Patents Assigned to Stockhausen GmbH
  • Patent number: 7964689
    Abstract: The invention relates to a superabsorbent polymer that includes a (meth)acrylic acid made by a process that comprises the following process steps: a) (meth)acrylic acid is crystallized out from a mother liquor; b) crystallized (meth)acrylic acid is separated from the mother liquor; c) at least part of the separated (meth)acrylic acid crystals are melted; d) the melted part is at least partially recycled to the step a) or step b). The superabsorbent polymer according to the present invention includes an process to make (meth)acrylic acid, the apparatus suitable for implementing the process, and the use of the apparatus for the production of (meth)acrylic acid characterized by a high purity of the thereby obtainable (meth)acrylic acid as well as by a high efficiency with regard to the achievable yield and necessary energy requirement, thereby providing an improved superabsorbent polymer.
    Type: Grant
    Filed: September 13, 2010
    Date of Patent: June 21, 2011
    Assignee: Evonik Stockhausen GmbH
    Inventors: Stefan Nordhoff, Axel Kobus, Stefan Gross, Hans-Rolf Lausch, Torsten Balduf, Roland Fornika, Guenther Bub
  • Patent number: 7939597
    Abstract: The present invention relates to a process for production of acrylic acid, comprising the steps of a) dehydration of glycerine to an acrolein-comprising dehydration product; b) gas phase oxidation of the dehydration product to obtain an acrylic acid-comprising monomer gas; c) bringing into contact of the monomer gas with a quench agent to obtain an acrylic acid-comprising quench phase; and d) work-up of the quench phase to obtain an acrylic acid-comprising monomer phase; whereby, during the dehydration a liquid phase a1 and a gas phase a2 is present, whereby in the liquid phase a1 a plurality of gas bubbles is generated, as well as a process for production of polymers by polymerization of acrylic acid, preferably for production of water-absorbing polymers, the water-absorbing polymers obtainable by this process, a composite, a process for production of a composite, the composite obtainable by this process, and further chemical products.
    Type: Grant
    Filed: August 22, 2007
    Date of Patent: May 10, 2011
    Assignee: Evonik Stockhausen GmbH
    Inventors: Günther Bub, Jürgen Mosler, Franz-Felix Kuppinger, Andreas Sabbagh, Guido Stochniol, Jörg Sauer, Markus Winterberg, Udo Knippenberg, Günter Latoschinski, Franck Furno, Thorsten Schwärtzke, Jörg Leistner
  • Patent number: 7893134
    Abstract: A process for producing an absorbent polymer including a first mixing event, in which a plurality of absorbent polymer particles (1) are mixed with a liquid (2) and a second mixing event, in which the liquid (2) is homogenized within the interior of the polymer particles. The polymer particles (1) in the first mixing event are mixed with a speed such that the kinetic energy of the individual polymer particles (1) is on average larger than the adhesion energy of the individual polymer particles (1), and the polymer particles (1) in the second mixing event are stirred at a lower speed than in the first mixing event. The different speeds effect a fluidization of the polymer particles (1), which prevents a clumping of the polymer particles (1) during the mixing event. The absorbent polymers thus produced are distinguished by a particularly rapid swelling behavior.
    Type: Grant
    Filed: April 27, 2009
    Date of Patent: February 22, 2011
    Assignee: Evonik Stockhausen GmbH
    Inventors: Armin Reimann, Manfred Van Stiphoudt, Herbert Vorholt
  • Publication number: 20110021398
    Abstract: The invention relates to skin and hand cleansers comprising the components a.) at least one alkyl ester and/or diester, b.) 0 to 40 wt.-% of at least one surfactant selected from the group of fatty alcohol ethoxylates, fatty alcohol ether sulfates and salts of sulfated and/pr sulfonated fatty acids, c.) at least one thixotropic agent and at least one hydrophilic, pyrogenic silicic acid, d.) 0 to 30 wt.-% of one or more abrasives, e.) 0 to 5 wt.-% of at least one physiologically compatible carbonic acid ester f.) 0 to <10 wt.-% water, g.) optionally one or more viscosity modifying agent, h.) optionally other cosmetic aids, additives and/or active ingredients, wherein the total of the components a.) through h.) adds up to 100 wt.-%, based on the composition of the cleanser.
    Type: Application
    Filed: May 13, 2009
    Publication date: January 27, 2011
    Applicant: EVONIK STOCKHAUSEN GMBH
    Inventors: Petra Allef, Marcel Veeger, Markus Hemming
  • Patent number: 7863338
    Abstract: Absorbent polymer granulate comprising the following process steps: i) polymerization of an aqueous monomer solution to obtain a polymer gel; ii) comminution of the polymer gel to obtain a gel granulate; and iii) drying of the gel granulate, and is characterized in that the gel granulate after step ii) has a spread behavior. The production process of an absorbent polymer distinguishes itself by a particularly efficient drying step iii), which enables a particularly gentle and uniform drying of the gel granulate. The obtained absorbent polymers and products and items produced therefrom have a particularly uniform product quality and constant physical-chemical properties.
    Type: Grant
    Filed: April 19, 2010
    Date of Patent: January 4, 2011
    Assignee: Evonik Stockhausen GmbH
    Inventors: Volker Becker, Heinz-Peter Grupe, Detlef Jung, Armin Reimann
  • Patent number: 7842386
    Abstract: A process for producing and a powdery water-absorbing polymers comprising: about 0.01 to 20 wt. % of a fine particle with a particle size of less than about 200 ?m; about 0.001 to 10 wt. % of a thermoplastic adhesive; and about 60 to 99.998 wt. % of a water-absorbing polymer particle with a particle size of about 200 ?m and above, wherein the powdery water-absorbing polymers have: a flow value (FFC) within the range from about 1 to 13, and/or a dust portion of at most about 6 are disclosed. Also disclosed are a transport process, a composite, chemical products, and a use of a thermoplastic adhesive.
    Type: Grant
    Filed: July 22, 2004
    Date of Patent: November 30, 2010
    Assignee: Evonik Stockhausen GmbH
    Inventors: Frank Loeker, Heinz Bremus, Scott Smith
  • Patent number: 7811458
    Abstract: The invention relates to a method for the accelerated dehydration of sludges in sludge disposal areas, especially of sludges from rivers and harbors, by the exclusive use of anionic polymer flocculants and the use of materials obtained according to the inventive method.
    Type: Grant
    Filed: June 4, 2009
    Date of Patent: October 12, 2010
    Assignees: Stockhausen GmbH & Co. KG, Detlef Hegeman GmbH & Co. KG
    Inventors: Thorsten Buddenberg, Holger Herrmann, Hartmut Pawel, Otto Schroers, Wolfgang Hoeppner, Volker Hartmann
  • Patent number: 7803969
    Abstract: The invention relates to a process for the purification of (meth)acrylic acid in a process stage that comprises the following process steps: a) (meth)acrylic acid is crystallized out from a mother liquor; b) crystallized (meth)acrylic acid is separated from the mother liquor; c) at least part of the separated (meth)acrylic acid crystals are melted; d) the melted part is at least partially recycled to the step a) or step b). The process according to the invention, the apparatus suitable for implementing the process, and the use of the apparatus according to the invention for the production of (meth)acrylic acid are characterized by a high purity of the thereby obtainable (meth)acrylic acid as well as by a high efficiency with regard to the achievable yield and necessary energy requirement.
    Type: Grant
    Filed: January 14, 2002
    Date of Patent: September 28, 2010
    Assignee: Evonik Stockhausen GmbH
    Inventors: Stefan Nordhoff, Axel Kobus, Stefan Gross, Hans-Rolf Lausch, Torsten Balduf, Roland Fornika, Guenther Bub
  • Publication number: 20100210499
    Abstract: The invention relates to skin cleansers/hand cleaners, particularly coarse hand cleaners, containing at least 0.1 wt. % of at least one hydrophilic emollient having an HLB value of ?10. Said skin cleansers/ hand cleaners especially contain, relative to the entire composition of the cleanser/cleaner, a.) at least 0.1 wt. % of at least one hydrophilic emollient, preferably a polyol ester, b.) 2 to 40 wt. % of at least one surfactant selected from among the group comprising fatty alcohol ethoxylates, fatty alcohol ether sulfates, and salts of sulfated and/or sulfonated fatty acids, c.) 30 to 90 wt. % of water, d.) 0 to 30 wt. % of one or more cleaning promoters selected from among the group comprising polyols, polyether, polyphosphates, and phosphates, e.) 0 to 30 wt. % of one or more abrasive agents, f.) 0 to 1.0 wt. % of propoxylated fatty alcohols, g.) one or more optional viscosity-forming agents, h.) other optional cosmetic auxiliary agents, additives, and/or active substances, the total of components a.
    Type: Application
    Filed: April 22, 2008
    Publication date: August 19, 2010
    Applicant: Evonik Stockhausen GmbH
    Inventors: Petra Allef, Volker Klotzbach, Marcel Veeger
  • Patent number: 7776984
    Abstract: Among other things, a process for producing an agglomerated superabsorbent polymer particle and an agglomerated superabsorbent polymer particle are disclosed. The process comprises the steps of: (A) bringing superabsorbent polymer fine particles having at least about 40 wt. %, a particle size of less than about 150 ?m into contact with a fluid comprising to more than about 10 wt. % a cross-linkable, uncrosslinked polymer based on polymerized, ethylenically unsaturated, acid group-bearing monomers or salts thereof; and (B) cross-linking the uncrosslinked polymer by heating the superabsorbent polymer fine particles and the fluid to a temperature from about 20 to about 300° C., so that the cross-linkable, uncrosslinked polymer at least partially crosslinks.
    Type: Grant
    Filed: July 22, 2004
    Date of Patent: August 17, 2010
    Assignee: Evonik Stockhausen GmbH
    Inventor: Markus Frank
  • Publication number: 20100139159
    Abstract: The invention relates to a method for ground cultivation, in particular of green spaces and existing areas of vegetation, comprising the following steps: a.) production of a conveyable application form of a soil conditioner in which the soil conditioner is present as a dispersion of pre-swollen particles and/or as hydrogel; b.) conveyance of the application form of the soil conditioner produced in step a.) to a depositing device; c.) depositing of the soil conditioner by means of a depositing device, and a device for carrying out such a cultivation method.
    Type: Application
    Filed: April 4, 2008
    Publication date: June 10, 2010
    Applicant: Evonik Stockhausen Gmbh
    Inventor: Dietmar Plate
  • Patent number: 7728045
    Abstract: The process according to the invention for production of an absorbent polymer comprising the following process steps: i) polymerization of an aqueous monomer solution to obtain a polymer gel; ii) comminution of the polymer gel to obtain a gel granulate; and iii) drying of the gel granulate, and is characterized in that the gel granulate after step ii) has a spread behavior. The production process of an absorbent polymer distinguishes itself by a particularly efficient drying step iii), which enables a particularly gentle and uniform drying of the gel granulate. The obtained absorbent polymers and products and items produced therefrom have a particularly uniform product quality and constant physical-chemical properties.
    Type: Grant
    Filed: April 20, 2005
    Date of Patent: June 1, 2010
    Assignee: Evonik Stockhausen GmbH
    Inventors: Volker Becker, Heinz-Peter Grupe, Detlef Jung, Armin Reimann
  • Publication number: 20100069505
    Abstract: An alcoholic foam composition, which can be dispensed as a foam via a pump-foam system contains a) at least 52 to ?99 wt % of an alcohol or mixture of alcohols, b) a surfactant or a surfactant mixture, c) at least one polyalkylene glycol, d) optionally, at least one foam stabilizer, e) optionally, at least one member selected from the group consisting of cosmetic auxiliaries, adjuvants, active ingredients, and mixtures thereof, and f) optionally water. The surface tension of component b) lies in the range of ±15 dyn/cm of the surface tension of component a) or corresponds to the surface tension of component a), and the sum of components a) to f) is 100 wt % relative to the total quantity of the foam composition.
    Type: Application
    Filed: November 23, 2009
    Publication date: March 18, 2010
    Applicant: Stockhausen GmbH
    Inventors: Marcel Veeger, Markus Himming
  • Patent number: 7670615
    Abstract: An alcoholic foam composition, which can be dispensed as a foam via a pump-foam system contains a) at least 52 to ?99 wt % of an alcohol or mixture of alcohols, b) a surfactant or a surfactant mixture, c) at least one polyalkylene glycol, d) optionally, at least one foam stabilizer, e) optionally, at least one member selected from the group consisting of cosmetic auxiliaries, adjuvants, active ingredients, and mixtures thereof, and f) optionally water. The surface tension of component b) lies in the range of ±15 dyn/cm of the surface tension of component a) or corresponds to the surface tension of component a), and the sum of components a) to f) is 100 wt % relative to the total quantity of the foam composition.
    Type: Grant
    Filed: December 21, 2005
    Date of Patent: March 2, 2010
    Assignee: Stockhausen GmbH
    Inventors: Marcel Veeger, Markus Himming
  • Publication number: 20090318570
    Abstract: The invention relates to a silicone-free skin protection composition, in particular a composition to protect against cold, containing the components a.) at least one oil with a pour point in accordance with DIN ISO 30 16 of ??10° C., b.) at least one polyol c.) at least one emulsifier d.) optionally at least one wax, where the viscosity difference in the temperature interval from +4° C. to +50° C. of highest and lowest viscosity of the skin protection composition has a value in the range from 0 to ?20 000 mPas.
    Type: Application
    Filed: November 9, 2007
    Publication date: December 24, 2009
    Applicant: Evonik Stockhausen GmbH
    Inventors: Marcel Veeger, Petra Allef
  • Patent number: 7625957
    Abstract: Water-absorbing, antimicrobial polymer particles comprising from about 1 to about 500 ppm, based on the particles, of a silver ion based on a silver salt, wherein the silver salt has a solubility product of at least about 1×10?8 (mol/l)m+n; at least about 10 wt. %, based on the polymer particle, of a water-absorbing polymer based on: (?1) from about 50 to about 99.99 wt. % polymerized, ethylenically unsaturated, acid groups-containing monomers or salts thereof, (?2) 0 to about 40 wt. % polymerized, mono-ethylenically unsaturated monomers polymerizable with ?1, (?3) from about 0.01 to about 5 wt. %, preferably from about 0.1 to about 3 wt. % of one or more crosslinkers, (?4) 0 to about 30 wt. % of a water soluble polymer and (?5) 0 to about 20 wt. % of auxiliaries, the concentration of the silver ion based on a silver salt in at most about 90 vol. % of the particles is less than about 0.01 ppm.
    Type: Grant
    Filed: April 23, 2003
    Date of Patent: December 1, 2009
    Assignee: Stockhausen GmbH
    Inventors: Jörg Harren, Jörg Issberner, Harald Schmidt
  • Patent number: 7612016
    Abstract: The invention describes superabsorbent polymers composed of surface-post crosslinked polycarboxypolysaccharides having excellent age-stable absorption properties, even under load, high attrition resistance and biodegradability and their use for absorbing water, aqueous or serous fluids and also blood. Also disclosed is a method of making which is impervious to changes in raw material quality and which provides consistent product quality.
    Type: Grant
    Filed: June 26, 2008
    Date of Patent: November 3, 2009
    Assignee: Evonik Stockhausen GmbH
    Inventors: Richard Mertens, Olaf Höller
  • Patent number: 7608208
    Abstract: The current invention relates to water-swellable polymers at least partially comprised of sulfonic acid group containing monomers as additives for fire extinguishing water, which exhibits an elevated NaCl content, used in fire prevention and to combat fire.
    Type: Grant
    Filed: February 8, 2002
    Date of Patent: October 27, 2009
    Assignee: Evonik Stockhausen GmbH
    Inventors: Jochen Houben, Erich Küster, Martin Tennie
  • Publication number: 20090236562
    Abstract: The invention relates to a method for the accelerated dehydration of sludges in sludge disposal areas, especially of sludges from rivers and harbors, by the exclusive use of anionic polymer flocculants and the use of materials obtained according to the inventive method.
    Type: Application
    Filed: June 4, 2009
    Publication date: September 24, 2009
    Applicants: Stockhausen GmbH & Co., KG, Detlef Hegemann GmbH & Co Kg
    Inventors: Thorsten Buddenberg, Holger Herrmann, Hartmut Pawel, Otto Schroers, Wolfgang Hoeppner, Volker Hartmann
  • Patent number: 7557245
    Abstract: The present invention relates to processes for purifying a composition containing (meth)acrylic acid, at least one impurity and water, wherein the composition has a water content in the range of 0.55 to 90, based on the composition, to form a purified phase containing (meth)acrylic acid and at least one impurity, wherein, in the purified phase, the quantity of at least one impurity is less than 7% by weight, based on (meth)acrylic acid in the purified phase.
    Type: Grant
    Filed: March 17, 2003
    Date of Patent: July 7, 2009
    Assignee: Evonik Stockhausen GmbH
    Inventors: Stefan Nordhoff, Torsten Balduf, Gunther Bub, Roland Fornika, Jurgen Mosler, Thomas Rathke, Axel Kobus, Dennis Thong