Abstract: Rubber compounds are readily bonded to nylon or polyamides, particularly tire cords of polyamides in which a high proportion of the amide linkages are attached directly to aromatic rings, using a two-step dip process in which the first dip comprises a liquid dispersion or solution of an epoxide having an average of from about two to four epoxide groups per molecule and a molecular weight up to about 600 and the second dip comprises an aqueous dispersion of a mixture of a major amount of a rubbery vinyl pyridine copolymer and a minor amount of a heat reactable 2,6-bis(2,4-dihydroxy phenylmethyl)-4-chlorophenol composition. High H-adhesions are obtained with this process. It is particularly useful for the bonding to rubber compounds of crystalline polyamides having a large number of aromatic groups in the polymeric structure, e.g., "Fiber B".

Abstract: An aqueous alkaline dispersion of a rubbery graft low gel vinyl pyridine copolymer and a water soluble, heat reactive phenolic resin is useful in forming an adhesive for bonding polyamide or polyester reinforcing elements or cords to rubber compounds or stocks. After dipping the polyamide or polyester cord in the one-step adhesive dip, the coated cord is heated to dry it and heat cure or heat set the adhesive on the cord. Thereafter, the adhesive containing polyamide or polyester cord is combined with, or laminated to (calendered), a curable rubber compound and the resulting assembly is cured to form a composite in which the polyamide or polyester cord is bonded to the rubber by means of said adhesive.

Abstract: A method is provided for rapidly distributing mixed gases throughout a partially evacuated ball mold. The invention is particularly useful in the pressurizing of tennis ball centers with a mixture of air and a low permeability gas. By this invention, the distribution of the low permeability gas throughout the mold can be accomplished by first partially evacuating air from the mold then injecting the mixed gases into the mold.

Abstract: Apparatus for coating one surface of a molded article that consists of a pair of hot relatively movable die members which when closed, form a cavity for molding the article in a desired configuration. A pin is selectively movable into and out of engagement with the surface of one of the die members. On retraction, the pin is also retracted through the opening in the injector nozzle allowing the injector to force material into the cavity to coat the outer surface of the article while the die members are closed. The barrel of the injector nozzle is cooled.

Abstract: A method comprises in-mold coating on a molded thermoset polyester glass fiber substrate an in-mold coating composition at a pressure of from about 25 to 50 p.s.i. and at a temperature not in excess of about 150.degree. F. for from about 2 to 12 minutes, said in-mold coating composition comprising the reaction product of an unsaturated aliphatic fumarate polyester diol, a saturated polyester diol flexibilizer, a cross-linking aliphatic polyol having from 3 to 6 OH groups, a diisocyanate in an amount by weight sufficient to provide from about 50 to 120%, preferably from about 80 to 103%, of the stoichiometric amount of --NCO groups required to react with all of the active hydrogen atoms in the coating composition and an ethylenically unsaturated monomer sufficient to polymerize with and crosslink the unsaturated polyester in admixture with a free radical peroxide initiator, an accelerator for said peroxide initiator and a polyurethane tin catalyst.

Abstract: A twister ring lubricant is formulated using a major portion of paraffin wax and a minor portion of conventional oil or grease. In the manufacture of ply which is used in making cord, the individual filaments are fed through the eye of a nylon traveler which spins around a steel twister ring. Two or more plies are cabled to form a cord also using a traveler which spins around a twister ring. The twister ring lubricant reduces the sliding friction between the nylon traveler and the steel twister ring.

Abstract: A thermoset, segmented and elastomeric polypropylene ether urethane is made by reacting together tolylene diisocyanate, ethylene glycol and a polypropylene ether triol having an average molecular weight of from 7,000 to 14,000, in certain ratios. The resulting polyurethane exhibits a temperature retraction TR-10 of less than about -35.degree. C. and a Goodyear-Healy rebound of greater than about 55%.

Abstract: A method and apparatus for making a pneumatic tire and particularly a giant off-the-highway radial type pneumatic tire is provided preferably by first forming a tire carcass around a tire carcass building drum and transporting the tire carcass to a second stage tire building machine by a carcass transport support means. The second stage machine comprises a first rotatable detachable building drum on a first shaft preferably capable of vertical positioning for placing the tire carcass on the first drum. The first drum is adapted to expand the tire carcass to a substantially toric configuration. A second rotatable collapsible drum for building a breaker assembly is mounted on a second shaft coaxially of the first shaft. Breaker transfer means travels over and between the drums to transfer the breaker assembly from the second drum to the first drum. When the breaker assembly is positioned over the first drum, the carcass is expanded into a toric configuration and mates with the breaker assembly.

Abstract: A method is disclosed comprising in-mold coating a structural foam part made from a thermoplastic aromatic polycarbonate resin or a thermoplastic ABS polymer resin with a thermosetting in-mold coating composition at a pressure of from about 25 to 50 p.s.i. and at a temperature not in excess of about 200.degree. F. for from about 1 to 10 minutes, preferably for from about 1 to 3 minutes, to provide hard, smooth and adherent coatings, said thermosetting in-mold coating composition comprising an ethylenically unsaturated polyester resin and an ethylenically unsaturated monomer(s) catalyzed with an organic perioxide initiator including an accelerator for the initiator.

Abstract: Process and apparatus for making a metal annular member of precise tolerances and desired surface finish. An external die has a continuous die surface of the configuration desired for the external surface of the metal annular member and an annular ridge surrounding the inside of the die for seating one end of an annular sheet metal blank. A first punch engages the sheet metal blank and drives it into the external die so as to reduce the external diameter of the blank and seat it against the ridge. The precise tolerance of the die surface of the external die determines both the external and at least a portion of the internal dimensions produced in the annular sheet metal blank. The first punch is axially movable to an endmost position wherein substantially all of the blank has been forced into the die. An ejector punch is positioned inside of the external die and operates to provide a portion of the forming die surfaces as well as to eject the completed workpiece.

Abstract: Liquid compositions suitable for hot post-mold coating of cured sheet molding compound (SMC) parts comprise a reaction product of an epoxide and an unsaturated carboxylic acid mixed with a low shrink additive. These liquid compositions are used to smooth surfaces, fill porosity and other voids and to eliminate or reduce sink marks. Coatings typically are cured in less than two minutes and appear able to provide many features of normal painting without paint facilities except possibly those needed for touch-up.The application method used to date has been to compression mold an SMC part in the usual way, separate the mold halves, inject the liquid composition and reclose the mold for a second cure cycle. A unique feature of the liquid composition is its ability to adhere to an uncleaned SMC molding.

Abstract: A thermoplastic, linear and segmented poly-1,2-propylene ether urethane having a Tg of below about -30.degree. C. for the poly-1,2-propylene ether segments is made by reacting poly-1,2-propylene glycol having a high molecular weight; ethylene glycol, 2,3-butane diol or neopentyl glycol or mixture thereof; and 2,4-tolylene diisocyanate containing from about 55 to 100% by weight of the 2,4-isomer with the balance being the 2,6-isomer.

Abstract: Ethylene-propylene-non-conjugated-diene rubber (EPDM) parts having a defective paint job can be stripped with 100 parts of a solution containing 50 to 99 parts of sulfuric acid, from about 0.1 to 10 parts of a surfactant and from about 0.9 to 49.9 parts of water. The stripped part can be effectively repainted with polyurethane enamel provided that the stripped part is not subjected to the normal pretreatment required in painting EPDM parts.

Abstract: A rubber-free heat reactable phenol-formaldehyde resin adhesive is used to bond bright steel tire cords to the tire rubber.

Abstract: White tire sidewall made from a urethane derived from a hydrogenated diphenylmethane diisocyanate terminated apolytetrahydrofuran and pigmented with titanium dioxide has exceptionally good flex resistance and adhesion. High molecular weight triol and a low molecular weight diol are used to chain extend and crosslink the urethane.

Abstract: The cured polyester or polyurethane adhesive bond seam joining two FRP (fiberglass reinforced plastic) parts, particularly in-mold coated FRP parts, is coated with a reactive polyepoxide resin-polyamide resinamine coating. After curing, sanding, sealing and painting, the seam area joining the parts did not exhibit any paint pops or sinks and the seam itself was invisible or nearly invisible.

Abstract: A method and apparatus for forming a thermoset in-the-mold coating on a hot, cured glass fiber reinforced thermoset resin substrate by (1) separating the mold halves slightly while maintaining a seal with the shear edge, (2) injecting an in-the-mold coating resin in a stream which flows parallel from the injector onto a surface of the substrate, and (3) closing the mold and curing the coating under pressure. The separation and of the mold halves is performed by the conventional mold ram. Preferably the mold surface forming the coated surface of the substrate is roughened.

Abstract: A laminate comprises an adherent in-mold thermoset coating composition on a thermoset polyester glass fiber substrate, the coating composition comprising essentially the reaction product of an unsaturated aliphatic fumarate polyester diol, a saturated polyester diol flexibilizer, a cross-linking aliphatic polyol having from 3 to 6 OH groups, a diisocyanate in an amount by weight sufficient to provide from about 50 to 120%, preferably from about 80 to 99%, of the stoichiometric amount of --NCO groups required to react with all of the active hydrogen atoms in the coating composition and an ethylenically unsaturated monomer sufficient to polymerize with and crosslink the unsaturated polyester in admixture with a minor amount by weight of polyvinyl acetate which serves to reduce or eliminate shrinkage of the coating composition.

Abstract: A plastic composition which emits a reduced amount of smoke when heated to flame temperature is thermoformable and high impact resistant is made by blending chlorinated polyvinyl chloride, a mixture of chlorinated polyethylenes, an alkyl acrylate polyvinyl chloride copolymer, and a mixture of a tin process aid and heat stabilizer. The plastic has application in thermoformed, high impact trim parts in aircraft and mass transit vehicles. The reduced amount of smoke emitted when the plastic reaches high temperature aids occupants of a plane or mass transit vehicle to visually find the high temperature source and/or to find their way to an exit when a fire, electrical short circuit or other high temperature condition occurs.

Abstract: Rubber compounds are readily bonded to tire cords using a dip process in which the dip contains an alkaline aqueous dispersion of a mixture of a major amount by weight of a rubbery vinyl pyridine/styrene/butadiene copolymer and a minor amount of a lignin amine-resorcinol-formaldehyde reaction product.