Patents Assigned to TFL Ledertechnik GmbH
  • Publication number: 20240011110
    Abstract: A deliming composition and a deliming method using graft polymers from polysaccharides and/or polypeptides or the corresponding derivatives, obtainable by radical polymerization of a monomer, selected at least from, or a monomer mixture of, acrylic acid or methacrylic acid or the mixtures thereof.
    Type: Application
    Filed: January 20, 2022
    Publication date: January 11, 2024
    Applicant: TFL Ledertechnik GmbH
    Inventors: Volker RABE, Susanne DÖPPERT
  • Patent number: 11851722
    Abstract: The invention relates to specific chrome tanning agents and also to their use for the tanning of hides and skins, and to the leather and pelts obtainable as a result. It further provides a new process wherein the protein-masked chrome tanning agents of the invention are obtained from materials containing chromium and collagen, more particularly from leather production wastes such as leather shavings, for example. This enables recycling of chromium-containing leather production wastes, thereby permitting a significant reduction in the amount of such wastes, a fact which leads to considerable economic, environmental and logistical advantages.
    Type: Grant
    Filed: January 11, 2019
    Date of Patent: December 26, 2023
    Assignee: TFL Ledertechnik GmbH
    Inventors: Volker Rabe, Susanne Doeppert, Juergen Reiners
  • Patent number: 11365456
    Abstract: A method of preparing hydrophobicizing leather treatment compositions includes the steps of a) free-radically initiated copolymerization of i) at least one ethylenically unsaturated carboxylic acid or its derivatives, and ii) at least one (meth)acrylate of a primary saturated C8 to C22 alcohol, b) mixing the reaction mixture obtained after step a) with water, c) salting at least some of the carboxyl groups of the reaction mixture obtained after step b) with a base, and d) shearing the reaction mixture obtained after step c) to an average particle size of 0.05-10 ?m, wherein step a) is carried out in oil as reaction medium and wherein the atmosphere in step a) contains less than 0.1% by volume of an oxidizing gas.
    Type: Grant
    Filed: December 4, 2017
    Date of Patent: June 21, 2022
    Assignee: TFL Ledertechnik GmbH
    Inventors: Bernhard Jansen, Juergen Reiners, Rafael Grosch, Guenter Kaster, Uwe Borowski
  • Publication number: 20220127687
    Abstract: The invention relates to a device for reducing the odor of tanned leather, comprising a treatment chamber, which is designed to dry tanned leather and/or treat dried leather, and at least one odor reducing reservoir, wherein the at least one odor reducing reservoir has at least one odor-neutralizing substance, and a gas-exchange connection is provided between the treatment chamber and the odor reducing reservoir.
    Type: Application
    Filed: December 9, 2019
    Publication date: April 28, 2022
    Applicant: TFL Ledertechnik GmbH
    Inventors: Jens Fennen, Rodolfo Ampuero Allen, Nina Schulte-Gauczinski, Lorenzo Mejias Llanos
  • Patent number: 10815542
    Abstract: A composition including an acetal of an aldehydic tanning agent for tanning hides and/or pelts, as well as a method for tanning hides and/or pelts in order to produce leather, wherein an acetal of an aldehydic tanning agent is used. By reducing the pH, the aldehydic tanning agent can be released, whereby a tanning step is initiated. The composition according to the invention and the method according to the invention are characterized by lower toxicity compared to conventional compositions and tanning methods based on aldehydic tanning agents. Furthermore, improved penetration of the tanning agents into deeper layers of the hide and/or the pelt is possible, so that particularly homogeneous tanning is achieved.
    Type: Grant
    Filed: May 13, 2019
    Date of Patent: October 27, 2020
    Assignee: TFL Ledertechnik GmbH
    Inventors: Catherine Gabagnou, Nina Schulte-Gauczinski, Grigore Daniel Herta, Jens Fennen
  • Patent number: 10604813
    Abstract: A composition including an acetal of an aldehydic tanning agent for tanning hides and/or pelts, as well as a method for tanning hides and/or pelts in order to produce leather, wherein an acetal of an aldehydic tanning agent is used. By reducing the pH, the aldehydic tanning agent can be released, whereby a tanning step is initiated. The composition and the method are characterized by lower toxicity compared to conventional compositions and tanning methods based on aldehydic tanning agents. Furthermore, improved penetration of the tanning agents into deeper layers of the hide and/or the pelt is possible, so that particularly homogeneous tanning is achieved.
    Type: Grant
    Filed: March 29, 2017
    Date of Patent: March 31, 2020
    Assignee: TFL Ledertechnik GmbH
    Inventors: Catherine Gabagnou, Nina Schulte, Grigore Daniel Herta, Jens Fennen
  • Publication number: 20190309379
    Abstract: A composition including an acetal of an aldehydic tanning agent for tanning hides and/or pelts, as well as a method for tanning hides and/or pelts in order to produce leather, wherein an acetal of an aldehydic tanning agent is used. By reducing the pH, the aldehydic tanning agent can be released, whereby a tanning step is initiated. The composition according to the invention and the method according to the invention are characterized by lower toxicity compared to conventional compositions and tanning methods based on aldehydic tanning agents. Furthermore, improved penetration of the tanning agents into deeper layers of the hide and/or the pelt is possible, so that particularly homogeneous tanning is achieved.
    Type: Application
    Filed: May 13, 2019
    Publication date: October 10, 2019
    Applicant: TFL Ledertechnik GmbH
    Inventors: Catherine Gabagnou, Nina Schulte-Gauczinski, Grigore Daniel Herta, Jens Fennen
  • Publication number: 20190106758
    Abstract: A composition including an acetal of an aldehydic tanning agent for tanning hides and/or pelts, as well as a method for tanning hides and/or pelts in order to produce leather, wherein an acetal of an aldehydic tanning agent is used. By reducing the pH, the aldehydic tanning agent can be released, whereby a tanning step is initiated. The composition and the method are characterized by lower toxicity compared to conventional compositions and tanning methods based on aldehydic tanning agents. Furthermore, improved penetration of the tanning agents into deeper layers of the hide and/or the pelt is possible, so that particularly homogeneous tanning is achieved.
    Type: Application
    Filed: March 29, 2017
    Publication date: April 11, 2019
    Applicant: TFL Ledertechnik GmbH
    Inventors: Catherine Gabagnou, Nina Schulte, Grigore Daniel Herta, Jens Fennen
  • Patent number: 10087497
    Abstract: The present invention is directed to a process for retanning leather comprising the steps of: a) providing tanned or pre-tanned leather b) treating the tanned leather of step a) with a composition comprising hollow microspheres, preferably as an aqueous composition, the hollow microspheres have a true density of from 0.01 to 0.10 g/cm3 (25° C.) and/or a bulk density of the dry powder of 0.005 to 0.06 g/cm3 (25° C.), c) drying, whereby the temperature of the leather during drying does not exceed 75° C. as well as to leather obtained by said process.
    Type: Grant
    Filed: July 25, 2014
    Date of Patent: October 2, 2018
    Assignee: TFL LEDERTECHNIK GMBH
    Inventors: Jens Fennen, Eric Kientz, Florian Döppert, Nina Schulte
  • Publication number: 20160160301
    Abstract: The present invention is directed to a process for retanning leather comprising the steps of: a) providing tanned or pre-tanned leather b) treating the tanned leather of step a) with a composition comprising hollow microspheres, preferably as an aqueous composition, the hollow microspheres have a true density of from 0.01 to 0.10 g/cm3 (25° C.) and/or a bulk density of the dry powder of 0.005 to 0.06 g/cm3 (25° C.), c) drying, whereby the temperature of the leather during drying does not exceed 75° C. as well as to leather obtained by said process.
    Type: Application
    Filed: July 25, 2014
    Publication date: June 9, 2016
    Applicant: TFL LEDERTECHNIK GMBH
    Inventors: Jens FENNEN, Eric KIENTZ, Florian DÖPPERT, Nina SCHULTE
  • Patent number: 8357207
    Abstract: D-Isoascorbic acid or one of its salts, as such or as a constituent of a liquid or solid formulation, is an effective agent for reducing the amount of Cr(VI) compounds in leathers tanned with Cr(III) salts by treatment of the leather in an aqueous liquor after tanning or finishing or of a commodity article with an aqueous solution.
    Type: Grant
    Filed: November 27, 2006
    Date of Patent: January 22, 2013
    Assignee: TFL Ledertechnik GmbH
    Inventor: Leonardus Strijbos
  • Publication number: 20090249554
    Abstract: D-Isoascorbic acid or one of its salts, as such or as a constituent of a liquid or solid formulation, is an effective agent for reducing the amount of Cr(VI) compounds in leathers tanned with Cr(III) salts by treatment of the leather in an aqueous liquor after tanning or finishing or of a commodity article with an aqueous solution.
    Type: Application
    Filed: November 27, 2006
    Publication date: October 8, 2009
    Applicant: TFL LEDERTECHNIK GMBH
    Inventor: Leonardus Strijbos
  • Publication number: 20080276378
    Abstract: Compositions comprising a) 5 to 50% by weight of an aliphatic dialdehyde having 2 to 10 carbon atoms; b) 2-5 to 20% by weight of at least one reductive saccharide having a dextrose equivalent of 10 to 100; c) 2.5 to 20% by weight of at least one water-soluble, optionally monoetherified polyoxaalkylene glycol having a molecular weight of more than 100 and not more than 2000; and d) 90 to 10% by weight of water, 0.05 to 0.19 mole of the components b) and c) being added per mole of the component a), outstandingly suitable for the pretanning of pelts and subsequent production of leathers free of heavy metals.
    Type: Application
    Filed: October 7, 2004
    Publication date: November 13, 2008
    Applicant: TFL Ledertechnik GmbH
    Inventor: Jens Fennen
  • Patent number: 7250456
    Abstract: Compositions comprising a mineral oil or wax and a liquid polysiloxane substituted by functional groups, an anionic surfactant and additionally a molecular mono- or polycarboxylic acid and optionally any emulsifiable, hydrophilic or amphiphilic polymer comprising carboxyl groups are outstanding water repellents for leather, furskins, textiles and fibrous materials.
    Type: Grant
    Filed: January 22, 2003
    Date of Patent: July 31, 2007
    Assignee: TFL Ledertechnik GmbH
    Inventors: Peter Eigen, Leonardus Strijbos
  • Patent number: 6916348
    Abstract: Tanned leather is (a) pretreated in an aqueous and alkaline medium either with ammonia, primary amines or a mixture of ammonia and primary amines and then with a polyfunctional organic compound containing at least one aldehyde group as a functional group, or (b) in an aqueous and acidic medium with a polyfunctional organic compound and then ammonia, primary amines or a mixture of ammonia and primary amines, and (c) then dyed in an aqueous and alkaline medium with a water-soluble dye containing at least one functional group which is capable of reacting with one of the functional groups of the organic compound, forming a covalent bond. A tanned and dyed leather is obtainable with a high color intensity, outstanding wet fastness and excellent grain tightness, wherein the dye is permanently and covalently bonded to the leather via a bridging group, preferably in the region of the surface, and the bridging group is essentially bonded to the leather via —N?CH— groups.
    Type: Grant
    Filed: August 27, 2001
    Date of Patent: July 12, 2005
    Assignee: TFL Ledertechnik GmbH
    Inventors: Jens Fennen, Campbell Thomas Page, Jon Louis McHugh
  • Patent number: 6251414
    Abstract: There is disclosed an aqueous formulation for pretanning leather, which formulation comprises (a) a reductive saccharide having a dextrose equivalent of 10 to 100, and (b) an aliphatic dialdehyde containing 2 to 8 carbon atoms, and which is devoid of mineral salts. The leather treated with the novel aqueous composition (wet white leather) is eminently suitable for further processing, especially for the manufacture of leathers which are devoid of heavy metals.
    Type: Grant
    Filed: October 30, 1998
    Date of Patent: June 26, 2001
    Assignee: TFL Ledertechnik GmbH & Co. KG
    Inventors: Alain Lauton, Markus Hess, Günter Streicher, Alois Püntener
  • Patent number: 6033590
    Abstract: Compositions for the simultaneous retanning and fatliquoring of leather are described which may include further leather treatment agents as well.
    Type: Grant
    Filed: December 19, 1997
    Date of Patent: March 7, 2000
    Assignees: Ciba Specialty Chemicals Corp., TFL Ledertechnik GmbH & Co. KG
    Inventors: Reiner Komforth, Alain Lauton