Abstract: A spent catalyst distributor in a fluid catalytic cracking unit regenerator is self aerated by attaching to the underside of each trough arm a contiguous lip which captures rising aeration fluid and uses the aeration fluid to aerate spent catalyst flowing through the trough arms of the spent catalyst distributor. Orifices in the bottom plate of each trough arm pass the captured aeration fluid up into the spent catalyst flowing within the trough arm. The aeration fluid provides aeration and fluidization of the spent catalyst to facilitate the flow of the spent catalyst through the trough arms of the spent catalyst distributor.

Abstract: A method and apparatus for desulfurizing a gas and regenerating a sorbent is disclosed. The sulfur-containing feed gas which can be an effluent gas from a coal gasification reactor, for example, is desulfurized with a particulated metallic oxide sorbent in a transport riser. The sulfided sorbent is than separated from a desulfurized effluent gas and regenerated by contact with an oxygen-containing gas in a transport riser. The regenerated sorbent is separated from an SO.sub.2 containing offgas and recycled to the desulfurization step. The degree of sorbent conversion in the desulfurization step is held at a low level and the sorbent regeneration rate is increased to avoid excessive temperature rise in the regeneration step. In such manner, sorbent cooling can be substantially eliminated. The regeneration riser preferably comprises a once-through lift riser to minimize the riser transport gas requirements to just oxidant gas or oxidant gas mixed with a reduced amount of diluent gas.

Abstract: Disclosed are a process for converting low value hydrocarbon streams to hydrogen and/or synthesis gas products and a transport reactor useful in the conversion process. In the transport reactor, carbon produced is deposited on a circulating inert particulated carrier. The carbon deposited is partially oxidized to supply heat for the endothermic reactions. Reaction effluent gas leaving the transport reactor can be processed to remove particulate matter, sulfur compounds, and acid gases; condense the steam; and separate hydrogen from carbon monoxide to produce a purified hydrogen and/or syngas product. The present process has the flexibility to continuously handle all types of low value hydrocarbon feeds substantially without process disruption.

Abstract: An integrated ammonia/urea process and a plant for carrying out the same. The process comprises recycling a high pressure purge stream made up mostly of air from the urea synthesis cycle to the autothermal reformer in a syngas production unit of the ammonia process. In such a manner, compression energy required for ammonia synthesis can be reduced since a portion of the high pressure air feed to the autothermal reactor is supplied by the urea purge stream recycle. In addition, the equipment needed to clean up the urea purge stream is largely eliminated.

Abstract: A process for removing nitrogen from liquefied natural gas (LNG) using an enhanced surface, reflux heat exchanger is disclosed. A relatively warm high pressure LNG stream is directed countercurrently in heat exchange with a cool low pressure LNG stream to chill the high pressure stream and partially vaporize the low pressure LNG stream in the reflux heat exchanger. Vapor produced thereby strips the low pressure LNG stream of nitrogen. The cool low pressure LNG stream is produced by expansion of the chilled high pressure LNG stream. Vapor produced by the expansion is combined with the vapor produced in the exchanger and withdrawn overhead. Product LNG which is lean in nitrogen is withdrawn from the bottom of the exchanger.

Abstract: A vessel unheading device and method especially suited to handle shot coke produced in a delayed coker unit of a petroleum refining process. The device includes a car having mounted thereon one or more bottom head retracting support members which can be laterally positioned below the head assembly. The support member includes a vertically retractable member suitable for elevating a bearing plate mounted at an upper end thereof into pivotable load bearing engagement with the head, and a horizontally retractable member having one end attached to the bearing plate and another end attached to the vertically retractable member for applying a pivot force. Shot coke or other debris is captured from the opened vessel by a mobile chute wheeled into position adjacent the unheading car. Following complete retraction, the head is transported to a remote location for maintenance.

Abstract: A gravity sedimentation unit for thickening or clarifying a solids containing liquid is disclosed. The unit comprises a settling basin for receiving the feed and permitting the suspended solids to settle. A pump moves around the basin to discharge solids accumulating at the bottom. Support and vertical positioning of the pump is effected by a pump suspension which comprises a winch and a solids level detector. Horizontal positioning of the pump is effected by a bridge-type crane including a traverse with a drive for moving the traverse over the basin and a motorized trolley for moving the pump suspension back and forth along the traverse. Control of the pump travel is effected by a controller programmed to carry out regular search patterns through the basin.

Abstract: The present invention optimizes the relationship of variables associated with a process having inputs and outputs such that the process has controlled variables, manipulated variables, associated variables and disturbance variables, to maximize production rates.

Abstract: A hybrid condensation-absorption process and unit is disclosed for the recovery of olefins. A mixed-component stream containing hydrogen, methane and olefins is compressed and refrigerated against propylene refrigerant to partially condense the stream. The condensate is stripped of volatile components and fed to a fractionation unit such as a deethanizer. The volatile components stripped from the condensate and the non-condensed vapor from the mixed-component stream are fed to a solvent absorption unit to remove olefins which are absorbed in the solvent. The olefins-rich solvent is regenerated to recover olefins and lean solvent. The lean solvent is recirculated to the absorption unit. The olefins recovered from regeneration of the solvent are fed to the fractionation unit along with the pre-stripped condensate. Vapor from the absorption unit is cryogenically processed to recover a crude hydrogen product, a fuel gas product and residual olefins which can be recycled to the absorption unit.

Abstract: An integrated three-column process for recovering hydrocarbon distillate products from a hydroprocessing or hydrocracking reactor effluent stream and a hydrocarbon distillate product recovery train are disclosed. According to the present recovery process, an effluent stream from the cracking reactor is cooled and separated into light and heavy phase streams. The heavy phase stream is depressurized and stripped of light end components in a steam stripping column. The light phase stream is further cooled to separate a liquid stream which is combined with the light ends from the stripper and fed to a debutanizer. A C.sub.4 -rich light end stream taken overhead from the debutanizer is condensed to produce LPG product stream(s). A C.sub.4 -lean heavy end stream removed from the bottoms of the debutanizer is combined with a heavy end bottoms stream from the stripper and fed to a fractionator for fractionation into product distillate streams such as light and heavy naphtha, jet fuel, diesel oil, and the like.

Abstract: An integrated middle distillate upgrading process and unit are disclosed. A middle distillate side-stream of a conventional single stage hydrocracking process is circulated to a hydrotreating stage such as an aromatics saturation reactor and/or a catalytic dewaxing reactor to effect middle distillate upgrade. The upgraded product is then finished in a fractionation stage side-stripper column. The integrated hydrotreating reactor can share the duty of existing hydrocracker stage equipment and take advantage of existing process heat to eliminate the need for much of the equipment generally required by a stand-alone hydrotreating reactor of the prior art.

Abstract: A method and apparatus for desulfurizing a gas and regenerating a sorbent is disclosed. The sulfur-containing feed gas which can be an effluent gas from a coal gasification reactor, for example, is desulfurized with a particulated metallic oxide sorbent in a transport riser. The sulfided sorbent is than separated from a desulfurized effluent gas and regenerated by contact with an oxygen-containing gas in a transport riser. The regenerated sorbent is separated from an SO.sub.2 containing offgas and recycled to the desulfurization step. The degree of sorbent conversion in the desulfurization step is held at a low level and the sorbent regeneration rate is increased to avoid excessive temperature rise in the regeneration step. In such manner, sorbent cooling can be substantially eliminated. The regeneration riser preferably comprises a once-through lift riser to minimize the riser transport gas requirements to just oxidant gas or oxidant gas mixed with a reduced amount of diluent gas.

Abstract: An enhanced method is disclosed for recovering olefins from a cracking furnace effluent stream in an olefins plant. In accordance with this method, a liquid hydrocarbon stream, preferably obtained from the compressor area drier liquids and/or from the deethanizer or depropanizer, is injected into the reaction effluent stream to condition the reaction effluent stream for enhanced condensation against propylene refrigeration. Also disclosed is an olefins plant utilizing liquid hydrocarbon injection and an improvement to existing olefins recovery process technology using liquid hydrocarbon injection for vapor stream conditioning.

Abstract: A method for recovering volatile components from reformer effluent condensate and fusel oil in a methanol plant is disclosed. The fusel oil is stripped with steam to produce an overhead vapor stream of steam and stripped organic components which is recycled to the feed to the reformer. Also disclosed are a methanol plant with a fusel oil stripper; and a unitized stripper column for treating fusel oil and process condensate wherein steam containing volatile gases stripped from the process condensate is used to strip the fusel oil. The present invention improves yield and reduces or eliminates liquid fusel oil waste by recycling volatile organic components contained in the fusel oil to the feed of the reformer.

Abstract: A separator apparatus and method for a hydrocarbon fluidized catalytic cracking process are disclosed. The apparatus comprises a main plenum in a disengagement vessel which connects a plurality of riser cyclones in a riser catalyst separation stage to a plurality of secondary cyclones in a secondary catalyst separation stage. The cyclones in the second and each succeeding stage receive a substantially equal amount of gas from the plenum. The effluent gas is substantially prevented from leaking into the interior space of the disengagement vessel. Also disclosed is a method for retrofitting an existing plant with the plenum design to provide a more compact arrangement of the catalyst separation equipment in the disengagement vessel.

Abstract: A high temperature heat exchanger having an improved support apparatus for suspending a tube bundle. The improved support comprises a skirt from which the tube sheet and the bundle are supported, and a lip on an upper end of the skirt engaged in a flange assembly receiving the lip. A first refractory lining on an inside face of the skirt extends downwardly from the lip, and overlaps a second refractory lining on an outside surface of the skirt extending upwardly from adjacent the tube sheet toward the lip. By securing the support apparatus in the cold flange assembly, the interior refractory is not used for supporting the tube bundle and can maintain its integrity, have a lower incidence of premature failure and yield an optimum refractory life.

Abstract: A methanol refining column and method using an intermediate reboiler. Use of the intermediate reboiler reduces methanol production energy requirements. A side stream at or near a fusel oil takeoff point is heated in an intermediate reboiler by a low temperature heating medium (relative to a bottoms reboiler) and returned to the column at or near the fusel oil take-off tray. The take-off tray is operated at 85.degree.-110.degree. C., and 70-90 percent of the reboiler duty is supplied through the intermediate reboiler. The remaining heat load is supplied by a bottoms steam reboiler.

Abstract: A feed line to a pyrolysis furnace and a liquid injection apparatus for introducing a liquid coke inhibitor in the feed line are disclosed. The injection apparatus includes a central passageway for supplying the liquid coke inhibitor, an annular passageway for delivering an atomizing gas and a mixing reservoir for mixing the liquid and gas wherein the mixed fluid is atomized by passage through an orifice in a nozzle. A cooling jacket surrounding the annular passageway prevents decomposition of the coke inhibiting agent which products can plug the nozzle. The injection apparatus is typically installed in a bend of a process feedstock conduit with a discharge end aligned to an axis of the flow. A hot injection point close to the inlet of the pyrolysis furnace is preferred for best results. To help ensure complete evaporation of a carrier liquid prior to the furnace, the injection apparatus can include an evaporation shroud.

Abstract: A process for recovering CO.sub.2 from a mixture of light hydrocarbons, e.g. light hydrocarbons produced from a CO.sub.2 injection enhanced oil recovery. The mixture is distilled in a distributive zone with CO.sub.2 produced overhead and in the bottoms. The overhead and bottoms produced from the distributive zone are then fed to first and second concentrating distillation zones, respectively. The first concentrating zone produces a bottoms product rich in CO.sub.2 and an overhead product rich in methane and lean in CO.sub.2. The second concentrating zone is refluxed with lean oil and produces a CO.sub.2 distillate and a CO.sub.2 -lean bottoms product. In various embodiments, at least a section of each of the concentrating zones are placed in a single column, the CO.sub.

Abstract: A method for pretreating a natural gas stream using a single scrub column to remove freezable C.sub.5+ components and provide an LNG product which can be conveniently handled and shipped is disclosed. The method comprises feeding a natural gas stream to a feed point on a scrub column operated substantially as an absorption column wherein the heavy components are absorbed from the feed gas using a liquid reflux essentially free of such C.sub.5+ components. The feed can be vapor introduced at a low point on the column, or can be optionally split, cooled and/or expanded and introduced at one or more feed points on the column. The reflux stream can be overhead vapor condensate having a temperature of about - 40.degree. C., or methane-rich LNG or a combination of LNG and vapor condensate.