Patents Assigned to Shin Nisso Kako Co., Ltd.
  • Patent number: 4954631
    Abstract: Fluoran compounds are disclosed of formula (I) ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently represent hydrogen, halogen, lower alkoxy, C.sub.1 -C.sub.9 -alkyl, C.sub.5 or C.sub.6 -cycloalkyl, benzyl or phenyl, said benzyl or phenyl being optionally substituted by halogen, lower alkyl or lower alkoxy, and further R.sub.1 and R.sub.2 as well as R.sub.3 and R.sub.4 taken together with Ring A, may form a naphthalene ring optionally substituted by halogen, lower alkyl or lower alkoxy, R.sub.5, R.sub.6 and R.sub.7 independently represent halogen, lower alkyl or lower alkoxy, B.sub.1 and B.sub.2 independently represent hydrogen, C.sub.1 -C.sub.8 -alkyl, benzyl or phenyl, said benzyl or phenyl being optionally substituted by halogen, lower alkyl, lower alkoxy, or alkyl-substituted, X represents hydrogen atom or --NR.sub.8 R.sub.9 wherein R.sub.8 and R.sub.9 independently represent hydrogen, C.sub.1 -C.sub.8 -alkyl, C.sub.5 or C.sub.
    Type: Grant
    Filed: February 2, 1989
    Date of Patent: September 4, 1990
    Assignee: Shin Nisso Kako Co., Ltd.
    Inventors: Takeo Obitsu, Yutaka Ohnishi, Shinji Yoshinaka, Minoru Koguchi, Mitsuhiro Yanagita, Nobuyuki Hirai
  • Patent number: 4864048
    Abstract: A process for preparing a phosphonitrile compound having a substituted hydroxyl group by making use of a phosphonitrile chloride oligomer and an alcohol as the starting materials, which comprises:(1) a first step of reacting said phosphonitrile chloride oligomer with said alcohol in a specific amount ratio of the active chlorine contained in said phosphonitrile chloride oligomer relative to the alcohol in the presence of a specific amount of a tertiary amine at a specific temperature, thereby substituting a specific amount of said active chlorine by a substituted alkoxy group,(2) a second step of elevating the temperature of the reaction mixture obtained in the first step to a specific temperature to cause a condensation reaction through the elimination of R--Cl, and(3) a third step of adding an alcohol in a specific amount ratio relative to said active chlorine which remains at the stage of completion of the second step, to the reaction system, and making said remaining active chlorine react with said alcoho
    Type: Grant
    Filed: August 6, 1987
    Date of Patent: September 5, 1989
    Assignee: Shin Nisso Kako Co., Ltd.
    Inventors: Masaharu Kaneko, Kazuhiko Fujikawa, Tetsuhiko Okamoto
  • Patent number: 4855389
    Abstract: This invention relates to a process for producing phosphonitrile oligomers containing maleimido phenoxy groups.
    Type: Grant
    Filed: August 28, 1987
    Date of Patent: August 8, 1989
    Assignee: Shin Nisso Kako Co., Ltd.
    Inventors: Shinichiro Ueyama, Masayuki Furukawa, Tadaichi Nishikawa
  • Patent number: 4826806
    Abstract: Fluoran compounds are disclosed of formula (I) ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently represent hydrogen, halogen, lower alkoxy, C.sub.1 -C.sub.9 -alkyl, C.sub.5 or C.sub.6 -cycloalkyl, benzyl or phenyl, said benzyl or phenyl being optionally substituted by halogen, lower alkyl or lower alkoxy, and further R.sub.1 and R.sub.2 as well as R.sub.3 and R.sub.4 taken together with Ring A, may form a naphthalene ring optionally substituted by halogen, lower alkyl or lower alkoxy, R.sub.5, R.sub.6 and R.sub.7 independently represent halogen, lower alkyl or lower alkoxy, B.sub.1 and B.sub.2 independently represent hydrogen, C.sub.1 -C.sub.8 -alkyl, benzyl or phenyl, said benzyl or phenyl being optionally substituted by halogen, lower alkyl, lower alkoxy, or alkyl-substituted amino, X represents hydrogen atom or --NR.sub.8 R.sub.9 wherein R.sub.8 and R.sub.9 independently represent hydrogen, C.sub.1 -C.sub.8 -alkyl, C.sub.5 or C.sub.
    Type: Grant
    Filed: July 29, 1987
    Date of Patent: May 2, 1989
    Assignee: Shin Nisso Kako Co., Ltd.
    Inventors: Takeo Obitsu, Yutaka Ohnishi, Shinji Yoshinaka, Minoru Koguchi, Mitsuhiro Yanagita, Nobuyuki Hirai
  • Patent number: 4795621
    Abstract: Phosphonitrile chloride oligomer, particularly, phosphonitrile chloride trimer, is produced in high yield while suppressing the formation of by-product phosphonitrile chloride tetramer, by reacting phosphorus pentachloride with ammonium chloride in an inert organic solvent, in the presence of a catalytic amount of a compound selected from the group consisting of quinoline, isoquinoline and their drivatives represented by the general formulae: ##STR1## wherein R stands for an alkyl group or a halogen atom and n stands for zero or an integer of 1 to 7,and pyridine derivatives represented by the general formula: ##STR2## wherein Q stands for a halogen atom or a hydroxyl group; R' stands for an alkyl group; m stands for an integer of 1 to 5 and p stands for zero of an integer of 1 to 4 with the proviso that the total number of m and p is from 1 to 5,and in the presence of a catalytic amount of a polyvalent metal compound.
    Type: Grant
    Filed: August 13, 1986
    Date of Patent: January 3, 1989
    Assignee: Shin Nisso Kako Co., Ltd.
    Inventors: Tetsuhiko Okamoto, Shinichiro Ueyama, Kazuhiko Fujikawa
  • Patent number: 4794069
    Abstract: Spirobenzanthracene phthalide compounds are disclosed of the formula (I) ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 independently represent C.sub.1 -C.sub.8 alkyl optionally substituted by C.sub.1 -C.sub.5 alkoxy; C.sub.5 or C.sub.6 cycloalkyl; or aralkyl or aryl optionally substituted by C.sub.1 -C.sub.5 alkyl or C.sub.1 -C.sub.5 alkoxy, and R.sup.1 and R.sup.2, R.sup.3 and R.sup.4, and R.sup.5 and R.sup.6 taken together with the nitrogen atom to which they are attached, may form pyrrolidino, piperidino or morpholino ring, and R.sup.7, R.sup.8, R.sup.9 and R.sup.10 independently represent hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.1 -C.sub.5 alkoxy or trifluoromethyl. The compounds are used, together with a developer, in color for materials such as pressure-sensitive copying papers, heat-sensitive recording papers and the like.
    Type: Grant
    Filed: July 14, 1987
    Date of Patent: December 27, 1988
    Assignee: Shin Nisso Kako Co., Ltd.
    Inventors: Yutaka Ohnishi, Shinji Yoshinaka, Toshiyuki Tanaka, Minoru Koguchi, Takeo Obitsu
  • Patent number: 4727162
    Abstract: A molecular compound of a fluoran compound and a ketone useful as a color former for heat or pressure-sensitive color-developable recording material.
    Type: Grant
    Filed: November 25, 1986
    Date of Patent: February 23, 1988
    Assignee: Shin Nisso Kako Co., Ltd.
    Inventors: Masakichi Yahagi, Tetsuo Igaki
  • Patent number: 4695640
    Abstract: Addition compound of fluoran compound and ketone useful as color former for heat or pressure-sensitive color-developable recording material.
    Type: Grant
    Filed: October 21, 1985
    Date of Patent: September 22, 1987
    Assignee: Shin Nisso Kako Co., Ltd.
    Inventors: Masakichi Yahagi, Tetsuo Igaki, Shinji Yoshinaka, Kimiaki Kinoshita, Morikuni Saito, Toshiyuki Yamashita, Morio Nanbu
  • Patent number: 4687862
    Abstract: The fluoran compounds of the formula (I) are new red color forming chromogenic dyes. ##STR1## wherein R represents an isobutyl or isopentyl group, R.sub.1 represents a hydrogen or halogen atom or an alkyl group, R.sub.2 represents a hydrogen or halogen atom or an alkyl group, R.sub.3 represents a hydrogen atom, and R.sub.4 represents a hydrogen atom, or R.sub.4 and R.sub.1 as well as R.sub.2 and R.sub.3 taken together with the carbon atoms to which they are attached may form a benzene ring which may be substituted with a halogen atom. They are used, together with an acidic developer, in chromogenic recording materials for use in pressure sensitive copying paper, heat-sensitive recording paper and thermo-sensitive, reversible color changing composition.
    Type: Grant
    Filed: October 14, 1986
    Date of Patent: August 18, 1987
    Assignee: Shin Nisso Kako Co., Ltd.
    Inventors: Takeo Obitsu, Tetsuo Igaki, Kimiaki Kinoshita, Morio Nanbu, Shinichi Satoh
  • Patent number: 4680598
    Abstract: The fluoran compounds of the formula (I) are new red color forming chromogenic dyes. ##STR1## wherein R represents an isobutyl or isopentyl group, R.sub.1 represents a hydrogen or halogen atom or an alkyl group, R.sub.2 represents a hydrogen or halogen atom or an alkyl group, R.sub.3 represents a hydrogen atom, and R.sub.4 represents a hydrogen atom, or R.sub.4 and R.sub.1 as well as R.sub.2 and R.sub.3 taken together with the carbon atoms to which they are attached may form a benzene ring which may be substituted with a halogen atom. They are used, together with an acidic developer, in chromogenic recording materials for use in pressure sensitive copying paper, heat-sensitive recording paper and thermo-sensitive, reversible color changing composition.
    Type: Grant
    Filed: April 8, 1986
    Date of Patent: July 14, 1987
    Assignee: Shin Nisso Kako Co., Ltd.
    Inventors: Takeo Obitsu, Tetsuo Igaki, Kimiaki Kinoshita, Morio Nanbu, Shinichi Satoh
  • Patent number: 4677203
    Abstract: Certain 3-piperidino fluoran derivatives useful as color recording materials are disclosed.
    Type: Grant
    Filed: June 14, 1983
    Date of Patent: June 30, 1987
    Assignee: Shin Nisso Kako Co., Ltd.
    Inventors: Masakichi Yahagi, Shoichi Horiuchi, Takahumi Toyama, Akio Kashiwagi, Teruo Suzuki, Tetsuo Igaki, Kazuyuki Horisawa, Mituhiro Shoji
  • Patent number: 4668967
    Abstract: 3-N-isobutyl-ethylamino-7-phenylaminofluoran is a new green color former. It is used, together with an acidic substance, in color forming record materials for use in pressure sensitive copying paper, heat-sensitive recording paper and the like.
    Type: Grant
    Filed: May 28, 1986
    Date of Patent: May 26, 1987
    Assignee: Shin Nisso Kako Co., Ltd.
    Inventors: Masakichi Yahagi, Takeo Obitsu, Tetsuo Igaki, Kazuyuki Horisawa, Morio Nanbu, Kimiaki Kinoshita, Sumio Manaka
  • Patent number: 4665199
    Abstract: 3-N-isobutylethylamino-6-methyl-7-phenylamino fluoran of formula (I) ##STR1## is described.
    Type: Grant
    Filed: December 23, 1985
    Date of Patent: May 12, 1987
    Assignee: Shin Nisso Kako Co., Ltd.
    Inventors: Masakichi Yahagi, Tetsuo Igaki, Sinzi Yoshinaka, Kousaku Morita, Morikuni Saito, Kimiaki Kinoshita
  • Patent number: 4616239
    Abstract: 4-Hydroxy-4'-isopropoxydiphenylsulfone useful as color developer for heat-sensitive color-developable recording material.
    Type: Grant
    Filed: September 16, 1985
    Date of Patent: October 7, 1986
    Assignee: Shin Nisso Kako Co., Ltd.
    Inventors: Masakichi Yahagi, Tetsuo Igaki, Shinji Yoshinaka, Kosaku Morita, Kimiaki Kinoshita, Masashi Enokiya, Akio Kaneko, Toshiyuki Yamashita
  • Patent number: 4613879
    Abstract: This invention relates to chromogenic recording materials comprising as a chromogenic substance 3-N-isobutylethylamino-6-methyl-7-phenylaminofluoran of the following formula (I) ##STR1##
    Type: Grant
    Filed: April 18, 1984
    Date of Patent: September 23, 1986
    Assignee: Shin Nisso Kako Co., Ltd.
    Inventors: Masakichi Yahagi, Tetsuo Igaki, Sinzi Yoshinaka, Kousaku Morita, Morikuni Saito, Kimiaki Kinoshita
  • Patent number: 4590498
    Abstract: Chromogenic recording materials which utilizes a fluoran compound of the formula ##STR1## wherein R is methyl or ethyl, is described.
    Type: Grant
    Filed: February 23, 1984
    Date of Patent: May 20, 1986
    Assignee: Shin Nisso Kako Co., Ltd.
    Inventors: Masakichi Yahagi, Tetsuo Igaki, Sinzi Yosinaka, Kousaku Morita, Morikuni Saito, Kimiaki Kinoshita
  • Patent number: 4571310
    Abstract: A process for preparing alkoxyphosphonitrile compounds.
    Type: Grant
    Filed: May 23, 1984
    Date of Patent: February 18, 1986
    Assignee: Shin Nisso Kako Co., Ltd.
    Inventors: Hiroshi Tanino, Tetsuhiko Okamoto, Shinichiro Ueyama, Kazuhiko Fuzikawa
  • Patent number: 4567028
    Abstract: A process for the preparation of phosphonitrile chloride oligomer, particularly, phosphonitrile chloride trimer at a high yield while suppressing the by-production of phosphonitrile chloride tetramer by reacting phosphorus pentachloride and ammonium chloride in an inert organic solvent under the presence of a polyvalent metal compound catalyst, wherein a catalytic amount of a compound selected from the group consisting of pyridine and alkyl-substituted pyridine derivatives capable of forming chloropyridinium salts in reaction with phosphorus pentachloride is present in the reaction system.
    Type: Grant
    Filed: February 11, 1985
    Date of Patent: January 28, 1986
    Assignee: Shin Nisso Kako Co., Ltd.
    Inventors: Hiroshi Tanino, Tetsuhiko Okamoto, Shinichiro Ueyama
  • Patent number: 4560526
    Abstract: A process for preparing a molded silicon carbide product, by molding a mixture of silicon carbide powder, an organosilicon compound and one or more lubricants to form a compact and sintering the thus-formed compact, is described.
    Type: Grant
    Filed: March 12, 1984
    Date of Patent: December 24, 1985
    Assignee: Shin Nisso Kako Co., Ltd.
    Inventor: Masatoshi Okumura
  • Patent number: 4522689
    Abstract: A process for completely separating tri(phosphonitrile chloride) from tetra(phosphonitrile chloride) and/or phosphonitrile chloride oligomer which includes vacuum distillation of the phosphonitrile chloride mixture together with an inert mixture of hydrocarbons as solvent.
    Type: Grant
    Filed: October 9, 1984
    Date of Patent: June 11, 1985
    Assignee: Shin Nisso Kako Co., Ltd.
    Inventors: Hiroshi Tanino, Tetsuhiko Okamoto, Shinichiro Ueyama, Kazuhiko Fujikawa, Takatoshi Tsumiyama