Patents Assigned to Stockhausen GmbH
-
Patent number: 7964689Abstract: The invention relates to a superabsorbent polymer that includes a (meth)acrylic acid made by a process that comprises the following process steps: a) (meth)acrylic acid is crystallized out from a mother liquor; b) crystallized (meth)acrylic acid is separated from the mother liquor; c) at least part of the separated (meth)acrylic acid crystals are melted; d) the melted part is at least partially recycled to the step a) or step b). The superabsorbent polymer according to the present invention includes an process to make (meth)acrylic acid, the apparatus suitable for implementing the process, and the use of the apparatus for the production of (meth)acrylic acid characterized by a high purity of the thereby obtainable (meth)acrylic acid as well as by a high efficiency with regard to the achievable yield and necessary energy requirement, thereby providing an improved superabsorbent polymer.Type: GrantFiled: September 13, 2010Date of Patent: June 21, 2011Assignee: Evonik Stockhausen GmbHInventors: Stefan Nordhoff, Axel Kobus, Stefan Gross, Hans-Rolf Lausch, Torsten Balduf, Roland Fornika, Guenther Bub
-
Patent number: 7939597Abstract: The present invention relates to a process for production of acrylic acid, comprising the steps of a) dehydration of glycerine to an acrolein-comprising dehydration product; b) gas phase oxidation of the dehydration product to obtain an acrylic acid-comprising monomer gas; c) bringing into contact of the monomer gas with a quench agent to obtain an acrylic acid-comprising quench phase; and d) work-up of the quench phase to obtain an acrylic acid-comprising monomer phase; whereby, during the dehydration a liquid phase a1 and a gas phase a2 is present, whereby in the liquid phase a1 a plurality of gas bubbles is generated, as well as a process for production of polymers by polymerization of acrylic acid, preferably for production of water-absorbing polymers, the water-absorbing polymers obtainable by this process, a composite, a process for production of a composite, the composite obtainable by this process, and further chemical products.Type: GrantFiled: August 22, 2007Date of Patent: May 10, 2011Assignee: Evonik Stockhausen GmbHInventors: Günther Bub, Jürgen Mosler, Franz-Felix Kuppinger, Andreas Sabbagh, Guido Stochniol, Jörg Sauer, Markus Winterberg, Udo Knippenberg, Günter Latoschinski, Franck Furno, Thorsten Schwärtzke, Jörg Leistner
-
Patent number: 7893134Abstract: A process for producing an absorbent polymer including a first mixing event, in which a plurality of absorbent polymer particles (1) are mixed with a liquid (2) and a second mixing event, in which the liquid (2) is homogenized within the interior of the polymer particles. The polymer particles (1) in the first mixing event are mixed with a speed such that the kinetic energy of the individual polymer particles (1) is on average larger than the adhesion energy of the individual polymer particles (1), and the polymer particles (1) in the second mixing event are stirred at a lower speed than in the first mixing event. The different speeds effect a fluidization of the polymer particles (1), which prevents a clumping of the polymer particles (1) during the mixing event. The absorbent polymers thus produced are distinguished by a particularly rapid swelling behavior.Type: GrantFiled: April 27, 2009Date of Patent: February 22, 2011Assignee: Evonik Stockhausen GmbHInventors: Armin Reimann, Manfred Van Stiphoudt, Herbert Vorholt
-
Publication number: 20110021398Abstract: The invention relates to skin and hand cleansers comprising the components a.) at least one alkyl ester and/or diester, b.) 0 to 40 wt.-% of at least one surfactant selected from the group of fatty alcohol ethoxylates, fatty alcohol ether sulfates and salts of sulfated and/pr sulfonated fatty acids, c.) at least one thixotropic agent and at least one hydrophilic, pyrogenic silicic acid, d.) 0 to 30 wt.-% of one or more abrasives, e.) 0 to 5 wt.-% of at least one physiologically compatible carbonic acid ester f.) 0 to <10 wt.-% water, g.) optionally one or more viscosity modifying agent, h.) optionally other cosmetic aids, additives and/or active ingredients, wherein the total of the components a.) through h.) adds up to 100 wt.-%, based on the composition of the cleanser.Type: ApplicationFiled: May 13, 2009Publication date: January 27, 2011Applicant: EVONIK STOCKHAUSEN GMBHInventors: Petra Allef, Marcel Veeger, Markus Hemming
-
Patent number: 7863338Abstract: Absorbent polymer granulate comprising the following process steps: i) polymerization of an aqueous monomer solution to obtain a polymer gel; ii) comminution of the polymer gel to obtain a gel granulate; and iii) drying of the gel granulate, and is characterized in that the gel granulate after step ii) has a spread behavior. The production process of an absorbent polymer distinguishes itself by a particularly efficient drying step iii), which enables a particularly gentle and uniform drying of the gel granulate. The obtained absorbent polymers and products and items produced therefrom have a particularly uniform product quality and constant physical-chemical properties.Type: GrantFiled: April 19, 2010Date of Patent: January 4, 2011Assignee: Evonik Stockhausen GmbHInventors: Volker Becker, Heinz-Peter Grupe, Detlef Jung, Armin Reimann
-
Patent number: 7842386Abstract: A process for producing and a powdery water-absorbing polymers comprising: about 0.01 to 20 wt. % of a fine particle with a particle size of less than about 200 ?m; about 0.001 to 10 wt. % of a thermoplastic adhesive; and about 60 to 99.998 wt. % of a water-absorbing polymer particle with a particle size of about 200 ?m and above, wherein the powdery water-absorbing polymers have: a flow value (FFC) within the range from about 1 to 13, and/or a dust portion of at most about 6 are disclosed. Also disclosed are a transport process, a composite, chemical products, and a use of a thermoplastic adhesive.Type: GrantFiled: July 22, 2004Date of Patent: November 30, 2010Assignee: Evonik Stockhausen GmbHInventors: Frank Loeker, Heinz Bremus, Scott Smith
-
Patent number: 7811458Abstract: The invention relates to a method for the accelerated dehydration of sludges in sludge disposal areas, especially of sludges from rivers and harbors, by the exclusive use of anionic polymer flocculants and the use of materials obtained according to the inventive method.Type: GrantFiled: June 4, 2009Date of Patent: October 12, 2010Assignees: Stockhausen GmbH & Co. KG, Detlef Hegeman GmbH & Co. KGInventors: Thorsten Buddenberg, Holger Herrmann, Hartmut Pawel, Otto Schroers, Wolfgang Hoeppner, Volker Hartmann
-
Patent number: 7803969Abstract: The invention relates to a process for the purification of (meth)acrylic acid in a process stage that comprises the following process steps: a) (meth)acrylic acid is crystallized out from a mother liquor; b) crystallized (meth)acrylic acid is separated from the mother liquor; c) at least part of the separated (meth)acrylic acid crystals are melted; d) the melted part is at least partially recycled to the step a) or step b). The process according to the invention, the apparatus suitable for implementing the process, and the use of the apparatus according to the invention for the production of (meth)acrylic acid are characterized by a high purity of the thereby obtainable (meth)acrylic acid as well as by a high efficiency with regard to the achievable yield and necessary energy requirement.Type: GrantFiled: January 14, 2002Date of Patent: September 28, 2010Assignee: Evonik Stockhausen GmbHInventors: Stefan Nordhoff, Axel Kobus, Stefan Gross, Hans-Rolf Lausch, Torsten Balduf, Roland Fornika, Guenther Bub
-
Publication number: 20100210499Abstract: The invention relates to skin cleansers/hand cleaners, particularly coarse hand cleaners, containing at least 0.1 wt. % of at least one hydrophilic emollient having an HLB value of ?10. Said skin cleansers/ hand cleaners especially contain, relative to the entire composition of the cleanser/cleaner, a.) at least 0.1 wt. % of at least one hydrophilic emollient, preferably a polyol ester, b.) 2 to 40 wt. % of at least one surfactant selected from among the group comprising fatty alcohol ethoxylates, fatty alcohol ether sulfates, and salts of sulfated and/or sulfonated fatty acids, c.) 30 to 90 wt. % of water, d.) 0 to 30 wt. % of one or more cleaning promoters selected from among the group comprising polyols, polyether, polyphosphates, and phosphates, e.) 0 to 30 wt. % of one or more abrasive agents, f.) 0 to 1.0 wt. % of propoxylated fatty alcohols, g.) one or more optional viscosity-forming agents, h.) other optional cosmetic auxiliary agents, additives, and/or active substances, the total of components a.Type: ApplicationFiled: April 22, 2008Publication date: August 19, 2010Applicant: Evonik Stockhausen GmbHInventors: Petra Allef, Volker Klotzbach, Marcel Veeger
-
Patent number: 7776984Abstract: Among other things, a process for producing an agglomerated superabsorbent polymer particle and an agglomerated superabsorbent polymer particle are disclosed. The process comprises the steps of: (A) bringing superabsorbent polymer fine particles having at least about 40 wt. %, a particle size of less than about 150 ?m into contact with a fluid comprising to more than about 10 wt. % a cross-linkable, uncrosslinked polymer based on polymerized, ethylenically unsaturated, acid group-bearing monomers or salts thereof; and (B) cross-linking the uncrosslinked polymer by heating the superabsorbent polymer fine particles and the fluid to a temperature from about 20 to about 300° C., so that the cross-linkable, uncrosslinked polymer at least partially crosslinks.Type: GrantFiled: July 22, 2004Date of Patent: August 17, 2010Assignee: Evonik Stockhausen GmbHInventor: Markus Frank
-
Publication number: 20100139159Abstract: The invention relates to a method for ground cultivation, in particular of green spaces and existing areas of vegetation, comprising the following steps: a.) production of a conveyable application form of a soil conditioner in which the soil conditioner is present as a dispersion of pre-swollen particles and/or as hydrogel; b.) conveyance of the application form of the soil conditioner produced in step a.) to a depositing device; c.) depositing of the soil conditioner by means of a depositing device, and a device for carrying out such a cultivation method.Type: ApplicationFiled: April 4, 2008Publication date: June 10, 2010Applicant: Evonik Stockhausen GmbhInventor: Dietmar Plate
-
Patent number: 7728045Abstract: The process according to the invention for production of an absorbent polymer comprising the following process steps: i) polymerization of an aqueous monomer solution to obtain a polymer gel; ii) comminution of the polymer gel to obtain a gel granulate; and iii) drying of the gel granulate, and is characterized in that the gel granulate after step ii) has a spread behavior. The production process of an absorbent polymer distinguishes itself by a particularly efficient drying step iii), which enables a particularly gentle and uniform drying of the gel granulate. The obtained absorbent polymers and products and items produced therefrom have a particularly uniform product quality and constant physical-chemical properties.Type: GrantFiled: April 20, 2005Date of Patent: June 1, 2010Assignee: Evonik Stockhausen GmbHInventors: Volker Becker, Heinz-Peter Grupe, Detlef Jung, Armin Reimann
-
Publication number: 20100069505Abstract: An alcoholic foam composition, which can be dispensed as a foam via a pump-foam system contains a) at least 52 to ?99 wt % of an alcohol or mixture of alcohols, b) a surfactant or a surfactant mixture, c) at least one polyalkylene glycol, d) optionally, at least one foam stabilizer, e) optionally, at least one member selected from the group consisting of cosmetic auxiliaries, adjuvants, active ingredients, and mixtures thereof, and f) optionally water. The surface tension of component b) lies in the range of ±15 dyn/cm of the surface tension of component a) or corresponds to the surface tension of component a), and the sum of components a) to f) is 100 wt % relative to the total quantity of the foam composition.Type: ApplicationFiled: November 23, 2009Publication date: March 18, 2010Applicant: Stockhausen GmbHInventors: Marcel Veeger, Markus Himming
-
Patent number: 7670615Abstract: An alcoholic foam composition, which can be dispensed as a foam via a pump-foam system contains a) at least 52 to ?99 wt % of an alcohol or mixture of alcohols, b) a surfactant or a surfactant mixture, c) at least one polyalkylene glycol, d) optionally, at least one foam stabilizer, e) optionally, at least one member selected from the group consisting of cosmetic auxiliaries, adjuvants, active ingredients, and mixtures thereof, and f) optionally water. The surface tension of component b) lies in the range of ±15 dyn/cm of the surface tension of component a) or corresponds to the surface tension of component a), and the sum of components a) to f) is 100 wt % relative to the total quantity of the foam composition.Type: GrantFiled: December 21, 2005Date of Patent: March 2, 2010Assignee: Stockhausen GmbHInventors: Marcel Veeger, Markus Himming
-
Publication number: 20090318570Abstract: The invention relates to a silicone-free skin protection composition, in particular a composition to protect against cold, containing the components a.) at least one oil with a pour point in accordance with DIN ISO 30 16 of ??10° C., b.) at least one polyol c.) at least one emulsifier d.) optionally at least one wax, where the viscosity difference in the temperature interval from +4° C. to +50° C. of highest and lowest viscosity of the skin protection composition has a value in the range from 0 to ?20 000 mPas.Type: ApplicationFiled: November 9, 2007Publication date: December 24, 2009Applicant: Evonik Stockhausen GmbHInventors: Marcel Veeger, Petra Allef
-
Patent number: 7625957Abstract: Water-absorbing, antimicrobial polymer particles comprising from about 1 to about 500 ppm, based on the particles, of a silver ion based on a silver salt, wherein the silver salt has a solubility product of at least about 1×10?8 (mol/l)m+n; at least about 10 wt. %, based on the polymer particle, of a water-absorbing polymer based on: (?1) from about 50 to about 99.99 wt. % polymerized, ethylenically unsaturated, acid groups-containing monomers or salts thereof, (?2) 0 to about 40 wt. % polymerized, mono-ethylenically unsaturated monomers polymerizable with ?1, (?3) from about 0.01 to about 5 wt. %, preferably from about 0.1 to about 3 wt. % of one or more crosslinkers, (?4) 0 to about 30 wt. % of a water soluble polymer and (?5) 0 to about 20 wt. % of auxiliaries, the concentration of the silver ion based on a silver salt in at most about 90 vol. % of the particles is less than about 0.01 ppm.Type: GrantFiled: April 23, 2003Date of Patent: December 1, 2009Assignee: Stockhausen GmbHInventors: Jörg Harren, Jörg Issberner, Harald Schmidt
-
Patent number: 7612016Abstract: The invention describes superabsorbent polymers composed of surface-post crosslinked polycarboxypolysaccharides having excellent age-stable absorption properties, even under load, high attrition resistance and biodegradability and their use for absorbing water, aqueous or serous fluids and also blood. Also disclosed is a method of making which is impervious to changes in raw material quality and which provides consistent product quality.Type: GrantFiled: June 26, 2008Date of Patent: November 3, 2009Assignee: Evonik Stockhausen GmbHInventors: Richard Mertens, Olaf Höller
-
Patent number: 7608208Abstract: The current invention relates to water-swellable polymers at least partially comprised of sulfonic acid group containing monomers as additives for fire extinguishing water, which exhibits an elevated NaCl content, used in fire prevention and to combat fire.Type: GrantFiled: February 8, 2002Date of Patent: October 27, 2009Assignee: Evonik Stockhausen GmbHInventors: Jochen Houben, Erich Küster, Martin Tennie
-
Publication number: 20090236562Abstract: The invention relates to a method for the accelerated dehydration of sludges in sludge disposal areas, especially of sludges from rivers and harbors, by the exclusive use of anionic polymer flocculants and the use of materials obtained according to the inventive method.Type: ApplicationFiled: June 4, 2009Publication date: September 24, 2009Applicants: Stockhausen GmbH & Co., KG, Detlef Hegemann GmbH & Co KgInventors: Thorsten Buddenberg, Holger Herrmann, Hartmut Pawel, Otto Schroers, Wolfgang Hoeppner, Volker Hartmann
-
Patent number: 7557245Abstract: The present invention relates to processes for purifying a composition containing (meth)acrylic acid, at least one impurity and water, wherein the composition has a water content in the range of 0.55 to 90, based on the composition, to form a purified phase containing (meth)acrylic acid and at least one impurity, wherein, in the purified phase, the quantity of at least one impurity is less than 7% by weight, based on (meth)acrylic acid in the purified phase.Type: GrantFiled: March 17, 2003Date of Patent: July 7, 2009Assignee: Evonik Stockhausen GmbHInventors: Stefan Nordhoff, Torsten Balduf, Gunther Bub, Roland Fornika, Jurgen Mosler, Thomas Rathke, Axel Kobus, Dennis Thong