Patents Assigned to Umicore Shokubai Japan Co., Ltd.
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Patent number: 9429055Abstract: Provided is a method for extending a temperature range enabling combustion of high concentration hydrocarbon, or for rapidly supplying high temperature gas to a later stage catalyst. Provided is a method for purification of exhaust gas from an internal-combustion engine comprised by: providing a temperature-raising catalyst for exhaust gas from an internal-combustion engine in an exhaust gas passage of the internal-combustion engine, along flow of said exhaust gas, at the upstream side of a purification catalyst for said exhaust gas; and introducing hydrocarbon in an amount of 1,000 to 40,000 ppm, as converted to methane, from the upstream side of the temperature-raising catalyst, wherein said temperature-raising catalyst has catalytically active components supported onto a refractory three-dimensional structure, wherein concentration of said components has a gradient such that said concentration gradually becomes lower from the inflow side toward the outflow side of said exhaust gas.Type: GrantFiled: July 13, 2007Date of Patent: August 30, 2016Assignees: UMICORE SHOKUBAI USA INC., UMICORE SHOKUBAI JAPAN CO., LTD.Inventor: Masanori Ikeda
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Patent number: 9421528Abstract: A catalyst that is not only capable of efficiently treating CO even at a low exhaust gas temperature, but also capable of exerting favorable CO purification efficiency in a low-temperature exhaust gas even in a case of being exposed for a long time to an engine exhaust gas that is a high temperature and contains HC, CO, NOx, water vapor and the like; and an exhaust gas treatment technique are described. The catalyst for purifying exhaust gas contains: a noble metal; an oxide containing as a base material A at least two kinds of elements selected from the group consisting of aluminum, zirconium and titanium; and an oxide containing as a base material B at least one kind of element selected from the group consisting of silicon, cerium, praseodymium and lanthanum; in which the base material A and the base material B satisfy a specific formula.Type: GrantFiled: February 24, 2014Date of Patent: August 23, 2016Assignee: UMICORE SHOKUBAI JAPAN CO., LTD.Inventors: Yosuke Goto, Naohiro Kato, Yuta Akasaka, Shota Kawashima
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Patent number: 9404406Abstract: A catalyst for use in a process for purifying exhaust gas from a gasoline engine of the fuel-direct-injection type that varies, in response to changes in the air-fuel ratio, between a first exhaust-gas state featured by an air-fuel ratio in the vicinity of the stoichiometrical air-fuel ratio, and a second exhaust-gas state that forms a more oxidizing, low-temperature atmosphere and that is featured by an air-fuel ratio greater than the stoichiometrical air-fuel ratio, the catalyst being obtained by causing a noble metal and a rare-earth oxide and/or a transition metal to be carried by or to be mixed with a fire-resistant inorganic oxide.Type: GrantFiled: May 1, 2013Date of Patent: August 2, 2016Assignees: UMICORE SHOKUBAI JAPAN CO., LTD., UMICORE SHOKUBAI USA INC.Inventors: Masao Hori, Akihisa Okumura, Makoto Horiuchi
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Publication number: 20160184803Abstract: An exhaust gas purification method by which carbon monoxide (CO), hydrocarbon (HC), and nitrogen oxide (NOx), particularly NOx, which are hazardous components contained in an exhaust gas can be removed efficiently. The disclosure relates to a catalyst for exhaust gas purification including: a three-dimensional structure; and a catalyst component layer composed of one or more constituting layers on the three-dimensional structure, wherein the catalyst component layer contains (a) a noble metal-unsupported alumina having mesopores, (b) NOx storage material-supported cerium, (c) a refractory inorganic oxide, and (d) a noble metal, and the constituting layer of the uppermost surface among the one or more constituting layers contains (a) the noble metal-unsupported alumina and (b) the NOx storage material-supported cerium, a method for producing the same, and an exhaust gas purification method using the catalyst.Type: ApplicationFiled: July 8, 2014Publication date: June 30, 2016Applicant: UMICORE SHOKUBAI JAPAN CO., LTD.Inventors: Takahiro UMENO, Masaya HANZAWA, Yoshiyuki HAYASHI
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Publication number: 20160129430Abstract: The purpose of the present invention is to provide an oxidation catalyst for exhaust gas purification having high durability and a method for producing the catalyst. The purpose is achieved by an oxidation catalyst for exhaust gas purification containing a refractory inorganic oxide, and a catalyst component and a metal component, which are supported on the refractory inorganic oxide, wherein the catalyst component is platinum, or platinum and palladium, and the metal component is one or more selected from the group consisting of magnesium, calcium, strontium and barium.Type: ApplicationFiled: December 29, 2015Publication date: May 12, 2016Applicants: UMICORE SHOKUBAI JAPAN CO., LTD., UMICORE SHOKUBAI USA INC.Inventors: Naohiro KATO, Yosuke GOTO, Yuta AKASAKA
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Patent number: 9254480Abstract: The purpose of the present invention is to provide an oxidation catalyst for exhaust gas purification having high durability and a method for producing the catalyst. The purpose is achieved by an oxidation catalyst for exhaust gas purification containing a refractory inorganic oxide, and a catalyst component and a metal component, which are supported on the refractory inorganic oxide, wherein the catalyst component is platinum, or platinum and palladium, and the metal component is one or more selected from the group consisting of magnesium, calcium, strontium and barium.Type: GrantFiled: March 21, 2012Date of Patent: February 9, 2016Assignees: Umicore Shokubai Japan Co., Ltd., Umicore Shokubai USA Inc.Inventors: Naohiro Kato, Yosuke Goto, Yuta Akasaka
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Publication number: 20160001275Abstract: A catalyst that is not only capable of efficiently treating CO even at a low exhaust gas temperature, but also capable of exerting favorable CO purification efficiency in a low-temperature exhaust gas even in a case of being exposed for a long time to an engine exhaust gas that is a high temperature and contains HC, CO, NOx, water vapor and the like; and an exhaust gas treatment technique are described. The catalyst for purifying exhaust gas contains: a noble metal; an oxide containing as a base material A at least two kinds of elements selected from the group consisting of aluminum, zirconium and titanium; and an oxide containing as a base material B at least one kind of element selected from the group consisting of silicon, cerium, praseodymium and lanthanum; in which the base material A and the base material B satisfy a specific formula.Type: ApplicationFiled: February 24, 2014Publication date: January 7, 2016Applicant: UMICORE SHOKUBAI JAPAN CO., LTD.Inventors: Yosuke GOTO, Naohiro KATO, Yuta AKASAKA, Shota KAWASHIMA
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Publication number: 20150375205Abstract: The present invention is to provide a NOx storage reduction catalyst for purifying exhaust gas capable of efficiently removing carbon monoxide (CO), a hydrocarbon (HC), and a nitrogen oxide (NOx), in particular NOx, which are harmful components contained in exhaust gas. The NOx storage reduction catalyst for purifying exhaust gas of the present invention is characterized by being obtained by using a complex oxide of strontium and cerium as a catalytic active component, in which the complex oxide of strontium and cerium adsorbs 1.0 mL or less of oxygen per gram in a 400° C. atmosphere, and sinters a precursor at 300° C. or more.Type: ApplicationFiled: February 7, 2014Publication date: December 31, 2015Applicant: UMICORE SHOKUBAI JAPAN CO., LTD.Inventors: Takahiro UMENO, Masaya HANZAWA, Yoshiyuki HAYASHI
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Publication number: 20150367328Abstract: As a way to suppress deterioration of catalytic performance in an exhaust gas purification catalyst even after being exposed to an exhaust gas containing a phosphorus compound, an exhaust gas purification catalyst is provided. The catalyst purifies an exhaust gas containing a phosphorus compound, and the catalyst includes a catalyst layer containing rhodium (Rh), palladium (Pd), and either a ceria-zirconia-lanthana complex oxide or a ceria-zirconia-lanthana-yttria complex oxide as catalyst active components. Further, an average value of distances between Rh particles and the nearest Pd particles of the Rh and the Pd is within 4000 nm, a weight ratio of the Pd to the Rh is from 0.2 to 4.9, and a content rate of yttria in the ceria-zirconia-lanthana-yttria complex oxide is 19% by weight or less.Type: ApplicationFiled: January 31, 2014Publication date: December 24, 2015Applicant: UMICORE SHOKUBAI JAPAN CO., LTD.Inventors: Masanori IKEDA, Kazuyoshi KOMATA, Shigekazu MINAMI, Yuji OGINO, Hideki GOTO
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Patent number: 8938953Abstract: A method of purifying an exhaust gas, includes: disposing a NOx trapping catalyst in an exhaust pipe of an internal combustion engine, the NOx trapping catalyst including: a metal substrate including cells, a corner portion of each of cells having an acute angle; and a catalyst layer supported in the metal substrate and including a noble metal, a heat-resistant inorganic oxide and a NOx trapping material, the catalyst layer having pores formed by addition of a pore formation promoting material, and the NOx trapping catalyst: adsorbing NOx in the exhaust gas when an exhaust air-fuel ratio is in a lean state; and desorbing and reducing the adsorbed NOx when the exhaust air-fuel ratio is in a stoichiometric state or a rich state; and removing the NOx by the exhaust air-fuel ratio being shifted between the lean state and the rich state.Type: GrantFiled: October 28, 2009Date of Patent: January 27, 2015Assignees: Mitsubishi Jidosha Kogyo Kabushiki Kaisha, ICT Co., Ltd., Umicore Shokubai Japan Co., Ltd.Inventors: Kinichi Iwachido, Ken Tanabe, Takayuki Onodera, Masanori Ide, Hiroaki Ohhara, Mariko Ono, Akihisa Okumura, Masao Hori
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Patent number: 8808653Abstract: PROBLEM The present invention is directed to provide a catalyst for purifying exhaust gas capable of maintaining a superior catalytic performance even when the catalyst is exposed to an exhaust gas at a high temperature of 800° C. or higher. SOLUTION The catalyst for purifying exhaust gas of the present invention comprises a catalytically active component containing a noble metal and a promoter containing an oxygen storage material both being supported on a carrier. The oxygen storage material comprises cerium, zirconium, and iron, and content of iron in the oxygen storage material is 0.01% by mass or more and less than 0.70% by mass (Fe2O3 conversion) relative to the total mass of the oxygen storage material. And the oxygen storage material is (a) a complex oxide or a solid solution of iron and a metal comprising cerium and zirconium; or (b) an iron is supported on a complex oxide or a solid solution of a metal comprising cerium and zirconium.Type: GrantFiled: March 4, 2010Date of Patent: August 19, 2014Assignees: Umicore Shokubai Japan Co., Ltd., Umicore Shokubai USA Inc.Inventors: Kosuke Mikita, Takahiro Ikegami, Masanori Ikeda, Hideki Goto
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Patent number: 8771624Abstract: An Object of the patent is to remove highly reducing hydrocarbon exhausted during acceleration period, and to remove efficiently hydrocarbon even after contacting with highly reducing hydrocarbon. By using a catalyst having a higher proportion of palladium having surface charge of 2-valence or 4-valence supported than that of 0-valence by supporting palladium together with magnesium oxide, hydrocarbon exhausted from an internal combustion engine especially during acceleration period can be efficiently removed.Type: GrantFiled: March 13, 2009Date of Patent: July 8, 2014Assignees: Umicore Shokubai Japan Co., Ltd, Umicore Shokubai USA Inc.Inventors: Masanori Ikeda, Hideki Goto, Kosuke Mikita
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Patent number: 8722001Abstract: A catalyst for the purification of exhaust gas that can be used to highly efficiently treat an exhaust gas which has moisture and fluctuates between an oxidizing atmosphere and a reducing atmosphere even after the catalyst is exposed to a high temperature is provided. The present invention relates to a catalyst for the purification of exhaust gas having a catalyst layer of catalyst components comprising a noble metal, magnesium oxide, and a refractory inorganic oxide formed on a three-dimensional structure, wherein the catalyst layer has two peaks originated from the magnesium oxide in a pore distribution obtained by mercury intrusion technique.Type: GrantFiled: October 16, 2009Date of Patent: May 13, 2014Assignees: Umicore Shokubai Japan Co., Ltd., Umicore Shokubai USA, Inc.Inventors: Mariko Ono, Akihisa Okumura
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Publication number: 20140072493Abstract: The purpose of the present invention is to provide a catalyst for exhaust gas purification, which is capable of effectively processing an exhaust gas, particularly carbon monoxide (CO) and hydrocarbon (HC) in the exhaust gas at a low temperature, and a method for producing the catalyst for exhaust gas purification. The purpose is achieved by a catalyst for exhaust gas purification, which is obtained by having a carrier that contains Al2O3 and one or more metal oxides selected from the group consisting of zirconium oxide (ZrO2), cerium oxide (CeO2), yttrium oxide (Y2O3), neodymium oxide (Nd2O3), silicon oxide (SiO2) and titanium oxide (TiO2) support one or more catalyst components selected from the group consisting of gold (Au), silver (Ag), platinum (Pt), palladium (Pd), rhodium (Rh), iridium (Ir), ruthenium (Ru) and osmium (Os). The metal oxides have particle diameters of less than 10 nm.Type: ApplicationFiled: February 29, 2012Publication date: March 13, 2014Applicants: UMICORE SHOKUBAI USA INC., UMICORE SHOKUBAI JAPAN CO., LTD.Inventors: Naohiro Kato, Yuta Akasaka, Yuji Ogino, Yosuke Goto
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Publication number: 20140065043Abstract: The purpose of the present invention is to provide an oxidation catalyst for exhaust gas purification having high durability and a method for producing the catalyst. The purpose is achieved by an oxidation catalyst for exhaust gas purification containing a refractory inorganic oxide, and a catalyst component and a metal component, which are supported on the refractory inorganic oxide, wherein the catalyst component is platinum, or platinum and palladium, and the metal component is one or more selected from the group consisting of magnesium, calcium, strontium and barium.Type: ApplicationFiled: March 21, 2012Publication date: March 6, 2014Applicants: UMICORE SHOKUBAI USA INC., UMICORE SHOKUBAI JAPAN CO., LTDInventors: Naohiro Kato, Yosuke Goto, Yuta Akasaka
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Publication number: 20140037524Abstract: Provided is a catalyst for purifying an exhaust gas, the catalyst excelling in catalytic performance and oxygen storage capacity. The catalyst for purifying an exhaust gas is a catalyst for purifying an exhaust gas which includes a ceria-zirconia composite oxide having a pyrochlore structure and a ceria-zirconia composite oxide having a cubic crystal structure, wherein at least a part of the ceria-zirconia composite oxide is composited with the ceria-zirconia composite oxide.Type: ApplicationFiled: January 27, 2012Publication date: February 6, 2014Applicant: UMICORE SHOKUBAI JAPAN CO., LTD.Inventors: Kosuke Mikita, Masanori Ikeda, Shinji Sugihara, Hideki Goto, Takahiro Ikegami
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Publication number: 20130239555Abstract: A catalyst for use in a process for purifying exhaust gas from a gasoline engine of the fuel-direct-injection type that varies, in response to changes in the air-fuel ratio, between a first exhaust-gas state featured by an air-fuel ratio in the vicinity of the stoichiometrical air-fuel ratio, and a second exhaust-gas state that forms a more oxidizing, low-temperature atmosphere and that is featured by an air-fuel ratio greater than the stoichiometrical air-fuel ratio, the catalyst being obtained by causing a noble metal and a rare-earth oxide and/or a transition metal to be carried by or to be mixed with a fire-resistant inorganic oxide.Type: ApplicationFiled: May 1, 2013Publication date: September 19, 2013Applicants: Umicore Shokubai USA Inc., Umicore Shokubai Japan Co., Ltd.Inventors: Masao HORI, Akihisa OKUMURA, Makoto HORIUCHI
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Patent number: 8465711Abstract: An exhaust gas purification catalyst of the present invention contains at least a precious metal coated with lanthanum-containing alumina. In at least one embodiment, it is possible to provide: an exhaust gas purification catalyst which can (i) have an increase in heat resistance, and (ii) inhibit the precious metal from being mixed in alumina and therefore inhibit the precious metal from forming a solid solution in combination with alumina; and a method for efficiently purifying, by use of the catalyst, an exhaust gas emitted from an internal-combustion engine.Type: GrantFiled: August 27, 2009Date of Patent: June 18, 2013Assignees: Umicore Shokubai Japan Co., Ltd., Umicore Shokubai USA Inc.Inventors: Masanori Ikeda, Kosuke Mikita, Takahiro Ikegami, Yuji Ogino, Hideki Goto
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Patent number: 8418444Abstract: Temperature range enabling combustion of high concentration hydrocarbon is enlarged, or high temperature gas is rapidly supplied to a latter part catalyst. Provided is a method for purification of exhaust gas from an internal combustion engine, by using a catalyst for increasing temperature of exhaust gas from an internal combustion engine, wherein hydrocarbon from 1,000 to 40,000 ppm by volume, as converted to methane, to the exhaust gas, is introduced at the upstream side of the catalyst for increasing temperature, along flow of the exhaust gas inside a passage of exhaust gas from the internal combustion engine.Type: GrantFiled: March 23, 2007Date of Patent: April 16, 2013Assignees: Umicore Shokubai Japan Co., Ltd., Umicore Shokubai USA IncInventors: Masanori Ikeda, Naohiro Kato