling passageway, to a plasma accelerating zone defined by a narrowed passageway that expands into a plasma/particle confining zone for the discharge of material from the apparatus. The narrowed passageway of the apparatus is cooled, and the powder material to be applied by the apparatus is introduced into the plasma stream along the cooled, narrowed passageway.

Abstract: An aqueous phosphoric bonding solution and coating composition slurry which are environmentally friendly in that they are generally free of molybdate or chromium. Yet the solution is stable with respect to inorganic metal particles, especially aluminum which are admixed to the bonding solution for the preparation of the coating slurry. The metal coated parts and the method of coating the parts with the coating composition are also described. The parts have very satisfactory properties.

Abstract: A coated article (10) and method of making the same is disclosed wherein the coated article (10) includes a substrate (12) consisting essentially of titanium or titanium alloy and an outer coating (14) of thermoplastic resin for protecting the substrate from chemical degradation and maintaining stability during exposure to temperatures of at least up to 260.degree. C. An adhesion primer layer (16) is disposed between the substrate (12) and the outer coating (14). The adhesion primer layer (16) includes an inorganic binder matrix for increasing adhesion to the titanium and titanium alloys. The primer layer (16) further includes a thermoplastic resin in particulate form for increasing adhesion to the outer coating (14).

Abstract: A method for applying a thermal spray coating onto a substrate (24) includes the steps of providing chamber apparatus (10) including a chamber (16) having a gas flow assembly (23) that includes a gas injector (27) and a spray nozzle (30) therein for introducing, a gas and spray coating. The chamber has an adjustably sized restricted opening (18) that is continuously open to the ambient atmosphere (21) that is exterior of the chamber (16). The total gas flow is maintained from the gas flow assembly (23) at a predetermined rate based on the size of the restricted opening (18) and the amount of oxygen that is desired to be present during the spraying of the coating and thereafter until the spray coating solidifies on the substrate. Gas flow from the spray nozzle (30) is determined by optimum process parameters for coating specified materials. If the gas flow from the nozzle (30) is insufficient to provide the total gas flow, the gas injector (27) supplements the total gas flow.

Abstract: A coating composition and method of use thereof for coating metal substrates, especially galvanically active metals, containing a resinous organic polymer, a corrosion inhibiting leachable pigment and an ion reactive pigment generally in the form of metallic spheroid particles. Coated materials have improved corrosion resistance.

Abstract: An apparatus (10) for applying a thermal spray coating onto a substrate (24) includes a chamber (16) having an open bottom portion (18), a gas source for releasing a gas lighter than oxygen into the chamber (16) and displacing the oxygen from the chamber (16), and a spray gun (30) for spraying coating through the gas in the chamber (16) and onto the substrate (24).A method is also provided including the steps of displacing oxygen from the chamber (16) with the gas, and spraying the coating through the gas and onto the substrate (24) disposed within the chamber, the gas preventing oxidation between the substrate (24) and layers of the coating.

Abstract: A method and apparatus for separating an upper (12) and lower (14) mold plate of a mold assembly (10) from a preformed substrate or casting (16) comprises a mold ejection apparatus (70) having a support surface (76) to receive and support the mold assembly (10). A plurality of clamps (84) pivotally connected to the support surface (76) engage the preformed substrate (16) at spaced apart intervals about the periphery of the preformed substrate (16) to restrain the substrate (16) and lower mold plate (14) against the support surface (76). The apparatus further includes a plurality of secondary hydraulic pumps (98) comprising a piston (106) and cylinder (108) assembly and a lifting bar (120) pivotally connected to one end of the piston (106). The secondary pumps (98) are supported on the support surface (76) at spaced apart intervals adjacent the periphery of the mold assembly (10).

Abstract: A method and apparatus for separating an upper (12) and lower (14) mold plate of a mold assembly (10) from a preformed substrate or casting (16) by including a mold ejection apparatus (70) having a support surface (76) to receive and support the mold assembly (10). A plurality of clamps (84) pivotally connected to the support surface (76) engage the preformed substrate (16) at spaced apart intervals about the periphery of the preformed substrate (16) to restrain the substrate (16) and lower mold plate (14) against the support surface (76). The apparatus further includes a plurality of secondary hydraulic pumps (98) having a piston (106) and cylinder (108) assembly and a lifting bar (120) pivotally connected to one end of the piston (106). The secondary pumps (98) are supported on the support surface (76) at spaced apart intervals adjacent the periphery of the mold assembly (10).

Abstract: A spray booth for applying a coating to a substrate includes an outer chamber (12) containing a fluid therein having a predetermined first temperature and/or humidity and an inner chamber (14) in fluid communication with the outer chamber (12). The inner chamber (14) contains the fluid therein at a higher predetermined second humidity and/or temperature. The inner chamber (14) includes a fan (42) for recirculating a flow of the fluid at the second predetermined temperature and/or humidity therethrough and filters (34,36,44,46) for removing airborne comtaminants. A temperature and/or humidity control device (58) exhausts a predetermined amount of the fluid from the inner chamber (14) out of the inner (14) and outer chambers (12) said exhausted fluid being essentially free of toxic contaminants, the exhaust of the fluid drawing fluid from the outer chamber (22) into the inner chamber (14) to lower the temperature and/or humidity in the inner chamber (14).

Abstract: A coating composition and method of use thereof for coating metal substrates, especially galvanically active metals, containing a resinous organic polymer, a corrosion inhibiting leachable pigment and an ion reactive pigment generally in the form of metallic spheroid particles. Coated materials have improved corrosion resistance.

Abstract: A cured coating composition and substrate coated with the cured coating composition which coating is based upon an aqueous acid binder solution containing phosphate and chromate and/or molybdate ions into which has been dispersed a blend of metallic powder particles of three primary dimensions and flat metal flake materials, which can be applied to a substrate part to be coated more uniformly and thickly than conventional metal flake coatings, and which imparts better corrosion and impact resistance than conventional powder metal coatings.

Abstract: A coating composition for providing a part with improved salt spray resistance, which includes undissolved solid hexavalent chromate in an aqueous acid solution which is the reaction product of phosphate ions with ions of the group consisting of chromate or molybdate ions, and their coatings and coated parts.

Abstract: Porous coating for substrates especially metal substrates. The pores are created by the removal of a fugitive material. The coatings have useful numerous applications also for heat exchange, optical coating and non-slip. Products formed from the coating and a method of forming such products are also disclosed.

Abstract: A coating composition for providing a part with improved salt spray resistance, which comprises undissolved solid hexavalent chromate in an aqueous acid solution which is the reaction product of phosphate ions with ions of the group consisting of chromate or molybdate ions, and their coatings and coated parts.

Abstract: A coating composition based upon an aqueous acid binder solution containing phosphate and chromate and/or molybdate ions into which has been dispersed a blend of metallic powder particles of three primary dimensions and flat metal flake materials, which can be applied to a substrate part to be coated more uniformly and thickly than conventional metal flake coatings, and which imparts better corrosion and impact resistance than conventional powder metal coatings.