Patents Assigned to TSRC Corporation
  • Publication number: 20240166789
    Abstract: The present invention provides a conjugated diene based rubber comprising a conjugated diene based copolymer comprising at least two conjugated diene monomer units and optionally comprising a vinyl aromatic hydrocarbon monomer unit, wherein the conjugated diene based copolymer comprises a first block composed of a first conjugated diene monomer unit and the vinyl aromatic hydrocarbon monomer unit or a second conjugated diene monomer unit, the second conjugated diene monomer unit being distinct from the first conjugated diene monomer unit, the first block being random; and a second block, comprising at least the second conjugated diene monomer unit and optionally comprising the vinyl aromatic hydrocarbon monomer unit, wherein the first block is connected to the second block, and the amount of the vinyl aromatic hydrocarbon monomer units or the second conjugated diene monomer units is at least 35 wt % of the first block.
    Type: Application
    Filed: November 17, 2023
    Publication date: May 23, 2024
    Applicant: TSRC Corporation
    Inventors: Chun-Lin Chen, Yun-Ta Lee
  • Patent number: 11939456
    Abstract: A composition for preparing a foam, a foam, and a shoe employing the foam are provided. The composition for preparing a foam includes 3-30 parts by weight of a first polymer and at least one of a second polymer and a third polymer. The first polymer is cyclic olefin polymer (COP), cyclic olefin copolymer (COC), metallocene based cyclic olefin copolymer (mCOC), fully hydrogenated conjugated diene-vinyl aromatic copolymer, or a combination thereof. The total weight of the second polymer and the third polymer is 70-97 parts by weight. The second polymer is polyolefin, olefin copolymer, or a combination thereof. The third polymer is conjugated diene-vinyl aromatic copolymer, partially hydrogenated conjugated diene-vinyl aromatic copolymer, or a combination thereof. The total weight of the first polymer and at least one of the second polymer and the third polymer is 100 parts by weight.
    Type: Grant
    Filed: July 20, 2018
    Date of Patent: March 26, 2024
    Assignee: TSRC CORPORATION
    Inventors: Hsi-Hsin Shih, Hsuan-Tsung Lin, Ying-Pin Tu, Han-Ming Tsai
  • Patent number: 11746226
    Abstract: The present invention provides a polymer composition for manufacturing a foam, the polymer composition comprising a vinyl aromatic based copolymer and a processing aid, wherein the amount of the processing aid in the total weight of the polymer composition is equal to or more than 5 wt % and equal to or less than 75 wt %; and the polymer composition does not comprise ethylene-vinyl acetate copolymer, ethylene-butyl acrylate copolymer, ethylene-?-olefin copolymer, homopolymer and copolymer of polyethylene, homopolymer and copolymer of polypropylene, homopolymer and copolymer of polybutene and olefin-based ionic polymer. The present invention also provides the foam and the method for forming the same.
    Type: Grant
    Filed: December 5, 2019
    Date of Patent: September 5, 2023
    Assignee: TSRC CORPORATION
    Inventors: Hsi-Hsin Shih, Chia-Hung Hsu, Pang-Hsuan Lin, Yun-Shiuan Yeh
  • Patent number: 11718771
    Abstract: The present invention provides a polymer composition for fibers or non-woven fabrics, comprising a vinyl aromatic based copolymer and 0 to 30 wt % of an olefin based polymer based on the total weight of the polymer composition. The vinyl aromatic copolymer is represented by a formula A1-B-A2, wherein block A1 and block A2 are the same or different vinyl aromatic blocks, block A1 or block A2 having 3,800 to 4,800 of a peak molecular weight, and block B is a hydrogenated conjugated diene block. A vinyl structure content of a conjugated diene monomer content in the vinyl aromatic based copolymer is from 32 wt % to 50 wt %; and a melt flow index (MFI) of the vinyl aromatic based copolymer is 20 g/10 min˜60 g/10 min (230° C., 2.16 kg). The present invention also provides the fibers or the non-woven fabrics made from the polymer composition.
    Type: Grant
    Filed: November 6, 2020
    Date of Patent: August 8, 2023
    Assignee: TSRC Corporation
    Inventors: Tai-Yi Shiu, Feng-Yu Yang, Yu-Chuan Tsai, Der-Kai Sun, Ching Ting
  • Patent number: 11208505
    Abstract: A catalyst composition for selectively hydrogenating a conjugated diene polymer in a homogeneous system is provided, wherein the conjugated diene polymer comprises a conjugated diene monomer or a combination of a conjugated diene monomer and a vinyl aromatic monomer. The catalyst composition includes the catalyst components of (a) a titanium compound; (b) an organometallic compound; and (c) an oligomer containing a polyglycol segment. The hydrogenated polymer produced using the catalyst composition and the method thereof is also provided.
    Type: Grant
    Filed: February 17, 2020
    Date of Patent: December 28, 2021
    Assignee: TSRC Corporation
    Inventors: Kuoyu Weng, Fengyu Yang, Wenhsien Wen, Ching Ting, Ting-Yu Lee
  • Patent number: 10934382
    Abstract: The present invention provides a conjugated diene polymer, formulations, and manufacturing methods for the same. The present invention provides a conjugated diene polymer obtained by polymerizing conjugated diene monomers and vinyl aromatic monomers using an initiator by way of an anionic polymerization, the conjugated diene polymer comprising a plurality of blocks having more than 6 consecutive vinyl aromatic units, wherein a vinyl aromatic monomer content of the plurality of blocks having more than 6 consecutive vinyl aromatic units is less than 5 wt % based on a total vinyl aromatic monomer content of the conjugated diene polymer. The present invention also provides formulations for preparing the conjugated diene polymer and the manufacturing methods for the same.
    Type: Grant
    Filed: October 8, 2018
    Date of Patent: March 2, 2021
    Assignee: TSRC Corporation
    Inventors: Juin-Meng Yu, Chin-Wei Chiou, Kun-Yi Chen, Adel Farhan Halasa
  • Patent number: 10844143
    Abstract: The present invention provides a modified rubber containing silicon and phosphorus, and a composition and manufacturing method thereof. The present invention provides the modified rubber structured as formula (1), wherein X is selected from a C1-C12 alkylene group, a C2-C12 alkenylene group, a C3-C12 alicyclic group, and a C6-C12 aromatic group; and A1, A2, A3, Y, and Z are each independently selected from an alkyl group, an alkoxy group, a halide group, and a conjugated diene rubber, wherein the conjugated diene rubber is a polymer composed of a conjugated diene monomer or the conjugated diene monomer with a vinyl aromatic monomer, A1, A2, A3, Y, and Z are the same or different from each other, and at least one of A1, A2, A3, Y, and Z is the conjugated diene rubber.
    Type: Grant
    Filed: October 8, 2018
    Date of Patent: November 24, 2020
    Assignee: TSRC Corporation
    Inventors: Chun-Lin Chen, Yun-Ta Lee, Adel Farhan Halasa
  • Patent number: 10787547
    Abstract: A thermoplastic elastomer composition for crosslinked foam and the manufacturing method thereof are provided. The thermoplastic elastomer composition comprising (A) an ethylene-based copolymer; (B) a first copolymer; (C) a second copolymer, wherein the component (B) and (C) are copolymers comprising a vinyl aromatic monomer and a conjugated diene monomer, the first copolymer having a conjugated diene hydrogenation rate of at least 80% and the second copolymer having a conjugated diene hydrogenation rate of no more than 10%; (D) an organic peroxide; and (E) a foaming agent, wherein a mass ratio (A/(B+C)) of the component (A) to a combination of the component (B) and the component (C) is 95/5 to 5/95; and a mass ratio (B/C) of the component (B) to the component (C) is 9/1 to 1/9. A crosslinked foam made from the composition and the manufacturing method thereof are also provided.
    Type: Grant
    Filed: January 24, 2018
    Date of Patent: September 29, 2020
    Assignee: TSRC Corporation
    Inventors: Ching Ting, Wen-Hsien Wen, Feng-Yu Yang, Hsuan-Tsung Lin, Ying-Pin Tu
  • Publication number: 20200216726
    Abstract: A pressure sensitive adhesive composition and a protective film employing the same are provided. The pressure sensitive adhesive composition includes 30-45 parts by weight of a tackifier and 55-70 parts by weight of a polymer. The polymer includes at least one block copolymer. The block copolymer includes a vinyl aromatic block polymerized by a vinyl aromatic monomer and a conjugated diene block polymerized by a conjugated diene monomer. The block copolymer meets one of the following conditions: (1) the content of the vinyl aromatic monomer is from 15 wt % to 25 wt % and the content of the vinyl group of the conjugated diene block is less than or equal to 45 wt % or, (2) the content of the vinyl aromatic monomer is from 10 wt % to 15 wt % and the content of the vinyl group of the conjugated diene block is less than or equal to 45 wt %, or greater than or equal to 60 wt %.
    Type: Application
    Filed: December 27, 2019
    Publication date: July 9, 2020
    Applicant: TSRC CORPORATION
    Inventors: Wen-Pin TSAI, Philip Chung-Ming YANG, Hsi-Hsin SHIH
  • Patent number: 10590209
    Abstract: A catalyst composition for selectively hydrogenating a conjugated diene polymer in a homogeneous system is provided, wherein the conjugated diene polymer comprises a conjugated diene monomer or a combination of a conjugated diene monomer and a vinyl aromatic monomer. The catalyst composition includes the catalyst components of (a) a titanium compound; (b) an organometallic compound; and (c) an oligomer containing a polyglycol segment. The hydrogenated polymer produced using the catalyst composition and the method thereof is also provided.
    Type: Grant
    Filed: November 28, 2017
    Date of Patent: March 17, 2020
    Assignee: TSRC Corporation
    Inventors: Kuoyu Weng, Fengyu Yang, Wenhsien Wen, Ching Ting, Ting-Yu Lee
  • Patent number: 10407532
    Abstract: A catalyst composition, a method for hydrogenating styrenic block copolymer employing the same, and a hydrogenated polymer from the method are provided. The method for hydrogenating styrenic block copolymer includes subjecting a hydrogenation process to a styrenic block copolymer in the presence of a catalyst composition. In particular, the catalyst composition includes an oxide carrier, and a catalyst disposed on the oxide carrier, wherein the catalyst includes a platinum-and-rhenium containing phosphorus compound.
    Type: Grant
    Filed: August 14, 2017
    Date of Patent: September 10, 2019
    Assignee: TSRC CORPORATION
    Inventors: Chih-Wei Hsu, Man-Yin Lo, Yin-Chieh Chen
  • Publication number: 20190023884
    Abstract: A composition for preparing a foam, a foam, and a shoe employing the foam are provided. The composition for preparing a foam includes 3-30 parts by weight of a first polymer and at least one of a second polymer and a third polymer. The first polymer is cyclic olefin polymer (COP), cyclic olefin copolymer (COC), metallocene based cyclic olefin copolymer (mCOC), fully hydrogenated conjugated diene-vinyl aromatic copolymer, or a combination thereof. The total weight of the second polymer and the third polymer is 70-97 parts by weight. The second polymer is polyolefin, olefin copolymer, or a combination thereof. The third polymer is conjugated diene-vinyl aromatic copolymer, partially hydrogenated conjugated diene-vinyl aromatic copolymer, or a combination thereof. The total weight of the first polymer and at least one of the second polymer and the third polymer is 100 parts by weight.
    Type: Application
    Filed: July 20, 2018
    Publication date: January 24, 2019
    Applicant: TSRC CORPORATION
    Inventors: Hsi-Hsin SHIH, Hsuan-Tsung LIN, Ying-Pin TU, Han-Ming TSAI
  • Patent number: 10131733
    Abstract: A catalyst composition, a method for hydrogenating styrenic block copolymer employing the same, and a hydrogenated polymer from the method are provided. The method for hydrogenating styrenic block copolymer includes subjecting a hydrogenation process to a styrenic block copolymer in the presence of a catalyst composition. In particular, the catalyst composition includes an oxide carrier, and a catalyst disposed on the oxide carrier, wherein the catalyst includes a platinum-and-rhenium containing phosphorus compound.
    Type: Grant
    Filed: November 28, 2013
    Date of Patent: November 20, 2018
    Assignee: TSRC CORPORATION
    Inventors: Chih-Wei Hsu, Man-Yin Lo, Yin-Chieh Chen
  • Patent number: 9963585
    Abstract: The present invention provides polymer compositions containing a block copolymer having a formula A-B-A, wherein the block A is a vinyl aromatic block and the block B is a hydrogenated conjugated diene block, and compounds made from the polymer compositions. The block copolymer exhibits excellent flow characteristics, which allow it to be molded or extruded to isotropic articles. The present invention also provides films and molded articles therefrom.
    Type: Grant
    Filed: July 24, 2015
    Date of Patent: May 8, 2018
    Assignee: TSRC Corporation
    Inventors: Dale Lee Handlin, Jr., Chun Yu Cheng
  • Patent number: 9561465
    Abstract: An ecosystem operated in a plant having a drying unit is provided. The ecosystem includes: a regenerative thermal oxidization unit for processing a waste gas to produce a hot gas; a first hot gas pipeline connected to the regenerative thermal oxidization unit and the drying unit, wherein the hot gas is transferred from the regenerative thermal oxidization unit to the drying unit via the first hot gas pipeline; a heat recovery unit disposed at the first hot gas pipeline to absorb heat from the first hot gas pipeline; an absorption refrigeration unit connected to a target to be cooled; and a hot liquid pipeline connected to the heat recovery unit and the absorption refrigeration unit, wherein the heat recovery unit transfers heat from the first hot gas pipeline to the absorption refrigeration unit via the hot liquid pipeline to actuate the absorption refrigeration unit to cool the target.
    Type: Grant
    Filed: November 29, 2013
    Date of Patent: February 7, 2017
    Assignee: TSRC Corporation
    Inventors: Jung Chang Lu, Cheng Hsien Lin, Sheng-Te Yang
  • Patent number: 9260578
    Abstract: A thermoplastic elastomer foaming material is provided. The thermoplastic elastomer foaming material includes a hydrogenated styrenic/conjugated diene copolymer in a range from 5 to 35 weight percent; at least one of an acetate copolymer and an acrylate copolymer in a range from 3 to 30 weight percent; an amorphous polyolefin in a range from 20 to 60 weight percent; and a plasticizer in a range from 10 to 40 weight percent.
    Type: Grant
    Filed: December 21, 2009
    Date of Patent: February 16, 2016
    Assignee: TSRC CORPORATION
    Inventors: Jan-Rong Su, Cheng-Te Lee, Ching-En Tsai
  • Patent number: 9260537
    Abstract: A method of forming modified conjugated diene rubber includes (a) reacting an alkali metal ion-containing conjugated diene rubber with a first modifier having a structural formula (I), wherein R1, R2, R3 are each independently selected from the group consisting of C1-C12 of alkyl and C2-C12 of alkenyl groups and C6-C12 of aromatic group, and R4 is selected from the group consisting of C1-C12 of alkyl, C2-C12 of alkenyl, C1-C12 of alkoxy groups and C6-C12 of aromatic group; and (b) adding a second modifier having a structural formula (II) after (a), HO—R5—Y??(II) wherein R5 is selected from the group consisting of C1-C12 of alkylene, C2-C12 of alkenylene, C3-C12 of alicyclic groups and C6-C12 of aromatic group, and Y is selected from the group consisting of oxygen-containing C1-C12 group and nitrogen-containing, C1-C12 group, wherein Y has the oxygen atom or the nitrogen atom directly connected to a carbon atom of R5.
    Type: Grant
    Filed: October 18, 2012
    Date of Patent: February 16, 2016
    Assignee: TSRC Corporation
    Inventors: Chi-Chen Hsieh, Fu Lin, Chi-Ta Tsai, Hui-Kai Lin, Bo-Han Lin
  • Patent number: 9260593
    Abstract: A modified conjugated diene rubber is disclosed. A method for producing the modified conjugated diene rubber includes providing an alkali metal ion-containing conjugated diene rubber; and reacting the alkali metal ion-containing conjugated diene rubber with an alkoxysilane to generate the modified conjugated diene rubber, the alkoxysilane being of the structural formula: wherein R1, R2, R3 are each independently selected from a group consisting of oxygen-containing C2-C12 group and nitrogen-containing C3-C12 group, the oxygen-containing C2-C12 group has a carbon atom directly connected to oxygen atom of the alkoxysilane, the nitrogen-containing C1-C12 group has a nitrogen atom directly connected to oxygen atom of the alkoxysilane, and R4 is selected from a group consisting of C3-C12 of alkyl, alkenyl, aryl, and alkoxy.
    Type: Grant
    Filed: September 7, 2012
    Date of Patent: February 16, 2016
    Assignee: TSRC Corporation
    Inventors: Chi-Chen Hsieh, Fu Lin, Chi-Ta Tsai, Hui-Kai Lin, Bo-Han Lin
  • Patent number: 9181356
    Abstract: A hydrogenation catalyst composition for hydrogenating a polymer of conjugated diene is provided. The polymer of conjugated diene is a homopolymer of conjugated diene or a copolymer of conjugated diene and vinyl aromatics. The hydrogenation catalyst composition includes: (a) a titanium compound, (b) a compound of formula (II), where R5 is C1˜C12 alkyl, alkenyl, amine, ether, ketone or ester groups, R3 and R6 are C1˜C12 alkyl or alkenyl groups, R4 and R7 are C1˜C12 alkyl, alkenyl, amine, ether, ketone or ester groups, n and m are integrals, 1?n?3, 1?m?3, and (c) alkyl aluminum.
    Type: Grant
    Filed: May 18, 2010
    Date of Patent: November 10, 2015
    Assignee: TSRC CORPORATION
    Inventors: Chi-Chen Hsieh, Chih-Kuang Tsai, Yen-Hsian Li, Ming-Cheng Chiu
  • Patent number: 9051396
    Abstract: The present invention discloses a method for partially hydrogenating polymer. The method comprises providing a polymer having at least one vinyl aromatic block; and hydrogenating the polymer in presence of a heterogeneous catalyst on a support selected from the group consisting of BaSO4, Al2O3, TiO2, ZrO2, active carbon and any combination thereof to obtain a hydrogenated polymer. The hydrogenated polymer comprises at least one hydrogenated vinyl aromatic block having a carbon ring linking with a backbone of the hydrogenated polymer, wherein the average weight percent of the hydrogenated vinyl aromatic block(s) having only one and two double bonds on the carbon ring is between 1-30 wt % based on the total weight of the hydrogenated polymer.
    Type: Grant
    Filed: August 27, 2010
    Date of Patent: June 9, 2015
    Assignee: TSRC Corporation
    Inventors: Hung Chieh Hou, Man-Yin Lo