Patents Assigned to Tonen Corporation
  • Patent number: 5547597
    Abstract: A lubricating oil composition for two-cycle engines, consisting essentially of, by weight: (1) 30% to 70% of a polyol ester having a kinematic viscosity of 9 to 15 cSt at 100.degree. C., 30% to 70% of a diester having a kinematic viscosity of 2 to 5 cSt at 100.degree. C., 1% to 5% of a polybutene having a molecular weight of 500 to 2,500 and/or 1% to 5% of a polymethacrylate having a molecular weight of 5,000 to 40,000, and 5% to 25% of a dispersant; or (2) 30% to 70% of a polyol ester having a kinematic viscosity of 4 to 15 cSt at 100.degree. C., 0% to 35% of a complex ester having a kinematic viscosity of 10 to 14 cSt at 100.degree. C., 10% to 70% of a diester having a kinematic viscosity of 2 to 5 cSt at 100.degree. C., and. 5% to 25% of a dispersant; or (3) a lubricating oil base, 5% to 25% of a polyamide dispersant, and 0.1% to 5% of a combination of a neutral calcium sulfonate and a neutral calcium salicylate, based on the total weight of the composition.
    Type: Grant
    Filed: May 18, 1995
    Date of Patent: August 20, 1996
    Assignee: Tonen Corporation
    Inventors: Katsuya Koganei, Takeshi Nomura, Toshiaki Kuribayashi, Noboru Umemoto
  • Patent number: 5542229
    Abstract: A simple reinforcement for concrete pole improving the elasticity of the pole is provided. A reinforcing layer of a fiber-reinforced composite material is applied to a portion of the outer circumference of the concrete pole 9 that comprises reinforced concrete. The reinforcing layer 11 covers a depth of at least 30 cm and a height of at least 100 cm relative to the ground level when the concrete pole 9 is placed in the ground. Reinforcing fibers 4 of the reinforcing layer 11 are oriented in the axial direction of the reinforced concrete. The total cross-sectional area (S.sub.R) and modulus of elasticity (E.sub.R) of the reinforcing fibers 4 of the reinforcing layer 11 satisfy the following relational formula relative to the total cross-sectional area (S.sub.S) and modulus of elasticity (E.sub.S) of the axial reinforcing bar of the reinforced concrete:0.06<E.sub.R .multidot.S.sub.R /E.sub.S .multidot.S.sub.S <3.0.
    Type: Grant
    Filed: May 11, 1994
    Date of Patent: August 6, 1996
    Assignee: Tonen Corporation
    Inventors: Makoto Saito, Yoshinori Tanaka
  • Patent number: 5540905
    Abstract: An optically anisotropic pitch, which is suited for manufacturing particularly high compressive strength carbon fibers in a stable fashion, with satisfactory productivity and continuously, and also a method of manufacturing high compressive strength carbon fibers using the optically anisotropic pitch.The optically anisotropic pitch for manufacturing high compressive strength carbon fibers is composed of a benzene soluble component (BS) and a benzene insoluble component (BI) and has a Q value (i.e., weight-average molecular weight divided by number-average molecular weight) of 1.6 or below, a number-average molecular weight ratio of the benzene soluble component to the benzene insoluble component of 2.5 or below, an aromatic carbon fraction factor (fa) of 0.8 or below, a C/H atomic ratio of 1.85 or below and an optically anisotropic phase of 90% or more.
    Type: Grant
    Filed: September 15, 1994
    Date of Patent: July 30, 1996
    Assignees: Tonen Corporation, Mitsubishi Gas Chemical Co., Inc.
    Inventors: Tsutomu Naito, Takashi Hino, Masaru Miura, Kazuyuki Murakami
  • Patent number: 5514292
    Abstract: The invention concerns a lubricating oil composition in which a lubricating oil base contains 0.1% by weight to 20% by weight of an aromatic glycidyl carboxylate having the following general formula (1): ##STR1## wherein R is a C.sub.6-14 aryl or alkylaryl group, and n represents an integer of 1 or 2, and/or 0.05% by weight to 10% by weight of a phosphonate type additive having the following general formula (2): ##STR2## where R.sub.1 or R.sub.2 is selected from the group consisting of alkyl, aralkyl, aryl and hydroxyalkyl groups that may or may not have a substitute, and two R.sub.2 groups may be identical with or different from each other, and which is excellent in stability to hydrolysis, heat and oxidation as well as in lubricating properties, and so provides a particularly excellent refrigerating oil composition.
    Type: Grant
    Filed: August 8, 1994
    Date of Patent: May 7, 1996
    Assignee: Tonen Corporation
    Inventors: Takehisa Sato, Toshiaki Kuribayashi, Hironari Ueda
  • Patent number: 5512119
    Abstract: The present invention relates to a hybrid prepreg having reinforcing carbon fibers and foreign fibers. The carbon fibers have a diameter ranging from 5-30 microns and are unidirectionally arranged. The foreign fibers are composed either of single monofilaments having a diameter ranging from between about 50-150 microns or of strands formed by bundling together a plurality of single monofilaments having a diameter ranging from between about 5-50 microns. If strands are employed, they have a conversion diameter (D.sub.0) which is less than about 500 microns. The conversion diameter (D.sub.0) is represented by the following equation: ##EQU1## wherein n is the number of monofilaments used in forming the strand, and wherein d is the diameter of these monofilaments. Examples of foreign fibers which can be used when practicing this invention include boron fibers, metal fibers and organic fibers.
    Type: Grant
    Filed: September 27, 1993
    Date of Patent: April 30, 1996
    Assignee: Tonen Corporation
    Inventors: Makoto Takezawa, Makiji Miyao, Sadahisa Wada, Hiroshi Inoue
  • Patent number: 5502114
    Abstract: The present invention provides a linear polyolefin wherein one of the terminals of linear polypropylene or linear ethylene-propylene random copolymer is modified with a (meth)acrylic derivative unit or styrene derivative unit to give a substantially monodipersed system. The feature thereof consists in such a linear polyolefin in which the terminal of linear polypropylene or linear ethylene-propylene random copolymer obtained by living polymerization is modified with a (meth)acrylic derivative unit or styrene derivative unit. For the production thereof, there are used methacrylic acid chloride, acrylic acid chloride, ethylene glycol dimethacrylate, etc. as the (meth)acrylic derivative, and divinylbenzene, etc. as the styrene derivative.
    Type: Grant
    Filed: March 16, 1994
    Date of Patent: March 26, 1996
    Assignee: Tonen Corporation
    Inventors: Naomi Murakami, Miyuki Usui, Hiroyuki Furuhashi, Satoshi Ueki
  • Patent number: 5494978
    Abstract: A stabilized polysilazane obtained by reacting an inorganic polysilazane having a number average molecular weight of about 100 to about 100,000 with an alcohol, an organic acid, an ester, a ketone, an aldehyde, a mercaptan, or an alkysilazane preferably at a molar ratio of from 50/50 to 99.99/0.01 is described.
    Type: Grant
    Filed: November 30, 1994
    Date of Patent: February 27, 1996
    Assignee: Tonen Corporation
    Inventors: Yasuo Shimizu, Yuuji Tashiro, Hiroyuki Aoki, Masaaki Ichiyama, Hayato Nishii, Toshihide Kishi, Kouji Okuda, Takeshi Isoda
  • Patent number: 5459114
    Abstract: Repetition of a process of impregnating a metal fiber or ceramic fiber preform or porous ceramic with (3) a mixture of polysilazane-type polymers with a number average molecular weight of 200-3000 and a viscosity adjusted to 100 Pa.s or lower at the impregnation temperature, prepared by mixing (1) one or more types of polysilazane-type polymers with a number average molecular weight of 200-3000 and a viscosity of less than 1 Pa.s at the impregnation temperature with (2) one or more types of polysilazane-type polymers with a number average molecular weight of 200-100,000 and having a viscosity of 1 Pa.s or higher or solid at the impregnation temperature, which are selected from polysilazanes whose main repeating unit is --[(SiH.sub.2).sub.n (NH).sub.r ]-- (where n and r are 1, 2 or 3), and copolymers, modified polymers and crosslinked polymers based thereon, and performing crosslinking curing and then firing, is performed for its conversion into a ceramic.
    Type: Grant
    Filed: July 25, 1994
    Date of Patent: October 17, 1995
    Assignee: Tonen Corporation
    Inventors: Hiroshi Kaya, Kiyoshi Sato, Hiroki Morozumi, Atushi Tezuka, Tomoko Aoki, Hirohiko Nakahara, Tadashi Suzuki, Takeshi Isoda
  • Patent number: 5444119
    Abstract: The thermoplastic resin composition of the present invention is made of:(a) 5-95 weight % of polypropylene;(b) 95-5 weight % of a polyester; and(c) 2-70 parts by weight, per 100 parts by weight of the total of (a) + (b), of a polyolefin-polyester graft copolymer.The polyolefin-polyester graft copolymer is constituted by 10-90 parts by weight of a polyester having an intrinsic viscosity [n] of 0.30-1.20 and an end carboxyl group content of 15-200 milliequivalent/kg; and (B) 90-10 parts by weight of a modified polyolefin having an epoxy group or carboxyl group content of 0.2-5 mol % and a weight-average molecular weight of 8,000-140,000. This thermoplastic resin composition may further contain (d) a modified polypropylene grafted with an unsaturated carboxylic acid or its anhydride.
    Type: Grant
    Filed: December 3, 1993
    Date of Patent: August 22, 1995
    Assignee: Tonen Corporation
    Inventors: Yuji Fujita, Tetsuya Kawamura, Kouichi Yokoyama, Katsuyuki Yokomizo, Shigeyuki Toki
  • Patent number: 5436039
    Abstract: Artificial snow granule in granule form comprising a super absorbent polymer in granule form as a nucleus and an ice layer surrounding the nucleus is provided here. An aggregate form is provided by linkage of adjacent two ice layers and/or two granules. Further, a snow granule quality improver is provided. A method for making the above-mentioned snow granule in granule or an aggregate form is also provided here.
    Type: Grant
    Filed: August 30, 1993
    Date of Patent: July 25, 1995
    Assignees: Miura Dolphins, Co., Ltd., Tonen Corporation, Osaka Organic Chemical Industry Co., Ltd., Tonen Chemical Corp., Sanyo Electric Co., Ltd., Ohtsuka, Masahisa, Ohizumimachi
    Inventors: Yuichiro Miura, Kazuo Hirano, Takayuki Nate, Taiji Kambayashi, Masahisa Ohtsuka, Toshitake Nagai
  • Patent number: 5436297
    Abstract: A modified polyolefin comprising: (A) 100 parts by weight of a polyolefin; (B) 0.01 to 20 parts by weight of a monomer mixture consisting of: (b-1) 5 to 50% by mole of glycidyl acrylate, glycidyl methacrylate or an unsaturated glycidyl compound represented by general formula (I) below ##STR1## wherein R is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms; Ar is an aromatic hydrocarbon group having 6 to 20 carbon atoms and having at least one glycidyl group; and n is an integer of 1 to 4, and (b-2) 95 to 50% by mole of at least one monomer selected from the group consisting of acrylamide monomers, vinylpyrrolidones, acrylic acid esters and methacrylic acid esters, the monomer mixture being graft-copolymerized with the polyolefin.
    Type: Grant
    Filed: October 27, 1993
    Date of Patent: July 25, 1995
    Assignee: Tonen Corporation
    Inventors: Tatsuo Teraya, Shintaro Kikuchi, Kouichi Yokoyama, Yuji Fujita
  • Patent number: 5436398
    Abstract: A preceramic polymetalosilazane substantially free of Si-O groups is produced by reacting a polysilazane with a metal alkoxide in the presence of an alkylsilazane or alkylsilane. The preceramic polymer gives a high strength and heat resistant ceramic body which remains amorphous when calcined at 1,600.degree. C. for 10 hours in the atmosphere of nitrogen.
    Type: Grant
    Filed: April 6, 1994
    Date of Patent: July 25, 1995
    Assignee: Tonen Corporation
    Inventors: Yasuo Shimizu, Hirohiko Nakahara, Tomoko Aoki, Osamu Funayama, Takeshi Isoda
  • Patent number: 5424411
    Abstract: A hybrid upstream regulatory sequence including an upstream regulatory sequence of E. coli origin and yeast upstream regulatory sequence, which hybrid upstream regulatory sequence can function in a yeast cell; a hybrid promoter including the regulatory sequence of E. coli origin and a TATA region of a yeast promoter, which hybrid promoter can also function in a yeast cell; a hybrid promoter including the upstream regulatory sequence of E. coli origin and a yeast promoter, which hybrid promoter can function in a yeast cell; and a plasmid useful for a test of an upstream regulatory sequence, including a TATA region of a yeast promoter, a structural gene containing a translation start codon, and a yeast origin of replication.
    Type: Grant
    Filed: August 28, 1991
    Date of Patent: June 13, 1995
    Assignee: Tonen Corporation
    Inventors: Shintaro Yagi, Kiyoko Tanaka, Juri Yoshioka, Masanori Suzuki
  • Patent number: 5416015
    Abstract: A yeast PPIase characterized by possessing following properties: (1) acting on and isomerizing the bond X.sub.aa -Pro (wherein X.sub.aa stands for any amino acid and Pro stands for L-proline), (2) exhibiting a single molecular weight of about 17,000 daltons in the sodium dodecyl sulfate-polyacrylamide concentration gradient gel electrophoresis, (3) exhibiting a single isoelectric point of about 6.2 in the isoelectric focusing, and (4) inhibited by CsA;an E. coli PPIase-.beta. characterized by possessing the following properties: (1) acting on and isomerizing the bond X.sub.aa -Pro (wherein X.sub.aa stands for any amino acid and Pro for L-proline), (2) exhibiting a single molecular weight of about 20,000 daltons in the sodium dodecyl sulfate-polyacrylamide concentration gradient gel electrophoresis, (3) exhibiting a single isoelectric point of about 5.0 in the isoelectric focusing, and (4) no being inhibited by CsA;an E. coli PPIase-.alpha.
    Type: Grant
    Filed: July 9, 1993
    Date of Patent: May 16, 1995
    Assignee: Tonen Corporation
    Inventors: Toshiya Hayano, Setsuko Katou, Noboru Maki, Nobuhiro Takahashi, Masanori Suzuki
  • Patent number: 5397636
    Abstract: A hybrid laminated prepreg is disclosed, which comprises a resin layer, a decorative layer laminated thereon and having a pattern, and a transparent prepreg layer laminated on the decorative layer. In manufacturing a fiber reinforced composite resin material molding, the hybrid prepreg is laminated in a couple of layers on the outermost one of laminated layers of usual prepreg. Thus, it is possible to easily decorate the obtainable molding to readily provide an aesthetic sense to the appearance of the molding and also dispense with time-consuming operation of coating or the like. Further, unlike the coating or the like, it is possible to stably hold the aesthetic sense of the appearance for long time.
    Type: Grant
    Filed: December 8, 1992
    Date of Patent: March 14, 1995
    Assignee: Tonen Corporation
    Inventors: Makiji Miyao, Osamu Watanabe, Makoto Takezawa, Hiroshi Inoue
  • Patent number: 5395607
    Abstract: The pitch based carbon fiber has a uniform crystal structure in which substantially all crystal fibriles constituting the fiber have the thickness ranging from 30 to 200% of the average thickness Lav. Uniform stress distribution over uniform crystal fibriles can be obtained. This permits suppresion of non-linearity of the compressive modulus of elasticity of carbon fiber to greatly improve the compressive strength thereof. Typically, a compressive strength of 100 to 170 kg/mm.sup.2 can be obtained with a tensile modulus of elasticity of 50 ton/mm.sup.2. Such carbon fiber can be obtained by securing uniformity of molecular weight distribution of the liquid crystal pitch and also uniformity of the orientation of the liquid crystal constituent molecules by the application of multi-stage high shear spinning.
    Type: Grant
    Filed: June 25, 1993
    Date of Patent: March 7, 1995
    Assignee: Tonen Corporation
    Inventors: Hiroshi Toshima, Tsutomu Naito, Takashi Hino, Kazuyuki Murakami
  • Patent number: 5387301
    Abstract: In the prepreg manufacuturing method according to the present invention, at least one of a first and second release papers is coated with a matrix resin having a low viscosity. Reinforcing fibers are supplied in between the release papers and arranged on the matrix resin layer. Then, the reinforcing fibers are impregnated with the matrix resin by heating and pressing the release papers. After separating one of the papers, a room-temperature curing type hardener is applied onto the matrix resin layer to form a high viscosity layer on a surface layer of the matrix resin layer. Thereafter, a cover film is laid over the surface layer to make a prepreg.
    Type: Grant
    Filed: November 29, 1993
    Date of Patent: February 7, 1995
    Assignee: Tonen Corporation
    Inventors: Makiji Miyao, Makoto Takezawa
  • Patent number: 5387370
    Abstract: Electroviscous fluid according to the present invention is used for vibration control machines and devices such as variable damper, engine mount, bearing damper, clutch, valve, shock absorber, precision machine, accoustic machine, etc. and for display element. It has high electroviscous effect and wider application temperature range, and the electroviscous effect is stable.
    Type: Grant
    Filed: March 24, 1993
    Date of Patent: February 7, 1995
    Assignee: Tonen Corporation
    Inventors: Hirotaka Tomizawa, Makoto Kanbara, Tetsuo Miyamoto
  • Patent number: 5382634
    Abstract: The object of the present invention is to provide such a polyolefin that only the terminal of polypropylene or ethylene-propylene random copolymer is modified with a (meth)acrylic derivative unit to give a substantially monodipersed system. The feature thereof consists in such a polyolefin that the terminal of polypropylene or ethylene-propylene random copolymer obtained by living polymerization is modified with a (meth)acrylic derivative unit. As the (meth)acrylic derivative, there are used vinyl methacrylate, allyl methacrylate, trimethylsiloxyethyl methacrylate, 2-trimethylsiloxypropyl methacrylate, N, N-dimethylaminoethyl methacrylate, N,N-diethylaminoethyl methacrylate, glycidyl methacrylate, acrylic acid chloride and like.
    Type: Grant
    Filed: April 25, 1994
    Date of Patent: January 17, 1995
    Assignee: Tonen Corporation
    Inventors: Naomi Koyama, Miyuki Usui, Hiroyuki Furuhashi, Satoshi Ueki
  • Patent number: 5382374
    Abstract: Hydraulic fluids for automobile suspensions are described. They contain, as a base oil, a mixed oil which in turn contains 70-90 wt. % of an olefin oligomer and 10-30 wt. % of a diester obtained by condensation of an aliphatic dibasic acid having 4-14 carbon atoms and an alcohol having 4-14 carbon atoms. The hydraulic fluids also comprise a phosphate ester friction modifier to improve the friction characteristics and antiwear characteristics in an initial stage and at least one friction modifier selected from the group consisting of phosphite esters and phosphoric ester amine salts to retain low friction characteristics over a long period of time.
    Type: Grant
    Filed: February 26, 1993
    Date of Patent: January 17, 1995
    Assignees: Tonen Corporation, Toyota Jidosha Kabushiki Kaisha
    Inventors: Koji Takemitsu, Kenyu Akiyama, Hiroshi Ohashi, Syoichi Ichikawa