Patents Assigned to Tokuyama Dental Corporation
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Publication number: 20130324635Abstract: A dental curable composition includes: a radically polymerizable monomer; a polymerization initiator; and a hyperbranched polymer, in which the hyperbranched polymer includes a unit structure represented by the general formula (I) and unit structures represented by the general formula (IIA) and/or the general formula (IIB) (in the general formula (I), A represents a single bond for bonding C and R1, >C?O, —O—, or —COO—, R1 represents a divalent saturated aliphatic hydrocarbon group or a divalent aromatic hydrocarbon group, and R2 represents a hydrogen atom or a methyl group; and in the general formula (IIA) and the general formula (IIB), R3, R4, and R5 each represent a hydrogen atom, an alkyl group, an alkoxycarbonyl group, an aryl group, or a cyano group, and R6 represents an alkylene group).Type: ApplicationFiled: February 10, 2012Publication date: December 5, 2013Applicant: TOKUYAMA DENTAL CORPORATIONInventors: Tomonao Shimizu, Tatsuya Yamazaki, Hideki Kazama, Hironobu Akizumi
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Patent number: 8546459Abstract: Provided is a filling/restoring material, including a photopolymerization initiator of a quaternary system formed by combining an ?-diketone compound, an aliphatic amine compound, an aromatic amine compound, and a photoacid generator, in which even when the filling/restoring material is filled and cured on a cured layer of a dental adhesive material including a radical-polymerizable monomer having an acidic group, the filling/restoring material undergoes sufficient curing up to a contact interface between the filling/restoring material and the cured layer, thereby providing high adhesive strength stably.Type: GrantFiled: February 3, 2010Date of Patent: October 1, 2013Assignee: Tokuyama Dental CorporationInventors: Mihoko Kajikawa, Takeshi Suzuki
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Publication number: 20130220172Abstract: To suppress a curing agent paste stored in a sealed state in a packaging container from self-curing over a long period of time, provided are a dental alginate impression material as described below, and a curing agent paste to be used for the dental alginate impression material. The dental alginate impression material may includes: a base material paste including as main components: an alginic acid salt (A); and water (B); and a curing agent paste including as main components: a gelling reaction agent (C); a poorly water-soluble organic solvent (D); and a humectant (E).Type: ApplicationFiled: October 21, 2011Publication date: August 29, 2013Applicant: TOKUYAMA DENTAL CORPORATIONInventors: Yuko Nagasawa, Koji Matsushige, Hidetoshi Gyakushi
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Patent number: 8513327Abstract: An adhesive composition for dental use exhibiting acidic property, including a mixture of a polymerizable monomer component (A) containing a phosphoric acid-type polymerizable monomer having an acidic group derived from phosphoric acid, and a multivalent metal ion-releasing component (B), wherein the multivalent metal ion-releasing component (B) is capable of releasing at least earth metal ions, and in the composition, earth metal ions stemming from the component (B) are present together with the phosphoric acid-type polymerizable monomer in such an amount that a total valency ratio (RE) defined by the following formula (1) is in a range of 0.2 to 3.0. The adhesive composition is capable of strongly adhering and fixing a composite resin or a prosthetic material to a tooth for extended periods of time maintaining stability.Type: GrantFiled: November 8, 2007Date of Patent: August 20, 2013Assignee: Tokuyama Dental CorporationInventors: Koji Matsushige, Takeshi Suzuki, Shizuka Shimizu, Ayumi Dodomi
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Patent number: 8506298Abstract: Provided is a dental filling/restoration kit, in which a pretreatment material and a filling/restoring material can be cured by only one irradiation with light, which enables further improved adhesion between a tooth and the filling/restoring material, which prevents the filling/restoring material from being easily colored, to thereby exhibit its excellent sensuousness. Specifically provided is a dental filling/restoration kit which includes: a filling/restoring material (A) containing 100 parts by mass of a radical-polymerizable monomer (a) containing 3 to 30 parts by mass of a water-soluble radical-polymerizable monomer having no acidic group (a1), a photopolymerization initiator (b), and a filler (c), the filler (c) being contained in an amount of 80 to 2,000 parts by mass relative to 100 parts by mass of the radical-polymerizable monomer (a); and a pretreatment material (B) containing a radical-polymerizable monomer having an acidic group (d) and water (e).Type: GrantFiled: June 5, 2008Date of Patent: August 13, 2013Assignee: Tokuyama Dental CorporationInventors: Takeshi Suzuki, Hideki Kazama
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Patent number: 8497312Abstract: An adhesive composition comprising (A) a polymerizable monomer component containing not less than 5% by mass of an acidic group-containing polymerizable monomer, (B) a polyvalent metal ion-eluting filler, (C) a volatile organic solvent, and (D) water, wherein the polyvalent metal ion-eluting filler (B) is blended in such an amount that the amount of the polyvalent metal ions eluted out from the filler becomes 1.0 to 7.0 meq per gram of the polymerizable monomer component (A), the volatile organic solvent (C) is blended in an amount in a range of 30 to 150 parts by mass per 100 parts by mass of the polymerizable monomer component (A) and so as to satisfy 20·X parts by mass or more (X is a number representing the amount of elution of the polyvalent metal ions), and the water (D) is blended in an amount of 3 to 30 parts by mass per 100 parts by mass of the polymerizable monomer component (A).Type: GrantFiled: November 24, 2008Date of Patent: July 30, 2013Assignee: Tokuyama Dental CorporationInventors: Koji Matsushige, Makoto Oguri, Shizuka Shimizu, Takeshi Suzuki
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Publication number: 20130175300Abstract: [Problems] To provide an ejection container capable of falling a liquid in drops from the container body without relying on the sense of the fingertips and without affected by a change in the temperature. [Means for Solution] A knock-type ejection container 1 in which an ejection port 8 is provided at one end of a container body 2, a knock button 4 is provided at the other end thereof, a container chamber 22 is provided in the container body 2 to contain a liquid, and the liquid contained in the container chamber 22 is ejected from the ejection port 8 being interlocked to the operation of the knock button 4.Type: ApplicationFiled: September 5, 2011Publication date: July 11, 2013Applicant: Tokuyama Dental CorporationInventors: Hidetoshi Gyakushi, Nobutoshi Yamaguchi
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Publication number: 20130068132Abstract: Disclosed is a kit for adhesion between an alginate impression material for dental use and an impression tray, which contains: (U) a pretreatment agent that contains (I) 100 parts by mass of an organic solvent that has a solubility parameter (?) of 17.0-23.0 [(MPa)1/2] and (II) 0.1-30 parts by mass of inorganic particles having an average particle diameter of 10 ?m or less; and (V1) an adhesive that contains (I) a polyamine compound that contains two or more amino groups in each molecule and (III) a lower alcohol solvent, or (V2) an adhesive that is obtained by mixing (I) a polyamine compound that contains two or more amino groups in each molecule, (II) an organic peroxide and (III) a lower alcohol solvent.Type: ApplicationFiled: May 10, 2011Publication date: March 21, 2013Applicant: TOKUYAMA DENTAL CORPORATIONInventors: Kouji Matsushige, Makoto Oguri
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Publication number: 20130071804Abstract: The present invention discloses an adhesive for orthodontic attachments, which contains (A) a polymerizable monomer, (B) a polymerization initiator and (C) a fluorescent dye and, when cured, exhibits a fluorescence spectrum having a peak at 400 to 800 nm. As the polymerization initiator (B), there is preferably used a compound which generates a radical through the transfer of hydrogen between two components, or a compound which generates a radical species through intramolecular cleavage. As the fluorescent dye (C), a coumarin type dye is used preferably.Type: ApplicationFiled: November 9, 2012Publication date: March 21, 2013Applicants: TOKUYAMA DENTAL CORPORATION, NIHON UNIVERSITYInventors: Yasuhiro Namura, Noriyoshi Shimizu, Shizuka Amma, Takeshi Suzuki, Hideki Kazama
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Patent number: 8394869Abstract: Disclosed are photopolymerizable compositions suitable for uses such as dental composite resins, and that comprise (A) a radical-polymerizable monomer, (B) a photopolymerization initiator that comprises (B1) an ?-diketone compound, (B2) a photoacid generating agent, (B3) an aromatic amine compound, and (C) an organic filler containing a phthalate ester fluorescent agent.Type: GrantFiled: May 20, 2009Date of Patent: March 12, 2013Assignee: Tokuyama Dental CorporationInventors: Hironobu Akizumi, Junichiro Yamagawa
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Publication number: 20130032058Abstract: Provided is an aqueous composition containing alginic acid or a derivative thereof, the composition having a viscosity retained stably over a long period of time. The alginic acid-containing aqueous composition includes alginic acid or a derivative thereof (A), water (B), and a non-reducing sugar (C). Also provided are a dental alginate impression material and a base material for a dental alginate impression material each using the composition, in which the viscosity of the aqueous composition is stably maintained for a long period.Type: ApplicationFiled: April 20, 2011Publication date: February 7, 2013Applicant: TOKUYAMA DENTAL CORPORATIONInventors: Hidetoshi Gyakushi, Koji Matsushige, Yuko Nagasawa
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Publication number: 20130032241Abstract: [Problems] To fill a container with a material without applying a high pressure to the material that is to be filled. [Means for Solution] An ejection device 1 comprises a filling chamber 24 formed in a cylindrical member for containing a material to be filled, a discharge portion 7 having a discharge nozzle 12 for pouring out the filled material to the exterior, and a piston 4 that pushes the filled material toward the front end side of the filling chamber 24 to discharge the filled material through the discharge nozzle 12. In the ejection device 1, the discharge portion 7 is formed separately from the filling chamber 24 and in a manner to be fitted to an opening on one end side of the cylindrical member 24, the opening serving as a filling port for filling the material to be filled, and after the material to be filled is poured into the filling chamber 24 through the filling port, the discharge portion 7 is coupled to the filling chamber 24.Type: ApplicationFiled: April 20, 2011Publication date: February 7, 2013Applicant: TOKUYAMA DENTAL CORPORATIONInventors: Nobutoshi Yamaguchi, Hironobu Akizumi, Yusaku Andoh
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Patent number: 8357731Abstract: A one-package type tooth surface coating material that is capable of forming, on the surface of a tooth, a cured film having not only a very high strength of adhesion to the tooth surface but also excellent properties such as long-term adhesion, long-term durability, dentinal tubule occlusion and aesthetic appearance, and that has excellent storage stability and can be stored in the form of one package. The one-package type tooth surface coating material includes (A) a polymerizable monomer component containing not less than 5% by mass of an acidic group-containing polymerizable monomer; (B) polyvalent metal ions; (C) a volatile water-soluble organic solvent; (D) water; and (E) an effective amount of a photopolymerization initiator; the amount of the polyvalent metal ions (B) and the amount of the volatile water-soluble organic solvent (C) satisfying a specific relationship.Type: GrantFiled: October 8, 2008Date of Patent: January 22, 2013Assignee: Tokuyama Dental CorporationInventors: Koji Matsushige, Qian Cui, Mikio Kimura
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Publication number: 20130005846Abstract: Disclosed is an organic/inorganic composite filler that contains: inorganic agglomerated particles comprising agglomerations of inorganic primary particles having a mean diameter between 10 and 1000 nm; an organic resin phase that covers the surface of each inorganic primary particle and binds the inorganic primary particles to each other; and intra-agglomerate voids, formed between the organic resin phase covering the surface of each inorganic primary particle, with a pore volume (here, “pore” refers to holes with diameters between 1 and 500 nm) between 0.01 and 0.30 cm3/g as measured by mercury intrusion porosimetry. Also disclosed is a method for manufacturing the above organic/inorganic composite filler.Type: ApplicationFiled: March 11, 2011Publication date: January 3, 2013Applicant: TOKUYAMA DENTAL CORPORATIONInventors: Tatsuya Yamazaki, Hironobu Akizumi
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Publication number: 20120238658Abstract: [Problems] To provide a liquid dental adhesive composition which contains a phosphoric acid-type compound having a hydrogenphosphoric diester group as an acidic group-containing polymerizable monomer and, further, contains polyvalent metal ions, effectively preventing not only the gelation but also the formation of precipitates (cloudiness) during the storage.Type: ApplicationFiled: December 2, 2010Publication date: September 20, 2012Applicant: TOKUYAMA DENTAL CORPORATIONInventors: Koji Matsushige, Qian Cui, Ayumi Dodomi
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Publication number: 20120160718Abstract: [Problems] To provide a two-liquid mixing container which prevents two liquids from being mixed together by erroneous operation and does not permit sheet-like contaminants from mixing into the mixed liquid. [Means for Solution] A container body 2 of the two-liquid mixing container 1 is provided with liquid injection openings 7a, 8a for feeding different treating solutions into a plurality of liquid chambers 7, 8. A liquid chamber opening/closing member 4 is provided with sealing members which are fitted into one end side of the container body 2 and, at an advanced position of having entered into the liquid injection openings, work to close the liquid injection openings 7a, 8a to separately close the liquid chambers 7, 8 and, at a reversed position, work to open the liquid injection openings 7a, 8a permitting the liquid chambers 7, 8 to be communicated with each other.Type: ApplicationFiled: August 20, 2010Publication date: June 28, 2012Applicant: TOKUYAMA DENTAL CORPORATIONInventors: Nobutoshi Yamaguchi, Hidetoshi Gyakushi
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Publication number: 20120121804Abstract: Disclosed is a method for producing silica-zirconia composite oxide particles each coated with a silica layer, which is characterized in that a liquid dispersion of silica-zirconia composite oxide particles is obtained by reacting an alkoxide of silicon and/or a condensable compound derived from the alkoxide with an alkoxide of zirconium and/or a condensable compound derived from the alkoxide in a water-containing solvent that contains acetonitrile so that the reaction liquid is to contain not less than 10% by mass of acetonitrile, and then the surface of each silica-zirconia composite oxide particle is coated with a silica layer by reacting the silica-zirconia composite oxide particles dispersed in the liquid dispersion with an alkoxide of silicon and/or a condensable compound derived from the alkoxide in the liquid dispersion of silica-zirconia composite oxide particles.Type: ApplicationFiled: August 2, 2010Publication date: May 17, 2012Applicant: TOKUYAMA DENTAL CORPORATIONInventors: Masato Sekino, Masatsugu Kusano
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Publication number: 20120059079Abstract: A dual-cure curable material kit comprising: (A) a radical-polymerizable monomer component; (B) a photopolymerization initiator component comprising (b1) an ?-diketone compound, (b2) an aliphatic tertiary amine compound having a tertiary amino group in which three saturated aliphatic groups are bonded to a nitrogen atom and one of the saturated aliphatic groups has an electron-withdrawing group as a substituent, and (b3) an s-triazine compound having a trihalomethyl group as a substituent, or a diaryliodonium salt compound; and a chemical polymerization initiator component (C) comprising (c1) an organic peroxide, and (c2) an N,N-di(hydroxyalkyl)-p-toluidine compound; which is packed separately at least in two packages so that the component (b2) and the component (b3) of the photopolymerization initiator component (B) are not packed together in a single package and the component (c1) and the component (c2) of the chemical polymerization initiator component (C) are not packed together in a single package.Type: ApplicationFiled: December 8, 2009Publication date: March 8, 2012Applicant: TOKUYAMA DENTAL CORPORATIONInventors: Kyoichi Fujinami, Kazuhiko Okishio
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Patent number: 8104609Abstract: A container which is not bulky at the time of shipping and can be stably stood on a suitable place. The container includes a lid member for closing a take-out opening (brittle portion) of the container body 2. On the lower outer side of the container body, there are formed slits for fitting the lid member to the container body after the container body and the lid member are separated apart, and auxiliary leg portions that protrude outward of the container body. The lid member is forming holding leg portions that protrude outward therefrom. Wing portions of the holding leg portions are inserted in the slits to fit the lid member to the container body, and the erected attitude of the container body is supported by the holding leg portions.Type: GrantFiled: March 7, 2008Date of Patent: January 31, 2012Assignee: Tokuyama Dental CorporationInventors: Koji Matsushige, Masayuki Aizawa, Nobutoshi Yamaguchi, Ayumi Dodomi
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Publication number: 20120006709Abstract: A container which is not bulky at the time of shipping and can be stably stood on a suitable place. The container includes a lid member for closing a take-out opening (brittle portion) of the container body 2. On the lower outer side of the container body, there are formed slits for fitting the lid member to the container body after the container body and the lid member are separated apart, and auxiliary leg portions that protrude outward of the container body. The lid member is forming holding leg portions that protrude outward therefrom. Wing portions of the holding leg portions are inserted in the slits to fit the lid member to the container body, and the erected attitude of the container body is supported by the holding leg portions.Type: ApplicationFiled: September 20, 2011Publication date: January 12, 2012Applicant: Tokuyama Dental CorporationInventors: KOJI MATSUSHIGE, Masayuki Aizawa, Nobutoshi Yamaguchi, Ayumi Dodomi