Patents Assigned to TFL Ledertechnik GmbH
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Publication number: 20240011110Abstract: A deliming composition and a deliming method using graft polymers from polysaccharides and/or polypeptides or the corresponding derivatives, obtainable by radical polymerization of a monomer, selected at least from, or a monomer mixture of, acrylic acid or methacrylic acid or the mixtures thereof.Type: ApplicationFiled: January 20, 2022Publication date: January 11, 2024Applicant: TFL Ledertechnik GmbHInventors: Volker RABE, Susanne DÖPPERT
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Patent number: 11851722Abstract: The invention relates to specific chrome tanning agents and also to their use for the tanning of hides and skins, and to the leather and pelts obtainable as a result. It further provides a new process wherein the protein-masked chrome tanning agents of the invention are obtained from materials containing chromium and collagen, more particularly from leather production wastes such as leather shavings, for example. This enables recycling of chromium-containing leather production wastes, thereby permitting a significant reduction in the amount of such wastes, a fact which leads to considerable economic, environmental and logistical advantages.Type: GrantFiled: January 11, 2019Date of Patent: December 26, 2023Assignee: TFL Ledertechnik GmbHInventors: Volker Rabe, Susanne Doeppert, Juergen Reiners
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Patent number: 11365456Abstract: A method of preparing hydrophobicizing leather treatment compositions includes the steps of a) free-radically initiated copolymerization of i) at least one ethylenically unsaturated carboxylic acid or its derivatives, and ii) at least one (meth)acrylate of a primary saturated C8 to C22 alcohol, b) mixing the reaction mixture obtained after step a) with water, c) salting at least some of the carboxyl groups of the reaction mixture obtained after step b) with a base, and d) shearing the reaction mixture obtained after step c) to an average particle size of 0.05-10 ?m, wherein step a) is carried out in oil as reaction medium and wherein the atmosphere in step a) contains less than 0.1% by volume of an oxidizing gas.Type: GrantFiled: December 4, 2017Date of Patent: June 21, 2022Assignee: TFL Ledertechnik GmbHInventors: Bernhard Jansen, Juergen Reiners, Rafael Grosch, Guenter Kaster, Uwe Borowski
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Publication number: 20220127687Abstract: The invention relates to a device for reducing the odor of tanned leather, comprising a treatment chamber, which is designed to dry tanned leather and/or treat dried leather, and at least one odor reducing reservoir, wherein the at least one odor reducing reservoir has at least one odor-neutralizing substance, and a gas-exchange connection is provided between the treatment chamber and the odor reducing reservoir.Type: ApplicationFiled: December 9, 2019Publication date: April 28, 2022Applicant: TFL Ledertechnik GmbHInventors: Jens Fennen, Rodolfo Ampuero Allen, Nina Schulte-Gauczinski, Lorenzo Mejias Llanos
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Patent number: 10815542Abstract: A composition including an acetal of an aldehydic tanning agent for tanning hides and/or pelts, as well as a method for tanning hides and/or pelts in order to produce leather, wherein an acetal of an aldehydic tanning agent is used. By reducing the pH, the aldehydic tanning agent can be released, whereby a tanning step is initiated. The composition according to the invention and the method according to the invention are characterized by lower toxicity compared to conventional compositions and tanning methods based on aldehydic tanning agents. Furthermore, improved penetration of the tanning agents into deeper layers of the hide and/or the pelt is possible, so that particularly homogeneous tanning is achieved.Type: GrantFiled: May 13, 2019Date of Patent: October 27, 2020Assignee: TFL Ledertechnik GmbHInventors: Catherine Gabagnou, Nina Schulte-Gauczinski, Grigore Daniel Herta, Jens Fennen
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Patent number: 10604813Abstract: A composition including an acetal of an aldehydic tanning agent for tanning hides and/or pelts, as well as a method for tanning hides and/or pelts in order to produce leather, wherein an acetal of an aldehydic tanning agent is used. By reducing the pH, the aldehydic tanning agent can be released, whereby a tanning step is initiated. The composition and the method are characterized by lower toxicity compared to conventional compositions and tanning methods based on aldehydic tanning agents. Furthermore, improved penetration of the tanning agents into deeper layers of the hide and/or the pelt is possible, so that particularly homogeneous tanning is achieved.Type: GrantFiled: March 29, 2017Date of Patent: March 31, 2020Assignee: TFL Ledertechnik GmbHInventors: Catherine Gabagnou, Nina Schulte, Grigore Daniel Herta, Jens Fennen
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Publication number: 20190309379Abstract: A composition including an acetal of an aldehydic tanning agent for tanning hides and/or pelts, as well as a method for tanning hides and/or pelts in order to produce leather, wherein an acetal of an aldehydic tanning agent is used. By reducing the pH, the aldehydic tanning agent can be released, whereby a tanning step is initiated. The composition according to the invention and the method according to the invention are characterized by lower toxicity compared to conventional compositions and tanning methods based on aldehydic tanning agents. Furthermore, improved penetration of the tanning agents into deeper layers of the hide and/or the pelt is possible, so that particularly homogeneous tanning is achieved.Type: ApplicationFiled: May 13, 2019Publication date: October 10, 2019Applicant: TFL Ledertechnik GmbHInventors: Catherine Gabagnou, Nina Schulte-Gauczinski, Grigore Daniel Herta, Jens Fennen
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Publication number: 20190106758Abstract: A composition including an acetal of an aldehydic tanning agent for tanning hides and/or pelts, as well as a method for tanning hides and/or pelts in order to produce leather, wherein an acetal of an aldehydic tanning agent is used. By reducing the pH, the aldehydic tanning agent can be released, whereby a tanning step is initiated. The composition and the method are characterized by lower toxicity compared to conventional compositions and tanning methods based on aldehydic tanning agents. Furthermore, improved penetration of the tanning agents into deeper layers of the hide and/or the pelt is possible, so that particularly homogeneous tanning is achieved.Type: ApplicationFiled: March 29, 2017Publication date: April 11, 2019Applicant: TFL Ledertechnik GmbHInventors: Catherine Gabagnou, Nina Schulte, Grigore Daniel Herta, Jens Fennen
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Patent number: 10087497Abstract: The present invention is directed to a process for retanning leather comprising the steps of: a) providing tanned or pre-tanned leather b) treating the tanned leather of step a) with a composition comprising hollow microspheres, preferably as an aqueous composition, the hollow microspheres have a true density of from 0.01 to 0.10 g/cm3 (25° C.) and/or a bulk density of the dry powder of 0.005 to 0.06 g/cm3 (25° C.), c) drying, whereby the temperature of the leather during drying does not exceed 75° C. as well as to leather obtained by said process.Type: GrantFiled: July 25, 2014Date of Patent: October 2, 2018Assignee: TFL LEDERTECHNIK GMBHInventors: Jens Fennen, Eric Kientz, Florian Döppert, Nina Schulte
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Publication number: 20160160301Abstract: The present invention is directed to a process for retanning leather comprising the steps of: a) providing tanned or pre-tanned leather b) treating the tanned leather of step a) with a composition comprising hollow microspheres, preferably as an aqueous composition, the hollow microspheres have a true density of from 0.01 to 0.10 g/cm3 (25° C.) and/or a bulk density of the dry powder of 0.005 to 0.06 g/cm3 (25° C.), c) drying, whereby the temperature of the leather during drying does not exceed 75° C. as well as to leather obtained by said process.Type: ApplicationFiled: July 25, 2014Publication date: June 9, 2016Applicant: TFL LEDERTECHNIK GMBHInventors: Jens FENNEN, Eric KIENTZ, Florian DÖPPERT, Nina SCHULTE
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Patent number: 8357207Abstract: D-Isoascorbic acid or one of its salts, as such or as a constituent of a liquid or solid formulation, is an effective agent for reducing the amount of Cr(VI) compounds in leathers tanned with Cr(III) salts by treatment of the leather in an aqueous liquor after tanning or finishing or of a commodity article with an aqueous solution.Type: GrantFiled: November 27, 2006Date of Patent: January 22, 2013Assignee: TFL Ledertechnik GmbHInventor: Leonardus Strijbos
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Publication number: 20090249554Abstract: D-Isoascorbic acid or one of its salts, as such or as a constituent of a liquid or solid formulation, is an effective agent for reducing the amount of Cr(VI) compounds in leathers tanned with Cr(III) salts by treatment of the leather in an aqueous liquor after tanning or finishing or of a commodity article with an aqueous solution.Type: ApplicationFiled: November 27, 2006Publication date: October 8, 2009Applicant: TFL LEDERTECHNIK GMBHInventor: Leonardus Strijbos
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Publication number: 20080276378Abstract: Compositions comprising a) 5 to 50% by weight of an aliphatic dialdehyde having 2 to 10 carbon atoms; b) 2-5 to 20% by weight of at least one reductive saccharide having a dextrose equivalent of 10 to 100; c) 2.5 to 20% by weight of at least one water-soluble, optionally monoetherified polyoxaalkylene glycol having a molecular weight of more than 100 and not more than 2000; and d) 90 to 10% by weight of water, 0.05 to 0.19 mole of the components b) and c) being added per mole of the component a), outstandingly suitable for the pretanning of pelts and subsequent production of leathers free of heavy metals.Type: ApplicationFiled: October 7, 2004Publication date: November 13, 2008Applicant: TFL Ledertechnik GmbHInventor: Jens Fennen
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Patent number: 7250456Abstract: Compositions comprising a mineral oil or wax and a liquid polysiloxane substituted by functional groups, an anionic surfactant and additionally a molecular mono- or polycarboxylic acid and optionally any emulsifiable, hydrophilic or amphiphilic polymer comprising carboxyl groups are outstanding water repellents for leather, furskins, textiles and fibrous materials.Type: GrantFiled: January 22, 2003Date of Patent: July 31, 2007Assignee: TFL Ledertechnik GmbHInventors: Peter Eigen, Leonardus Strijbos
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Patent number: 6916348Abstract: Tanned leather is (a) pretreated in an aqueous and alkaline medium either with ammonia, primary amines or a mixture of ammonia and primary amines and then with a polyfunctional organic compound containing at least one aldehyde group as a functional group, or (b) in an aqueous and acidic medium with a polyfunctional organic compound and then ammonia, primary amines or a mixture of ammonia and primary amines, and (c) then dyed in an aqueous and alkaline medium with a water-soluble dye containing at least one functional group which is capable of reacting with one of the functional groups of the organic compound, forming a covalent bond. A tanned and dyed leather is obtainable with a high color intensity, outstanding wet fastness and excellent grain tightness, wherein the dye is permanently and covalently bonded to the leather via a bridging group, preferably in the region of the surface, and the bridging group is essentially bonded to the leather via —N?CH— groups.Type: GrantFiled: August 27, 2001Date of Patent: July 12, 2005Assignee: TFL Ledertechnik GmbHInventors: Jens Fennen, Campbell Thomas Page, Jon Louis McHugh
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Patent number: 6251414Abstract: There is disclosed an aqueous formulation for pretanning leather, which formulation comprises (a) a reductive saccharide having a dextrose equivalent of 10 to 100, and (b) an aliphatic dialdehyde containing 2 to 8 carbon atoms, and which is devoid of mineral salts. The leather treated with the novel aqueous composition (wet white leather) is eminently suitable for further processing, especially for the manufacture of leathers which are devoid of heavy metals.Type: GrantFiled: October 30, 1998Date of Patent: June 26, 2001Assignee: TFL Ledertechnik GmbH & Co. KGInventors: Alain Lauton, Markus Hess, Günter Streicher, Alois Püntener
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Patent number: 6033590Abstract: Compositions for the simultaneous retanning and fatliquoring of leather are described which may include further leather treatment agents as well.Type: GrantFiled: December 19, 1997Date of Patent: March 7, 2000Assignees: Ciba Specialty Chemicals Corp., TFL Ledertechnik GmbH & Co. KGInventors: Reiner Komforth, Alain Lauton