Abstract: A stacked thermoelectric conversion module has a structure in which the following are stacked: a module for use in a high-temperature portion which is a thermoelectric conversion module in which a metal oxide is used as each thermoelectric conversion material or a thermoelectric conversion module in which a silicon-based alloy is used as each thermoelectric conversion material; and a module for use in a low-temperature portion which is a thermoelectric conversion module in which a bismuth-tellurium-based alloy is used as each thermoelectric conversion material. The stacked thermoelectric conversion module disposes a flexible heat-transfer material and, if necessary, a metal sheet between the module for use in a high-temperature portion and the module for use in a low-temperature portion. Also, the stacked thermoelectric conversion module disposes a cooling member on the cooling surface side of the module and a flexible heat-transfer material.

Abstract: The present invention provides a metal material comprising an alloy that is represented by the compositional formula Mn3-xM1xSiyAlzM2a, wherein M1 is at least one element selected from the group consisting of Ti, V, Cr, We, Co, Ni, and Cu; M2 is at least one element selected from the group consisting of B, P, Ga, Ge, Sn, and Bi, where 0?x?3.0, 3.5?y?4.5, 2.5?z?3.5, and 0?a?1, the alloy having a negative Seebeck coefficient and an electrical resistivity of 1 m?·cm or less at a temperature of 25° C. or higher. The metal material of the present invention is a novel material that has good thermoelectric conversion capability in the intermediate temperature region and excellent durability, and that is useful as an n-type thermoelectric conversion material.