Patents Assigned to Sumitomo Metal Mining Co., Ltd.
  • Patent number: 11973223
    Abstract: Provided is a precursor of a positive electrode active material for non-aqueous electrolyte secondary batteries which allows a non-aqueous electrolyte secondary battery to have excellent battery characteristics. A manganese composite hydroxide is obtained by adjusting the pH value of an aqueous solution for nucleation containing cobalt and/or manganese to 7.5 to 11.1 on the basis of a liquid temperature of 25° C. to form plate-shaped crystal nuclei, and adjusting the pH value of a slurry for particle growth containing the plate-shaped crystal nuclei to 10.5 to 12.5 on the basis of a liquid temperature of 25° C., and supplying a mixed aqueous solution including a metal compound containing at least manganese to the slurry, thereby performing particle growth of the plate-shaped crystal nuclei.
    Type: Grant
    Filed: August 19, 2020
    Date of Patent: April 30, 2024
    Assignee: SUMITOMO METAL MINING CO., LTD.
    Inventors: Kazuomi Ryoshi, Kensaku Mori
  • Patent number: 11967700
    Abstract: A non-aqueous electrolyte secondary battery that has a low initial resistance and an increase in resistance after charging and discharging is suppressed. The secondary battery includes a positive electrode, a negative electrode, and a non-aqueous electrolyte. The positive electrode includes a positive electrode active substance layer, which contains a lithium composite oxide having a layered structure. The lithium composite oxide is a porous particle. A surface of the porous particle includes a layer having a rock salt type structure. A thickness of the layer is not less than 5 nm and not more than 80 nm. A void ratio of the porous particle is not less than 15% and not more than 48%. The porous particle contains two or more voids having diameters that are at least 10% of the particle diameter of the porous particle. The surface of the porous particle includes a coating of lithium tungstate.
    Type: Grant
    Filed: July 10, 2020
    Date of Patent: April 23, 2024
    Assignees: TOYOTA JIDOSHA KABUSHIKI KAISHA, SUMITOMO METAL MINING CO., LTD.
    Inventors: Yuji Yamamoto, Momoko Procter, Yoshinari Makimura, Tetsutaro Hayashi, Willy Shun Kai Bong
  • Patent number: 11967713
    Abstract: The present invention relates to a positive electrode active material for non-aqueous electrolyte secondary battery, including lithium-nickel composite oxide particles having a layer structure of hexagonal system; and a lithium tungstate coating film disposed on a surface of secondary particles of the lithium-nickel composite oxide particles, wherein the positive electrode active material for non-aqueous electrolyte secondary battery includes, as metallic elements, lithium (Li), nickel (Ni), cobalt (Co), element M (M) which is at least one element selected from Mn, V, Mg, Mo, Nb, Ti, Ca, Cr, Zr, Ta, and Al, and tungsten (W), wherein a ratio of amount of substance in the metallic elements contained is Li:Ni:Co:M:W=a:1-x-y:x:y:z, wherein 0.97?a?1.25, 0?x?0.35, 0?y?0.35, and 0.005?z?0.030.
    Type: Grant
    Filed: May 29, 2019
    Date of Patent: April 23, 2024
    Assignee: SUMITOMO METAL MINING CO., LTD.
    Inventors: Yuki Koshika, Haruki Kaneda, Jun Yokoyama
  • Patent number: 11967709
    Abstract: The present invention provides a composite oxide that can achieve a high low-temperature output characteristic, a method for manufacturing the same, and a positive electrode active material in which the generation of soluble lithium is suppressed and a problem of gelation is not caused during the paste preparation. A positive electrode active material for non-aqueous electrolyte secondary batteries, including a lithium-metal composite oxide powder including a secondary particle configured by aggregating primary particles containing lithium, nickel, manganese, and cobalt, or a lithium-metal composite oxide powder including both the primary particles and the secondary particle, wherein the secondary particle has a hollow structure inside as a main inside structure, the slurry pH is 11.5 or less, the soluble lithium content rate is 0.5 [% by mass] or less, the specific surface area is 2.0 to 3.0 [m2/g], and the porosity is 20 to 50 [%].
    Type: Grant
    Filed: July 31, 2018
    Date of Patent: April 23, 2024
    Assignee: SUMITOMO METAL MINING CO., LTD.
    Inventors: Hiroko Oshita, Kazuomi Ryoshi, Taira Aida, Koji Yamaji, Jiro Okada
  • Publication number: 20240130241
    Abstract: The magnetostrictive member is formed of a single crystal of an iron-based alloy having magnetostrictive characteristics, is a plate-like body having a long-side direction and a short-side direction, and has a lattice constant of a <100> orientation in the short-side direction larger than a lattice constant of a <100> orientation in the long-side direction.
    Type: Application
    Filed: February 4, 2022
    Publication date: April 18, 2024
    Applicant: SUMITOMO METAL MINING CO., LTD.
    Inventors: Kazuhiko Okubo, Kazutaka Osako, Kiyoshi Izumi
  • Patent number: 11959151
    Abstract: Provided is a method for separating copper from nickel and cobalt, which is capable of efficiently and selectively separating copper, and nickel and cobalt from an alloy containing copper, nickel and cobalt such as a highly anticorrosive alloy that is obtained by subjecting a waste lithium ion battery to a dry treatment and contains copper, nickel and cobalt. According to the present invention, an alloy containing copper, nickel and cobalt is brought into contact with an acid in the coexistence of a sulfurization agent, thereby obtaining a solid that contains copper and a leachate that contains nickel and cobalt.
    Type: Grant
    Filed: August 21, 2018
    Date of Patent: April 16, 2024
    Assignee: SUMITOMO METAL MINING CO., LTD.
    Inventors: Tatsuya Higaki, Hiroshi Takenouchi, Hiroshi Kobayashi, Satoshi Asano
  • Patent number: 11962000
    Abstract: A non-aqueous electrolyte secondary battery is obtained using a lithium composite oxide having a layered structure in a positive electrode active substance. An increase in resistance following repeated charging and discharging is suppressed. The battery includes a positive electrode provided with a positive electrode active substance layer, a negative electrode and a non-aqueous electrolyte. The positive electrode active substance layer contains a porous particle lithium composite oxide having a layered structure. The average void ratio of the porous particle is not less than 12% but not more than 50%, and it contains two or more voids having diameters that are at least 8% of its particle diameter. The surface of the porous particle is provided with a coating of lithium tungstate. The coverage ratio of the surface of the porous particle by the lithium tungstate is not less than 10% but not more than 65%.
    Type: Grant
    Filed: July 10, 2020
    Date of Patent: April 16, 2024
    Assignees: TOYOTA JIDOSHA KABUSHIKI KAISHA, SUMITOMO METAL MINING CO., LTD.
    Inventors: Yuji Yamamoto, Momoko Procter, Yoshinari Makimura, Tetsutaro Hayashi, Willy Shun Kai Bong
  • Publication number: 20240117485
    Abstract: [Object] Provided is a sputtering target that makes it possible to set nCs/nW (film) expressing a ratio of Cs atoms to W atoms in a cesium tungsten oxide film formed by a sputtering method within such a desired range (0.3 or more to 0.36 or less) that the film can exhibit high transmittance in the visible wavelength region and absorption in the near-infrared wavelength region. [Solution] This target contains Cs and W. When [T?S distance] denotes a distance between the target and a substrate for film formation and P denotes a pressure in an atmosphere during film formation by sputtering and nW denotes the number of W atoms and nCs denotes the number of Cs atoms contained in the target, nCs/nW(T) expressing a ratio of Cs atoms to W atoms in the target satisfies the following (Formula 1) with respect to [T?S distance] and P: 0.09/{(?0.00161×[T?S distance]+0.00559)×P+0.346}?nCs/nW (T)?0.13/{(?0.00161×[T?S distance]+0.00559)×P+0.346} (Formula 1).
    Type: Application
    Filed: February 21, 2022
    Publication date: April 11, 2024
    Applicant: SUMITOMO METAL MINING Co., Ltd.,
    Inventor: Hideharu OKAMI
  • Patent number: 11949102
    Abstract: A positive electrode active material precursor for a nonaqueous electrolyte secondary battery is provided that includes a nickel-cobalt-manganese carbonate composite represented by general formula NixCoyMnzMtCO3 (where x+y+z+t=1, 0.05?x?0.3, 0.1?y?0.4, 0.55?z?0.8, 0?t?0.1, and M denotes at least one additional element selected from a group consisting of Mg, Ca, Al, Ti, V, Cr, Zr, Nb, Mo, and W) and a hydrogen-containing functional group. The ratio H/Me of the amount of hydrogen H to the amount of metal components Me included in the positive electrode active material precursor is less than 1.60. The positive electrode active material further includes a secondary particle formed by a plurality of primary particles that have been aggregated.
    Type: Grant
    Filed: November 17, 2021
    Date of Patent: April 2, 2024
    Assignee: SUMITOMO METAL MINING CO., LTD.
    Inventors: Satoshi Matsumoto, Kazuomi Ryoshi, Kikoo Uekusa
  • Publication number: 20240105935
    Abstract: Provided are a cathode active material having a suitable particle size and high uniformity, and a nickel composite hydroxide as a precursor of the cathode active material. When obtaining nickel composite hydroxide by a crystallization reaction, nucleation is performed by controlling a nucleation aqueous solution that includes a metal compound, which includes nickel, and an ammonium ion donor so that the pH value at a standard solution temperature of 25° C. becomes 12.0 to 14.0, after which, particles are grown by controlling a particle growth aqueous solution that includes the formed nuclei so that the pH value at a standard solution temperature of 25° C. becomes 10.5 to 12.0, and so that the pH value is lower than the pH value during nucleation.
    Type: Application
    Filed: November 30, 2023
    Publication date: March 28, 2024
    Applicant: SUMITOMO METAL MINING CO., LTD.
    Inventors: Atsushi FUKUI, Katsuya INOUE, Shuhei ODA, Hiroyuki TOYA
  • Publication number: 20240099146
    Abstract: The magnetostrictive member is formed of a single crystal of an iron-based alloy having magnetostrictive characteristics, is a plate-like body having a long-side direction and a short-side direction, and has a lattice constant of a <100> orientation in the long-side direction not larger than a lattice constant average calculated from lattice constants of <100> orientations in three directions, or the long-side direction, the short-side direction, and a direction orthogonal to the long-side direction and the short-side direction.
    Type: Application
    Filed: February 4, 2022
    Publication date: March 21, 2024
    Applicant: SUMITOMO METAL MINING CO., LTD.
    Inventors: Kazuhiko Okubo, Kazutaka Osako, Kiyoshi Izumi
  • Publication number: 20240084418
    Abstract: A method capable of inexpensively recovering valuable metals is provided. The method for recovering a valuable metal includes: a preparation step of preparing a charge containing at least lithium (Li) and a valuable metal; an oxidation and reductive melting step of subjecting the charge to an oxidation treatment and a reductive melting treatment to produce a reduced product containing a molten alloy and a slag, the molten alloy containing the valuable metal; and a slag separation step of separating the slag from the reduced product to recover the molten alloy, in which the mole ratio of lithium (Li) to aluminum (Al) (Li/Al ratio) in the slag is 0.15 or more and less than 0.40, and the mole ratio of calcium (Ca) to aluminum (Al) (Ca/Al) in the slag is 0.15 or more.
    Type: Application
    Filed: December 14, 2021
    Publication date: March 14, 2024
    Applicant: SUMITOMO METAL MINING CO., LTD.
    Inventor: Yu Yamashita
  • Patent number: 11926883
    Abstract: Provided is a method which allows for strict control of an oxygen partial pressure required for the heating and melting of a raw material, and thereby more efficient recovery of a valuable metal. The method for recovering a valuable metal (Cu, Ni, and Co) includes the steps of: preparing a charge comprising at least phosphorus (P) and a valuable metal as a raw material; heating and melting the raw material to form a molten body and then converting the molten body into a molten product comprising an alloy and a slag; and separating the slag from the molten product to recover the alloy comprising the valuable metal, wherein the heating and melting of the raw material comprises directly measuring an oxygen partial pressure in the molten body using an oxygen analyzer, and regulating the oxygen partial pressure based on the obtained measurement result.
    Type: Grant
    Filed: June 29, 2021
    Date of Patent: March 12, 2024
    Assignee: SUMITOMO METAL MINING CO., LTD.
    Inventors: Yu Yamashita, Toshihiko Nagakura, Tomoya Hagio
  • Patent number: 11923533
    Abstract: A non-aqueous electrolyte secondary battery is obtained using a lithium composite oxide having a layered structure in a positive electrode active substance. An increase in resistance following repeated charging and discharging is suppressed. The battery includes a positive electrode provided with a positive electrode active substance layer, a negative electrode and a non-aqueous electrolyte. The positive electrode active substance layer contains a porous particle lithium composite oxide having a layered structure. The average void ratio of the porous particle is not less than 12% but not more than 50%, and it contains two or more voids having diameters that are at least 8% of its particle diameter. The surface of the porous particle is provided with a coating of lithium tungstate. The coverage ratio of the surface of the porous particle by the lithium tungstate is not less than 10% but not more than 65%.
    Type: Grant
    Filed: July 10, 2020
    Date of Patent: March 5, 2024
    Assignees: TOYOTA JIDOSHA KABUSHIKI KAISHA, SUMITOMO METAL MINING CO., LTD.
    Inventors: Yuji Yamamoto, Momoko Procter, Yoshinari Makimura, Tetsutaro Hayashi, Willy Shun Kai Bong
  • Patent number: 11923534
    Abstract: A non-aqueous electrolyte secondary battery which is obtained using a lithium composite oxide having a layered structure and coated with a tungsten-containing compound in a positive electrode active substance, and which has a low initial resistance, and in which an increase in resistance following repeated charging and discharging is suppressed. The non-aqueous electrolyte secondary battery includes a positive electrode, a negative electrode and a non-aqueous electrolyte. The positive electrode includes a positive electrode active substance layer containing a lithium composite oxide having a layered structure. The lithium composite oxide includes a porous particle having a void ratio of not less than 20% but not more than 50%. The porous particle contains two or more voids having diameters that are at least 10% of the particle diameter of the porous particle. The surface of the porous particle is provided with a coating containing tungsten oxide and lithium tungstate.
    Type: Grant
    Filed: July 10, 2020
    Date of Patent: March 5, 2024
    Assignees: TOYOTA JIDOSHA KABUSHIKI KAISHA, SUMITOMO METAL MINING CO., LTD.
    Inventors: Yuji Yamamoto, Momoko Procter, Yoshinari Makimura, Tetsutaro Hayashi, Willy Shun Kai Bong
  • Patent number: 11912054
    Abstract: An LTHC layer having the visible light transmission property, having sufficient infrared absorption property, capable of improving transfer accuracy of the organic electroluminescence device by irradiation with a laser beam, and further enabling application in a wide variety of fields including electronics, medicine, agriculture, machine, etc. A donor sheet using the LTHC layer including infrared absorbing particles and a binder component, wherein the infrared absorbing particles are composite tungsten oxide fine particles including a hexagonal crystal structure, a lattice constant of the composite tungsten oxide fine particles is such that the a-axis is 7.3850 ? or more and 7.4186 ? or less, and the c-axis is 7.5600 ? or more and 7.6240 ? or less, and a particle size of the composite tungsten oxide fine particles is 100 nm or less, and the solar radiation transmittance is 45% or less.
    Type: Grant
    Filed: September 14, 2018
    Date of Patent: February 27, 2024
    Assignee: SUMITOMO METAL MINING CO., LTD.
    Inventors: Hirofumi Tsunematsu, Takeshi Chonan
  • Patent number: 11912878
    Abstract: A method of producing organic-inorganic hybrid infrared absorbing particles includes a dispersion liquid preparing step of preparing a dispersion liquid containing infrared absorbing particles, a dispersant, and a dispersion medium; a dispersion medium removing step of removing the dispersion medium from the dispersion liquid by an evaporation; a raw material mixture liquid preparing step of preparing a raw material mixture liquid containing the infrared absorbing particles collected after the dispersion medium removing step, a coating resin material, an organic solvent, an emulsifying agent, water, and a polymerization initiator; a stirring step of stirring the raw material mixture liquid while cooling; and a polymerizing step of polymerizing the coating resin material after deoxygenation treatment which reduces an amount of oxygen in the raw material mixture liquid.
    Type: Grant
    Filed: December 16, 2019
    Date of Patent: February 27, 2024
    Assignees: SUMITOMO METAL MINING CO., LTD., NATIONAL UNIVERSITY CORPORATION YAMAGATA UNIVERSITY
    Inventors: Hirofumi Tsunematsu, Takeshi Chonan, Atsushi Tofuku, Seigou Kawaguchi, Naohiro Kobayashi
  • Patent number: 11909039
    Abstract: The nickel-containing composite hydroxide disclosed herein contain secondary particles, which are formed from an aggregation of numerous primary particles, which have an average particle size of the primary particles is 0.01 ?m to 0.40 ?m. These secondary particles have a spherical or ellipsoidal shape, an average particle size of 20 ?m to 50 ?m, and a BET value of 12 m2/g to 50 m2/g after being roasted in air for 2 hours at 800° C.
    Type: Grant
    Filed: January 22, 2020
    Date of Patent: February 20, 2024
    Assignee: SUMITOMO METAL MINING CO., LTD.
    Inventors: Kazuomi Ryoshi, Kensaku Mori, Katsuya Kase, Yasutaka Kamata
  • Patent number: 11895952
    Abstract: An agricultural and horticultural film that does not raise a temperature of an atmosphere such as a greenhouse by using the agricultural and horticultural film in the greenhouse, etc., while absorbing infrared rays from the sunlight and warming the soil, the film having an infrared absorbing layer containing infrared absorbing material ultrafine particles, wherein the infrared absorbing material ultrafine particles are composite tungsten oxide ultrafine particles, and the composite tungsten oxide ultrafine particles have a XRD peak top intensity ratio value of 0.13 or more based on an XRD peak intensity ratio value of 1 on plane of a silicon powder standard sample (640c produced by NIST).
    Type: Grant
    Filed: June 19, 2018
    Date of Patent: February 13, 2024
    Assignee: SUMITOMO METAL MINING CO., LTD.
    Inventors: Hirofumi Tsunematsu, Takeshi Chonan
  • Patent number: 11894555
    Abstract: A positive electrode active material for a lithium ion secondary battery containing lithium nickel manganese complex oxide particles, wherein the lithium nickel manganese complex oxide particles are composed of secondary particles in which primary particles of a lithium nickel manganese complex oxide represented by a general formula LidNi1?a?b?cMnaMbZrcO2+? (where M is at least one element selected from Co, W, Mo, Mg, Ca, Al, Ti, Cr, and Ta, and is 0.05?a<0.60, 0?b<0.60, 0.00003?c?0.03, 0.05?a+b+c?0.60, 0.95?d?1.20, and ?0.2???0.2), wherein at least a portion of zirconium is dispersed in the primary particle, and wherein an amount of a positive active material for a lithium ion secondary battery in which an amount of excessive lithium determined by a neutralization titration method is 0.02 mass % or more and 0.09 mass % or less.
    Type: Grant
    Filed: July 31, 2019
    Date of Patent: February 6, 2024
    Assignee: SUMITOMO METAL MINING CO., LTD.
    Inventors: Takuma Nakamura, Haruki Kaneda, Yuki Koshika