Abstract: Described are compounds of the structure R4-a—Si-(Sp-Y)a—Zb, wherein “a” is an integer from 1 to 4; “b” is an integer from 0 to (3×a); “Z,” which is absent when “b”=0, is “R” or wherein each “R” is halogen, C1-6 linear or branched alkyl, alkenyl, or alkynyl or C1-6 linear or branched halo-alkyl, halo-alkenyl, or halo-alkynyl; each “Sp” C1-15 linear or branched alkylenyl or C1-15 linear or branched halo-alkylenyl; and each “Y” an organic polar group. Also described are electrolyte compositions containing one or more of these compounds.

Abstract: Described are electrolyte compositions and electrochemical devices containing the electrolyte compositions. The compositions include an organosilicon compound, an imide salt and optionally LiPF6. The electrolytes provide improved high-temperature performance and stability and will operate at temperatures as high as 250° C.

Abstract: Described are compounds of the structure R4-a—Si-(Sp-Y)a—Zb, wherein “a” is integer from 1 to 4; “b” is an integer from 0 to (3×a); “Z,” which is absent when “b “R” or formula (II), wherein each “R” is halogen, C1-6 linear or branched alkyl, alkenyl, or alkynyl or C1-6 linear or branched halo-alkyl, halo-alkenyl, or halo-alkynyl; each “Sp” C1-15 linear or branched alkylenyl or CMS linear or branched halo-alkylenyl; and each “Y” an organic polar group. Also described are electrolyte compositions containing one or more of these compounds.

Abstract: Described are organosilicon electrolyte compositions having improved thermostability and electrochemical properties and electrochemical devices that contain the organosilicon electrolyte compositions.

Abstract: Described are electrolyte compositions having at least one salt and at least one compound selected from the group consisting of: wherein “a” is from 1 to 3; “b” is 1 or 2; 4?“a”+“b”?2; X is a halogen; R can be alkoxy or substituted alkoxy, among other moieties, and R1 is alkyl, substituted alkyl, aryl, substituted aryl, alkoxy, or substituted alkoxy. Also described are electrochemical devices that use the electrolyte composition.

Abstract: Described herein are liquid, organosilicon compounds that including a substituent that is a cyano (—CN), cyanate (—OCN), isocyanate (—NCO), thiocyanate (—SCN) or isothiocyanate (—NCS). The organosilicon compounds are useful in electrolyte compositions and can be used in any electrochemical device where electrolytes are conventionally used.

Abstract: Described are electrolyte compositions and electrochemical devices containing the electrolyte compositions. The compositions include an organosilicon compound, an imide salt and optionally LiPF6. The electrolytes provide improved high-temperature performance and stability and will operate at temperatures as high as 250° C.

Abstract: Described are electrolyte compositions and electrochemical devices containing them. The compositions include an organosilicon compound, an imide salt and optionally LiPF6. The electrolytes provide improved high-temperature performance and stability and will operate at temperatures as high as 250 C. An electrolyte composition comprising, in combination: an organosilicon compound and an imide salt and optionally UPF6; wherein when subjected to cyclic voltammetry at a plurality of cycles ranging from about 3V to about 5V and using a cathode current collector comprising aluminum versus Li/Lit electrodes the composition exhibits an oxidative corrosion current of about 0.10 mA/cm2 or less for a second and subsequent cycles.

Abstract: Described herein are liquid, organosilicon compounds that including a substituent that is a cyano (—CN), cyanate (—OCN), isocyanate (—NCO), thiocyanate (—SCN) or isothiocyanate (—NCS). The organosilicon compounds are useful in electrolyte compositions and can be used in any electrochemical device where electrolytes are conventionally used.

Abstract: Described are electrolyte compositions having at least one salt and at least one compound selected from the group consisting of: wherein “a” is from 1 to 3; “b” is 1 or 2; 4?“a”+“b”?2; X is a halogen; R can be alkoxy or substituted alkoxy, among other moieties, and R1 is alkyl, substituted alkyl, aryl, substituted aryl, alkoxy, or substituted alkoxy. Also described are electrochemical devices that use the electrolyte composition.