Patents Assigned to Umicore
-
Patent number: 11772077Abstract: The present invention relates to the use of a material B containing palladium and platinum in a weight ratio of 2:3 to 10:1 for increasing the low-temperature storage of nitrogen oxides by means of a material A containing palladium and zeolite, wherein material A and material B are present on a carrier substrate of the length L, and wherein material A and material B are different from one another.Type: GrantFiled: January 8, 2020Date of Patent: October 3, 2023Assignee: UMICORE AG & CO. KGInventor: Anke Woerz
-
Patent number: 11777082Abstract: A negative electrode material for lithium ion secondary batteries, including composite material particles containing nanosilicon particles having a 50% particle diameter (Dn50) of 5 to 100 nm in a number-based cumulative particle size distribution of primary particles, graphite particles and an amorphous carbon material; the composite material particles containing the nanosilicon particles at a content of 30 to 60 mass % or less, and the amorphous carbon material at a content of 30 to 60 mass % or less; the composite material particles having a 90% particle diameter (DV90) in the volume-based cumulative particle size distribution of 10.0 to 40.0 ?m, a BET specific surface area of 1.0 to 5.0 m2/g, and an exothermic peak temperature in DTA measurement of 830° C. to 950° C. Also disclosed is a paste for negative electrodes, a negative electrode sheet, a lithium ion secondary battery and a method for manufacturing the negative electrode material.Type: GrantFiled: September 18, 2018Date of Patent: October 3, 2023Assignees: Showa Denko K.K., UmicoreInventors: Yasunari Otsuka, Nobuaki Ishii, Nicolas Marx, Stijn Put
-
Publication number: 20230295203Abstract: The invention concerns a process for preparing an essentially silicon (Si) free compounds of the general formula [M(O)(OR)y], wherein M = Mo, y = 3 or M = W, y = 3 or 4. Furthermore, it is directed towards compounds obtained by the aforementioned process and towards the use of such an obtained compound. Another objective of the herein described invention are essentially silicon free compounds of the general formula MOXy or [MOXy(solv)p], prepared using the aforementioned process, wherein M = Mo, y = 3 or M = W, y = 3 or 4, X = Cl or Br, solv = an oxidizing agent Z binding or coordinating to M via at least one donor atom, p = 1 or 2.Type: ApplicationFiled: April 1, 2020Publication date: September 21, 2023Applicant: UMICORE AG & CO. KGInventors: Nicholas RAU, Wolf SCHORN, Annika FREY, Angelino DOPPIU, Eileen WOERNER, Ralf KARCH
-
Publication number: 20230285899Abstract: The present invention relates to a particulate filter which comprises a wall-flow filter of length L and two different catalytically active coatings Y and Z, wherein the wall flow filter comprises channels E and A that extend in parallel between a first and a second end of the wall-flow filter and are separated by porous walls which form the surfaces OE and OA, respectively, and wherein the channels E are closed at the second end and the channels A are closed at the first end. The invention is characterized in that the coating Y is located in the channels E on the surfaces OE and the coating Z is located in the porous walls.Type: ApplicationFiled: March 2, 2023Publication date: September 14, 2023Applicant: UMICORE AG & CO. KGInventors: Jan SCHOENHABER, Naina DEIBEL, Martin ROESCH, Stephanie SPIESS, Joerg-Michael RICHTER, Susanne KUNERT
-
Publication number: 20230271164Abstract: A Ce—Zr composite oxide contains cerium and zirconium, wherein an uneven distribution ratio of cerium atoms is 1.80 or less. A method for producing a Ce—Zr composite oxide includes an acid treatment step of bringing at least one selected from the group consisting of sulfuric acid, nitric acid, and hydrochloric acid, in an amount of 4 to 28 parts by mass with respect to 100 parts by mass of the raw material composite oxide, into contact with the surface of a raw material composite oxide containing cerium and zirconium, and a calcination step of calcining the treated composite oxide obtained in the acid treatment step at 400 to 1200° C. for 5 to 300 minutes.Type: ApplicationFiled: April 19, 2021Publication date: August 31, 2023Applicant: UMICORE SHOKUBAI JAPAN CO., LTD.Inventor: Daishi FUJINO
-
Patent number: 11732631Abstract: Subject of the invention is an exhaust gas purification system for a gasoline engine, comprising in consecutive order the following devices: ? a first three-way-catalyst (TWC1), a gasoline particulate filter (GPF) and a second three-way-catalyst (TWC2), ? wherein the platinum-group metal concentration (PGM) of the TWC2 is greater than the PGM of the GPF, wherein the PGM is determined in g/ft3 of the volume of the device. Also disclosed are methods in which the system is used and uses of the system.Type: GrantFiled: October 17, 2019Date of Patent: August 22, 2023Assignee: UMICORE AG & CO. KGInventors: Jan Schoenhaber, Joerg-Michael Richter, Carolin Braun
-
Publication number: 20230226534Abstract: The invention relates to a wire made of platinum group metals for producing grid catalysts comprising platinum and rhodium. The invention is characterized in that the wire is made as a sheathed wire and consists of a core and one or more sheaths arranged one over the other outwards from the core in a radially symmetrical manner, and the rhodium concentration in the outermost sheath is lower than the rhodium concentration in the sheath or core arranged directly under the outermost sheath.Type: ApplicationFiled: April 22, 2021Publication date: July 20, 2023Applicant: UMICORE AG & CO. KGInventors: Dirk BORN, Artur WISER, Stefan ZEUNER
-
Patent number: 11702971Abstract: The present invention relates to a particulate filter which comprises a wall flow filter of length L and two different catalytically active coatings Y and Z, wherein the wall flow filter comprises channels E and A that extend in parallel between a first and a second end of the wall flow filter and are separated by porous walls which form the surfaces OE and OA, respectively, and wherein the channels E are closed at the second end and the channels A are closed at the first end. The invention is characterized in that the coating Y is located in the channels E on the surfaces OE and the coating Z is located in the channels A on the surfaces OA.Type: GrantFiled: December 14, 2018Date of Patent: July 18, 2023Assignee: UMICORE AG & CO. KGInventors: Jan Schoenhaber, Naina Deibel, Martin Roesch, Stephanie Spiess
-
Patent number: 11702437Abstract: The invention relates to a method for producing aqueous preparations of complexes of platinum group metals (PGM) Pt, Pd, Rh and Ir having the general formula [MA/MB/MC (L)a (H2O)b (O2?)c(OH?)d](OH—)e(H+)f, wherein MA=PtII or PdII, MB=PtIV, MC=Rh or Ir, L is a neutral monodentate or bidentate donor ligand, and a is an integer between 1 and 4 (or 2) and/or between 1 and 6 (or 3), b is an integer between 0 and 3 (or 5), c is an integer between 0 and 3 (or 4), d is an integer between 0 and 3 (or 5), e is an integer between 0 and 2 (or 3 or 4) and f is an integer between 0 and 4 (or 5). In the method according to the invention, the hydroxo complexes H2Pd(OH)4 (in the case of MA=PdII), H2Pt(OH)6 (in the case of MA=PtII and MB=PtIV) or H3MC(OH)6 (for MC=RhIII IrIII) are converted in the presence of the donor ligands, wherein at least one hydroxo group of the hydro complex is exchanged. Preferably, the reaction occurs at temperatures in the range of 40 to 110° C.Type: GrantFiled: July 6, 2022Date of Patent: July 18, 2023Assignee: Umicore AG & Co. KGInventors: Eileen Woerner, Ralf Karch, Andreas Rivas-Nass, Angelino Doppiu
-
Patent number: 11691133Abstract: Described are a catalyst capable of effectively oxidizing an exhaust gas, a method for preparing the catalyst, and a method for oxidizing an exhaust gas using the catalyst. The exhaust gas oxidation catalyst includes at least two layers, a lower catalyst layer and an upper catalyst layer, laminated on a three-dimensional structure, wherein the lower catalyst layer and the upper catalyst layer independently contain precious metal and alumina and/or zeolite, and at least a part of the upper catalyst layer contains pores derived from a pore connecting agent with a combustion decomposition temperature of 300° C. or more to less than 450° C.Type: GrantFiled: November 11, 2019Date of Patent: July 4, 2023Assignee: UMICORE SHOKUBAI JAPAN CO., LTD.Inventors: Tatsuya Kumon, Yosuke Goto, Franz Dornhaus
-
Patent number: 11695169Abstract: The present disclosure concerns the production of precursor compounds for lithium battery cathodes. Batteries or their scrap are smelted in reducing conditions, thereby forming an alloy suitable for further hydrometallurgical refining, and a slag. The alloy is leached in acidic conditions, producing a Ni- and Co-bearing solution, which is refined. The refining steps are greatly simplified as most elements susceptible to interfere with the refining steps concentrate in the slag. Metals such as Co, Ni and Mn are then precipitated from the solution, forming a suitable starting product for the synthesis of new battery precursor compounds.Type: GrantFiled: April 17, 2020Date of Patent: July 4, 2023Assignee: UMICOREInventors: Harald Oosterhof, Jean Scoyer, Lennart Scheunis, Bart Klaasen, Willem Callebaut
-
Patent number: 11688883Abstract: A lithium secondary cell having an operating voltage ?4.35V, comprising a cathode comprising a doped LiCoO2 active material, an anode comprising graphite, and an electrolyte comprising a carbonate-based solvent, a lithium salt and both a succinonitrile (SN) and a lithium bis(oxalato)borate (LiBOB) additive wherein during the discharge at 45° C. from a state of charge (SOC) of 100% at 4.5V to a SOC of 0 at 3V at a C/10 rate the difference of the SOC at 4.42V and 4.35V is at least 7% but less than 14%, and wherein the active material is doped by at least 0.5 mole % of either one or more of Mn, Mg and Ti.Type: GrantFiled: June 30, 2020Date of Patent: June 27, 2023Assignees: UMICORE, UMICORE KOREA, LTD.Inventors: Xin Xia, Maxime Blangero, Jing Zhang, Wenlong Yang, Jens Paulsen
-
Publication number: 20230192736Abstract: The invention relates to a one-pot method for preparing oxido (tetraalkoxido) tungsten compounds according to the general formula [W(O)(OR)4] (I), originating from WCl6, hexamethyldisiloxane, an alcohol ROH and an amine or NH3 gas. The invention further relates to the use of a compounds [W(O)(OR)4] (I) and to a substrate which has on one surface a tungsten layer or a layer containing tungsten which are suitable for producing photovoltaic elements, semiconductor elements or car exhaust catalytic converters. The method permits the preparation of defined products in a simple, cost-effective and reproducible manner in high purity and good to very good yields.Type: ApplicationFiled: April 1, 2020Publication date: June 22, 2023Applicant: UMICORE AG & CO. KGInventors: Nicholas RAU, Annika FREY, Ralf KARCH, Eileen WOERNER, Angelino DOPPIU
-
Patent number: 11679359Abstract: The present invention relates to a wall flow filter, to a method for the production and the use of the filter for reducing harmful exhaust gases of an internal combustion engine. Particle filters are commonly used for filtering exhaust gases from a combustion process. Also disclosed are novel filter substrates and their specific use in exhaust gas aftertreatment.Type: GrantFiled: January 2, 2020Date of Patent: June 20, 2023Assignee: UMICORE AG & CO. KGInventors: Astrid Mueller, Meike Antonia Gotthardt, Martin Foerster, Stephanie Spiess, Yannic Weigl, Carsten Herzog
-
Patent number: 11667536Abstract: The present invention relates to a method for the preparation of a molecular sieve of the CHA-type as well as catalytic applications thereof.Type: GrantFiled: August 23, 2019Date of Patent: June 6, 2023Assignee: Umicore AG & Co. KGInventors: Peter Nicolai Ravnborg Vennestrom, Nuria Martin Garcia, Manuel Moliner Marin, Avelino Corma Canos
-
Patent number: 11670769Abstract: A lithium cobalt-based oxide cathode active material powder comprising particles having a median particle size D50 of greater than or equal to 20 ?m, preferably 25 ?m, and less than or equal to 45 ?m, said particles having an averaged circularity of greater than or equal to 0.85 and less than or equal to 1.00, said particles having a general formula Li1+aCo1-x-y-zAlxM?yMezO2, wherein M? and Me comprise at least one element of the group consisting of: Ni, Mn, Nb, Ti, W, Zr, and Mg, with ?0.01?a?0.01, 0.002?x?0.050, 0?y?0.020 and 0?z?0.050, said lithium cobalt-based oxide particles having a R-3m structure and (018) diffraction peak asymmetry factor AD(018) of greater than or equal to 0.85 and less than or equal to 1.15, said diffraction peak asymmetry factor being obtained by a synchrotron XRD spectrum analysis with an emission wavelength ? value equal to 0.825 ?.Type: GrantFiled: July 17, 2020Date of Patent: June 6, 2023Assignees: UMICORE, UMICORE KOREA LTD.Inventors: KyeongSe Song, Maxime Blangero
-
Patent number: 11661638Abstract: The present invention lies in the field of pyrometallurgy and discloses a process and a slag suitable for the recovery of Ni and Co from Li-ion batteries or their waste. The slag composition is defined according to: 10%<MnO<40%; (CaO+1.5*Li2O)/Al2O3>0.3; CaO+0.8*MnO+0.8*Li2O<60%; (CaO+2*Li2O+0.4*MnO)/SiO2?2.0; Li2?1%; and, Al2O3+SiO2+CaO+Li2O+MnO+FeO+MgO>85%. This composition is particularly adapted to limit or avoid the corrosion of furnaces lined with magnesia-bearing refractory bricks.Type: GrantFiled: May 13, 2022Date of Patent: May 30, 2023Assignee: UMICOREInventors: Ryohei Yagi, Lennart Scheunis
-
Publication number: 20230158454Abstract: The present invention relates to a catalyst, which comprises * a carrier substrate with a first end a and a second end b, and length L, * a material zone A containing a platinum group metal on a support material with a load of 40 to 150 g/l, relative to the volume of the carrier substrate and * material zone B containing a platinum group metal on a support material with a load of 75 to 200 g/l, relative to the volume of the carrier substrate, wherein material zone B has a greater content of platinum group metal, relative to the volume of the carrier substrate and calculated in g/l, than material zone A, and wherein material zone B has a proportion of pores with a diameter of 0.5 to 50 µm of 20 to 30%.Type: ApplicationFiled: May 6, 2021Publication date: May 25, 2023Applicant: UMICORE AG & CO. KGInventor: Birgit FRIEDRICH
-
Patent number: 11649753Abstract: An exhaust gas purification system for a gasoline engine is described the system comprising in consecutive order the following devices: •a first three-way-catalyst (TWC1), a gasoline particulate filter (GPF) and a second three-way-catalyst (TWC2), •wherein the oxygen storage capacity (OSC) of the GPF is greater than the OSC of the TWC1, wherein the OSC is determined in mg/l of the volume of the device.Type: GrantFiled: October 17, 2019Date of Patent: May 16, 2023Assignee: UMICORE AG & CO. KGInventors: Jan Schoenhaber, Joerg-Michael Richter, Carolin Braun
-
Patent number: 11648535Abstract: The present invention relates to a three-way catalyst (TWC) for treatment of exhaust gases from internal combustion engines operated with a predominantly stoichiometric air/fuel ratio, so called spark ignited engines.Type: GrantFiled: December 8, 2021Date of Patent: May 16, 2023Assignee: UMICORE AG & CO. KGInventors: Masashi Nakashima, John G. Nunan, Ryan J. Andersen