Patents Assigned to Ulano Corporation
  • Patent number: 5445916
    Abstract: Photopolymers based on polyvinyl alcohol derivatives of 8-hydroxy quinoline compositions having a high degree of photosensitivity, a marked degree of water solubility, and the ability to photodimerize when exposed to actinic radiation.
    Type: Grant
    Filed: April 5, 1993
    Date of Patent: August 29, 1995
    Assignee: Ulano Corporation
    Inventor: John Curtis
  • Patent number: 5360864
    Abstract: A process for preparing a compound having the structure ##STR1## which comprises heating under acidic conditions a polyvinyl alcohol and a compound of the structure ##STR2## is a polyvinyl acetal, n is an integer from 1 to 6,R is hydrogen or alkyl,m is an integer from 1 to 6,X is an anion, ##STR3## is a divalent radical having the structure ##STR4## Y is a monovalent radical having the structure ##STR5## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are hydrogen, alkyl, alkenyl, alkoxy, aralkyl, substituted alkyl, substituted alkoxy, carboxy, carboxy ester, amino, substituted amino, amido, substituted amido, cyano, hydroxy, nitro, isocyanato, sulphonyl halide, sulphonic acid and halide, and may be the same or different, or R.sub.1 taken together with R.sub.2 is methylene-dioxy, and A is a formyl or acetal group.
    Type: Grant
    Filed: April 8, 1993
    Date of Patent: November 1, 1994
    Assignee: Ulano Corporation
    Inventor: John Curtis
  • Patent number: 5358999
    Abstract: Polyvinyl alcohol is modified by reaction with a stilbazol quaternary salt acetal to produce a water soluble polymer capable of photodimerizing on exposure to active radiation to yield water-soluble photoresist materials.
    Type: Grant
    Filed: April 5, 1993
    Date of Patent: October 25, 1994
    Assignee: Ulano Corporation
    Inventor: John Curtis
  • Patent number: 5330877
    Abstract: Polyvinyl alcohol is modified by reaction with a stilbazol quaternary salt acetal to produce a water soluble polymer capable of photodimercezing on exposure to active radiation to yield water-soluble photoresist materials.
    Type: Grant
    Filed: May 29, 1992
    Date of Patent: July 19, 1994
    Assignee: Ulano Corporation
    Inventor: John Curtis
  • Patent number: 5326669
    Abstract: A photosensitive polymer composition comprising a compound of the structure ##STR1## wherein ##STR2## is a polyvinyl acetal, n is an integer from 1 to 6,R is hydrogen or alkyl,m is an integer from 1 to 6,X is an anion, ##STR3## is a divalent radical having the structure ##STR4## Y is a monovalent radical having the structure ##STR5## whereis a 5 or 6 membered heterocyclic ring in which Z is nitrogen, substituted nitrogen, oxygen or sulfur, and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are hydrogen, alkyl, alkenyl, alkoxy, aralkyl, substituted alkyl, substituted alkoxy, carboxy, carboxy ester, amino, substituted amino, amido, substituted amid, cyano, hydroxy, nitro, isocyanato, sulphonyl halide, sulphonic acid as halide, and may be the same or different or R.sub.1 taken together with R.sub.2 is methylenedioxy.
    Type: Grant
    Filed: May 4, 1992
    Date of Patent: July 5, 1994
    Assignee: Ulano Corporation
    Inventor: John Curtis
  • Patent number: 4847336
    Abstract: The transetherification reaction between hydroxyethyl acrylate and hexamethoxymethyl-melamine to produce oligomeric acryloyloxyethoxymethyl-melamines, which can be polymerized to form useful films and castings, can be increased in rate to produce the oligomer having less impurities and other undesirable properties by running the reaction in a hydrocarbon solvent, such as hexane, in the presence of iodine.
    Type: Grant
    Filed: April 28, 1988
    Date of Patent: July 11, 1989
    Assignee: Ulano Corporation
    Inventor: Robert F. Gerhardt
  • Patent number: 4655841
    Abstract: A stable hardener composition for films of poly (vinyl alcohol) or poly (vinyl acetate) which preferably comprises an alkanol solution containing about 5 to 80% by weight of an aliphatic dialdehyde-bis (di-lower alkyl acetal), from 0 to about 1% by weight of water, and from about one to 30% by weight of the amount of said acetal of a strong Bronsted or Lewis acid, said alkanol being a primary alcohol containing 1 to 6 carbon atoms. The solution may also contain soluble thickening agents and dyes.
    Type: Grant
    Filed: April 9, 1985
    Date of Patent: April 7, 1987
    Assignee: Ulano Corporation
    Inventor: Robert F. Gerhardt
  • Patent number: 4602097
    Abstract: Photoinitiators of the formulaG--O--(CH.sub.2 CH.sub.2 O).sub.n --CH.sub.2 --CH.sub.2 --O--Qwherein G is a photoinitiator moiety, R is hydrogen or lower alkyl, n has a value of at least 10, and Q is G or a lower alkyl are soluble in water and common organic solvents and are useful in polymerization systems employed in coatings used in screen printing.
    Type: Grant
    Filed: June 11, 1984
    Date of Patent: July 22, 1986
    Assignee: Ulano Corporation
    Inventor: John R. Curtis