Abstract: Antimonate-based redox catalysts are produced by a single slurry technique using a silica sol and fumed silica to supply the catalyst support.

Abstract: Catalysts containing iron, molybdenum, bismuth and nickel, cobalt, magnesium, zinc, cadmium, calcium or beryllium have been found to give especially large volumes of acrylonitrile or methacrylonitrile in a given time when manganese, antimony, thorium, zirconium, yttrium or mixtures thereof are incorporated into the catalyst.

Abstract: A slurry composition and method of using the same is provided which is particularly useful in filling spent in situ oil shale retorts to form a strong load bearing mass which minimizes surface subsidence. The slurry is formed by mixing spent oil shale with 50 to 300 weight percent water and at least one material selected from the group consisting of lignosulfonate, sodium silicate, and sodium gluconate. The maximum concentration of each material selected is 4 weight percent based on the spent oil shale.

Abstract: Catalyst for production of polyolefins of improved morphology comprises (A) organometallic promoter and (B) product obtained by contacting (1) at least one oxygenated compound of phosphorus with (2) catalytic complex comprising an intimate association of at least one reduced Group IVB-VB metal halide, at least one divalent metal halide and at least one aluminum compound. Oxygenated phosphorus compound is used in an amount effective to improve polymer morphology without substantial adverse effects on other catalytic properties.

Abstract: Allylbenzene is converted to indene by means of a tungsten-containing catalyst.

Abstract: The heavy organic material contained in the liquid bottoms from the quench column of an acrylonitrile recovery and purification system is extracted therefrom using acetonitrile as the extractant.

Abstract: Certain multiply promoted Sn-Sb oxides are superior catalysts for the ammoxidation of olefins to the corresponding unsaturated nitriles, the selective oxidation of olefins to unsaturated aldehydes and acids, and the oxydehydrogenation of olefins to diolefins.

Abstract: The present invention relates to a process for the conversion of tertiary-butyl-containing compounds to methacrylic derivatives, and more particularly to a process for the conversion of tertiary-butyl-containing compounds selected from the group consisting of alkyl tertiary-butyl ethers, tertiary-butyl alcohol, isobutylene dimer (2,2,4-trimethylpentene) and isobutylene trimer, to methacrolein, methacrylic acid or methacrylonitrile.

Abstract: Oxide complexes comprising copper-promoted antimony phosphates have been found to exhibit significant catalytic activity in various oxidation-type reactions such as the ammoxidation of propylene to produce acrylonitrile.

Abstract: Certain multiply promoted U-Sb-oxides are superior catalysts for the ammoxidation of olefins to the corresponding unsaturated nitriles, the selective oxidation of olefins to unsaturated aldehydes and acids, and the oxyde-hydrogenation of olefins to diolefins.

Abstract: Molybdenum-promoted antimony phosphates also containing at least one of tellurium and bismuth have been found to exhibit significant catalytic activity in various oxidation-type reactions.

Abstract: Certain multiply promoted Sn-Sb oxides are superior catalysts for the ammoxidation of olefins to the corresponding unsaturated nitriles, the selective oxidation of olefins to unsaturated aldehydes and acids, and the oxydehydrogenation of olefins to diolefins.

Abstract: The present invention provides a process for the preparation of oxidation catalysts containing mixed oxides of vanadium and phosphorus, which catalysts are particularly effective in the oxidation of n-butane, n-butenes, 1,3-butadiene or a mixture thereof with molecular oxygen or an oxygen-containing gas in the vapor phase to produce high yields of maleic anhydride with good selectivity. A vanadium compound is introduced into an olefinic halogenated organic liquid medium, a phosphorus-containing compound is added to the medium, reduction of at least a portion of the vanadium to a +4 valence state is effected either prior to or subsequent to the addition of the phosphorus-containing compound, and the resulting vanadium-phosphorus oxide catalyst precursor is recovered, dried and calcined.

Abstract: An oxydehydrogenation process for producing indene and substituted indenes from indene precursors more saturated than indene is described and comprises contacting said precursor with oxygen and a catalyst comprising cobalt oxide and molybdenum oxide at an elevated temperature above about 300.degree. C. Preferably the reaction is conducted at a temperature of about 500.degree.-650.degree. C. for a period of from 0.1 to about 30 seconds.

Abstract: A multi-stage dehydrogenation process for preparing indene and substituted indenes from indene precursors more saturated than indene is described. The process comprises the steps of(a) contacting said indene precursor in a first dehydrogenation zone with a dehydrogenation catalyst at an elevated temperature to form an intermediate product,(b) advancing the product of the first dehydrogenation zone to a second dehydrogenation zone,(c) contacting said product in the second dehydrogenation zone with a second dehydrogenation catalyst at an elevated temperature, and(d) recovering indene or a substituted indene from said second zone.The process of the invention results in yields of indene which are enhanced when compared to single stage, essentially isothermal processes using a single catalyst.

Abstract: Antimony-based oxide complex catalysts are improved by adding to these catalysts an antimony-containing compound such as Sb.sub.2 O.sub.3.

Abstract: Disclosed is a method and an apparatus for analyzing the composition of a gasoline-range petroleum product using a new copper on silica gel adsorption composition. The copper on silica gel adsorption composition is capable of separating olefins from saturates in a mixture by temporarily retaining the olefins while allowing the saturates to pass through. The method of analysis entails passing a gasoline sample through an absorption column whereby the aromatics are retarded while the saturates and olefins pass through. The saturates and olefins are then directed through the copper on silica gel composition wherein the olefins are retained while the saturates pass through into a detector and are measured. Once all the saturates are removed from the system, the aromatics are backflushed from the absorption column and are routed into the detector for measurement.

Abstract: An isomerization process which comprises isomerizing a hydrocarbon component comprising at least one saturated C.sub.5 -C.sub.6 hydrocarbon in the presence of hydrogen and a catalyst comprising tantalum pentafluoride and hydrogen halide and in the presence of a hydrocarbon promoter comprising at least one member selected from the group consisting of C.sub.8 -C.sub.14 multiple-branched paraffins, wherein the total concentration of C.sub.8 -C.sub.14 multiple-branched paraffins, is in the range of about 1 to 50 parts by weight per each 100 parts by weight of said saturated C.sub.5 -C.sub.6 hydrocarbons.