Abstract: Hydroxyl-functional disiloxanes and hydroxyl-functional polysiloxane oligomers are provided which contain hydroxyl groups bound to the silicon via Si--C bonds. These compounds may be crosslinked to form polysiloxane networks having improved mechanical strength or reacted to form linear, siloxane containing block copolymers.
Abstract: Polymeric materials are provided characterized by hard segments and copolymer soft blocks comprising hydrophobic and hydrophilic components. The polymeric materials may be mixed with a base polymer and/or inorganic salts. The polymeric materials and mixtures containing same are characterized by improved moisture vapor transmission rates. The polymeric materials may be formed into films for use as wound dressings, burn dressings, surgical drapes, semipermeable membranes, and coatings for textiles.
Abstract: A polymer admixture is formed from a base polymer and thermoplastic copolymer additive including polar hard segments and polar and nonpolar soft blocks in graft or block copolymer form. The polymer admixture is characterized by increased contact angle hysteresis and is formed into blood and tissue-contacting surfaces of a biomedical device or into textiles. A preferred additive comprises a segmented block copolymer having polydialkylsiloxanes as nonpolar soft blocks, and a polyurethane as hard segments and a polyalkylene oxide as a polar soft block.
Abstract: Novel linear polysiloxane-polylactone block copolymers are useful as surface modifying additives due in part to their miscibility with a wide variety of base polymers. A particularly preferred polysiloxane-polycaprolactone linear blocked copolymer is miscible with nylon and is useful for forming surface modified nylon products.
Abstract: Novel block copolymers are provided, comprising poly(oxazoline) blocks and polysiloxane blocks. Novel polysiloxane intermediates for preparing such block copolymers are also provided which contain benzyl halide terminal groups. The block copolymers are useful as surface-modifying additives for base polymers.