Abstract: In one or more embodiments, the present invention provides an way to modify the isoprene unit using an alder-ene reaction to form thermoset compounds comprising the resultant electron-deficient, readily crosslinkable polyisobutylene-based rubber that avoids the use of corrosive bromine or chlorine to make the activated butyl rubber, is easier to crosslink than the halobutyls, allows crosslinking with a simple organic base or a peroxide, and has mechanical properties as good as or better than sulfur crosslinked butyl rubbers.

Abstract: Fluorescent chromophores nicknamed BOPHY are provided. The chromophores may be readily synthesized in two steps from readily available reagents via the coupling of a pyrrole aldehyde or ketone with hydrazine, followed by reaction with BF3. The resultant symmetric and dimeric tetracycle is comprised of two BF2 units in six-member chelate rings, appended by pyrrole units on the periphery. The quantum yield of fluorescence for the unmodified compound and the tetramethyl variant are near unity, with values 95 and 92% respectively in CH2Cl2.

Abstract: In one or more embodiments, the present invention provides a method of applying or printing structural colors to a substrate that involves pre-treatment of the substrate surface to prevent absorption of the fluid containing the particles. This allows the fluid to maintain their sessile drop shapes and as the water evaporates, the colloidal particles spontaneously assemble within the confined geometry into semi-ordered structures that interact with light to produce structural color. While the pre-treatment may be done in a variety of ways, application of a, hydrophobic and/or oleophobic coating, like 1H-IH,2H-perfluoro-1-dodecene (C10F21—CH?CH2) (perfluoro) monomer, fluoroalkyls, fluorohydroalkyls, cyclo-fluoroalkyls, fluorobenzen, by plasma-enhanced chemical vapor deposition (cold plasma treatment) has been found to be effective, particularly for printing applications. These treated substrates allow production of a wide range of structural colors using binary systems of nanoparticles.

Abstract: An optical imaging system utilizes a three-dimensional (3D) light scanner to capture topography information, color reflectance information, and fluorescence information of a target object being imaged, such as a surgical patient. The system also utilizes the topography information of the target object to perform an image mapping process to project the captured fluorescence or other intraoperative images back onto the target object with enhanced definition or sharpness. Additionally, the system utilizes the topography information of the target object to co-register two or more images, such as a color image of the target object with a fluorescence image for presentation on a display or for projection back onto the target object.

Abstract: In one or more embodiments, the present invention provides a heat dissipating polymer materials (and films thereof) that utilize supramolecular chemistry. In various embodiments, these materials comprise networks of hydrogen bonded supramolecular crystals, self-assembled into aligned 2-D layered sheet structures that are distributed throughout a polymer matrix. In some of these embodiments, the heat dissipating polymer materials are prepared by in-situ co-precipitation of melamine and cyanuric acid in a PVA polymer resulting in homogenous distribution of MC crystals and the eventual formation of a network of hydrogen bonded melamine-cyanurate (MC) 2-D layered sheet structures throughout the PVA polymer.

Abstract: In various embodiments, the present invention is directed to polymer based heat dissipating materials and films that are highly elastic, thermally conductive and optically transparent and made using a non-conventional approach. The polymer based heat dissipating materials and films of the present invention use a hybrid filler comprising a very small loading of traditional fillers like boron nitride or graphene oxide combined with non-conventional fillers like organic linkers, dispersed in a preferably non-conductive polymer matrix. These hybrid fillers provide an elastic thermal network that drives heat conduction across the polymer chains, while provided flexibility and optical clarity.

Abstract: A polystyrene-g-(polyisobutylene-b-polystyrene) is taught. The polystyrene-g-(polyisobutylene-b-polystyrene) is synthesized by first providing a polystyrene backbone. Once the polystyrene backbone is provided, the polystyrene backbone is acetylated to provide acetyl groups on the polystyrene backbone. Next, the acetyl groups are converted to —C(CH3)2OH groups. Finally, the living polymerization of isobutylene is initiated, which is then followed by the living block polymerization of styrene. A polymer network of polystyrene-g-(polyisobutylene-b-polystyrene)s is also provided.

Abstract: A polystyrene-g-(polyisobutylene-b-polystyrene) is taught. The polystyrene-g-(polyisobutylene-b-polystyrene) is synthesized by first providing a polystyrene backbone. Once the polystyrene backbone is provided, the polystyrene backbone is acetylated to provide acetyl groups on the polystyrene backbone. Next, the acetyl groups are converted to —C(CH3)2OH groups. Finally, the living polymerization of isobutylene is initiated, which is then followed by the living block polymerization of styrene. A polymer network of polystyrene-g-(polyisobutylene-b-polystyrene)s is also provided.

Abstract: A star block copolymer and a thermoplastic elastomer including plurality of the star block copolymers and a method of making both is taught. The star block copolymers of the present invention include a core component having an ?-methylstyrene oligomer wherein arms emanate from the core component and the arms are poly(isobutylene-block-styrene) diblock copolymers.

Abstract: An acoustic noise mitigation system for an electric machine includes one or more suspension members. The suspension members may include arcuate members that are positioned between a machine housing and a stator. During operation of the electric machine, the electromagnetic force frequency that is generated by the stator relative to a rotating rotor is able to be absorbed by the suspension members. As a result, acoustic noise generated by the electric machine is reduced.

Abstract: In one or more embodiments, the present invention provide a polyisobutylene-based polyurethane-urea, and related method of preparation, wherein PIB-diols form the soft segment and a diisocyanate along with a well-defined combinations low molecular weight diol chain extenders and amino alcohol as co-chain extenders form the hard segments. In one or more embodiments, the present invention is directed to the use of judiciously chosen chain extender/co-chain extender combinations to enhance the strength of PUs by partially replacing urethane groups with urea groups by the use of amino alcohols to improve strength, while maintaining good processability. These thermoplastic PIB-PUU elastomers exhibit heretofore unattainable combinations of mechanical properties and processability.

Abstract: A surface treatment for a metal substrate includes a nitride layer and a diamond-like carbon coating on said nitride layer. The metal substrate can be a titanium-containing substrate. The nitride layer and diamond-like carbon coating serve to improve the tribological properties of the metal substrate.

Abstract: An axial flux machine (AFM) includes a rotor rotatably disposed between a pair of fixed stators. The rotor and the stators are formed of tape-wound laminated cores of ferromagnetic material. In addition, the rotor includes multiple layers of angled magnets that circumscribe the rotor. Such configuration enables the axial flux machine to achieve a high airgap flux density while achieving a high saliency ratio and lowered cogging torque as compared to current generation AFMs.

Abstract: An organic polymer photo device with broadband response and high photo-responsitivity includes an anode terminal with a hole transporting network, and a cathode terminal with an electron transporting network. Positioned in electrical communication with the hole transporting network and the electron transporting network is a blended material that has at least one organic polymer light absorbing component. The organic light absorbing component is configured to have a collection length that is larger than the distance to the nearest electron transporting network and hole transporting network. As such, the blended material forms a light absorbing area that has a dimension that is greater than the collection length of the organic polymer light absorbing component.

Abstract: In various embodiments the invention is directed to a structured filament for use in fused filament fabrication comprising an inner core comprising an first polymer or polymer blend; and an outer shell surrounding said inner core comprising a second polymer or polymer blend having ionic or crystalline functionality; wherein said first polymer or polymer blend has a higher solidification temperature than said second polymer or polymer blend. The ionic or crystalline functionality of the outer shell material strengthen the interface between the printed layers. This structured filament leads to printed 3D structures having improved dimensional fidelity and impact resistance in comparison to the individual components. The impact resistance of structures printed from these is greatly increased as energy is dissipated by delamination of the shell from the core near the crack tip, while the core remains intact to provide stability to the part after impact.

Abstract: A method for increasing the lipid content of algae includes combining algae and a lipid-precipitating addition in a growth-inhibitive medium, the growth-inhibitive medium being deficient in at least one nutrient that is necessary for reproductive growth of algae, thus frustrating algae reproduction, the lipid-precipitating addition selected from hydroxyl-containing compounds and amine-containing compounds. An organic acid addition may also be combined with the lipid-precipitating addition and algae in the growth-inhibitive medium, the organic acid addition including compounds containing carboxylic acid functionality. Direct production of biodiesel is also achieved by the use of particular lipid-precipitating additions and organic acid additions.

Abstract: Embodiments provide an integrated motor-compressor assembly including a rotating impeller to compress a fluid passing therethrough, and diffuser vanes radially spaced from the impeller, each of the diffuser vanes including a stator winding therearound, the stator windings being supplied with current to generate sufficient magnetic flux for rotating the impeller. Embodiments provide an integrated motor-compressor assembly including a volute casing housing a rotating impeller to compress a fluid passing therethrough, a stator fixedly positioned in the volute casing proximate to the impeller, the stator including stator poles axially spaced from the impeller, each of the stator poles including a stator winding, the stator windings being supplied with current to generate sufficient axial magnetic flux for rotating the impeller.

Abstract: A multi-purpose imaging and display system includes a display; a detector coupled to the display and having a field of view; and a filter communicating with the detector. The field of view is imaged by the detector through the filter, the filter configured to be sensitive to a first frequency spectrum, so the detector displays only objects within the field of view on the detector that emit one or more frequencies within the first frequency spectrum. The detector and filter can work together in different operational states or modes for acquiring image data of a target object under investigation. A computing device can be included to process acquired image data, and communication interfaces can be employed to achieve networking of multiple systems. A peripheral interface allows a plurality of peripheral devices to be selectively added to tailor the data acquisition and display capabilities of the imaging and display system.

Abstract: A star block copolymer and a thermoplastic elastomer including plurality of the star block copolymers and a method of making both is taught. The star block copolymers of the present invention include a core component having an -methylstyrene oligomer wherein arms emanate from the core component and the arms are poly(isobutylene-block-styrene) diblock copolymers.

Abstract: The present invention relates to a cell culture support including a substrate and a thermoresponsive polymeric blend layer, wherein the polymeric blend layer includes at least one thermoresponsive polymer and at least one network forming adhesion promoter. The present invention further relates a method of making a cell culture complex including: providing a substrate; blending at least one thermoresponsive polymer and at least one network forming adhesion promoter to provide a polymeric blend; applying a thin film of said polymeric blend to the substrate to provide a polymeric blend layer on the substrate; curing the polymeric blend layer on the substrate to provide a cell culture support; and depositing cells onto said cell culture support, wherein the cells may optionally further include medium, to provide a cell culture complex.