Patents Assigned to Tulalip
  • Publication number: 20020015923
    Abstract: The invention provides a multilayer silver halide color photographic element comprising a support having coated thereon at least two red-sensitive silver halide emulsion layers having different sensitivity to red light, characterized in that the most sensitive of said red-sensitive silver halide emulsion layers comprises a core-shell silver bromoiodide tabular emulsion having a pure bromide core, a total silver iodide content lower than 10% and an aspect ratio higher than 4.
    Type: Application
    Filed: May 21, 2001
    Publication date: February 7, 2002
    Applicant: Tulalip
    Inventors: Giuseppe Rocca, Antonio Poggi, Simona Fava
  • Patent number: 6235461
    Abstract: The present invention relates to a process for manufacturing a silver halide photographic element comprising the step of adding to a silver halide emulsion (1) an aryl compound having at least two hydroxyl groups and at least one additional substituent represented by a sulfonic group, an alkali metal sulfonate group, a hydroxyl group, a carboxy group or a hydroxymethyl group, and (2) a polyhydroxyalkyl derivative selected from the group consisting of non-hydrogenated polysaccharides having an average molecular weight higher than 10,000 and hydrogenated polysaccharides having an average molecular weight equal to or lower than 10,000. The use of such a combination to increase the speed to Dmin ratio of a silver halide photographic element and a silver halide element comprising such a combination is also claimed.
    Type: Grant
    Filed: June 7, 1999
    Date of Patent: May 22, 2001
    Assignee: Tulalip Consultoria Comercial Sociedade Unipessoal S.A.
    Inventors: Alain Dominique M. Sismondi, Marco Serafini
  • Patent number: 6214530
    Abstract: A base film including a substrate, an adhesion layer, a conductive layer, and a magnetic layer is provided. The adhesion layer preferably includes a sulfonated polyester/vinyl addition polymer, wherein the adhesion layer is disposed between the substrate and the conductive layer and improves adhesion between these layers, even under wet conditions. An adhesion layer is particularly useful in photographic elements and is at least located on a surface of the substrate that is opposite a silver halide emulsion layer, although emulsion receptivity can be enhanced by including an adhesion layer on the emulsion-side of the substrate.
    Type: Grant
    Filed: June 30, 1999
    Date of Patent: April 10, 2001
    Assignee: Tulalip Consultoria Comercial Sociedade Unidessoal S.A.
    Inventors: Eric D. Morrison, Paola Puppo
  • Patent number: 6045985
    Abstract: Photographic elements are disclosed having on a support a silver halide emulsion layer sensitive to radiation other than blue light in addition to its intrinsic sensitivity to blue region, and a yellow filter layer between the silver halide emulsion layers and the source of exposure, the yellow filter layer containing a yellow filter dye represented by the structural formula: ##STR1## wherein: R is hydrogen, alkyl group or aryl group;R.sub.1 is aryl group or heterocyclic group;X is O or N--R.sub.2 where R.sub.2 is hydrogen or alkyl group;Y is N--R.sub.3 where R.sub.3 is hydrogen or alkyl group;n is 0 or 1;Z is hydrogen, alkyl group or aryl group;W is hydrogen, or W and Z, taken together, represent the atoms necessary to form an aryl group.
    Type: Grant
    Filed: November 23, 1998
    Date of Patent: April 4, 2000
    Assignee: Tulalip Consultoria Comercial Sociedade Unipessoal S.A.
    Inventors: Piero Cavalleri, Sergio Massirio
  • Patent number: 6045986
    Abstract: The present invention provides a method of forming a dispersion of solid particles of a dye in a gelatin medium which includes the steps of milling the solid dye in the present of a glycerophospholipid dispersant in an aqueous medium and diluting the resulting dispersion with an aqueous solution containing a gelatin. In addition, a photographic element is provided comprising a support having coated thereon at least one silver halide emulsion layer and at least one additional gelatin layer that contains a dispersion of solid particles of a dye and a glycerophospholipid dispersant.
    Type: Grant
    Filed: May 18, 1998
    Date of Patent: April 4, 2000
    Assignee: Tulalip Consultoria Commerial Sociedade Unipessoal S.A.
    Inventors: Philip I. Mayo, Valerie Millar, Mark P. Kirk
  • Patent number: 6043011
    Abstract: A multilayer silver halide color photographic element comprises a support having coated thereon a silver antihalation layer, an interlayer, at least two red-sensitive silver halide emulsion layers, at least two green-sensitive silver halide emulsion layers a yellow filter layer, and at least two blue-sensitive silver halide emulsion layers, wherein a silver halide emulsion layer or a nonsensitive layer adjacent thereto comprises a bleach accelerator releasing coupler of formulaA-(TIME).sub.n -S-X-Rwherein A represents a coupler residue releasing from (TIME).sub.n -S-X-R upon reaction with the oxidation product of a color developing agent; TIME represents a timing group releasing S-X-R with delay under developing conditions; n represents 0 or 1; X represents a divalent linking groups consisting of an alkylene group containing 1 to 8 carbon atoms; and R represents a group selected in the group consisting of a), b) and c): ##STR1## wherein R.sub.
    Type: Grant
    Filed: May 11, 1998
    Date of Patent: March 28, 2000
    Assignee: Tulalip Consultoria Comercial Sociedade Unipessaol S.A.
    Inventors: Isabella Cogliolo, Paolo Beretta, Ivano Delprato, Sergio Massirio
  • Patent number: 6020115
    Abstract: Multilayer color photographic element having on a support base blue-, green- and red-sensitive silver halide emulsion layers respectively associated with non-diffusing yellow, magenta and cyan dye-forming couplers, wherein (a) the green-sensitive silver halide emulsion layer comprises three green-sensitive silver halide emulsion layers, respectively uppermost, intermediate and lowermost, sensitive to the same spectral region of visible light, in which the sensitivity of the three green-sensitive silver halide emulsion layers decreases in order from the uppermost silver halide emulsion layer to the lowermost silver halide emulsion layer, (b) each of the three green-sensitive silver halide emulsion layers contains an 1-phenyl-3-anilino-4-phenylthio-5-pyrazolone magenta dye-forming coupler, (c) the weight ratio of the coupler to silver halide (expressed as silver) in the highest sensitivity uppermost green-sensitive silver halide emulsion layer is higher than the weight ratio of the coupler to silver halide (exp
    Type: Grant
    Filed: June 23, 1998
    Date of Patent: February 1, 2000
    Assignee: Tulalip Consultoria Comercial Sociedade Unipessoal
    Inventors: Ferdinando Orengo, Luisa Tavella, Antonio Poggi