Patents Assigned to Vanderbilt Chemicals, LLC
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Publication number: 20170240837Abstract: The present invention relates to a compound of the Formula I: and a lubricating composition containing and a method for preparing the same. In Formula I, R1-R5 and R6-R10 are independently selected from the group consisting of hydrogen, hydrocarbyl groups and hydrocarbyl groups containing heteroatoms, such that the total carbon atoms from Q1 and Q2 is from 6 to 166 carbon atoms, and molybdate anion (Y) is a binuclear sulfur-containing dianion selected from the group consisting of [Mo2S8O2]2?, [Mo2S9O]2?, and [Mo2S10]2.Type: ApplicationFiled: February 14, 2017Publication date: August 24, 2017Applicant: VANDERBILT CHEMICALS, LLCInventors: Brian M. CASEY, Vincent J. GATTO
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Publication number: 20170190999Abstract: A lubricant composition comprises as a lubricant base, an oil soluble polyalkylene glycol suitable for use as a lubricant in an industrial oil, grease or metal working fluid; and an additive comprising (1) alkylated phenyl-?-naphthylamine; and (2) 2,2,4-trialkyl-1,2-dihydroquinoline.Type: ApplicationFiled: March 21, 2017Publication date: July 6, 2017Applicant: VANDERBILT CHEMICALS, LLCInventors: Junbing YAO, Steven G. DONNELLY
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Patent number: 9677024Abstract: The present invention relates to an engine oil lubricant composition for use in internal combustion engines comprising one or more molybdenum containing compounds that deliver 1-1000 ppm molybdenum to the finished oil, one or more phosphorus containing compounds that deliver 25-650 ppm phosphorus to the finished oil, and one or more poly(meth)acrylate viscosity index improvers (VI improvers) that may or may not be functionalized, for improved fuel economy and turbocharger related deposits. In addition, the composition comprises an antioxidant system which is carefully balanced to provide improved fuel economy, comprising an aminic antioxidant, a phenolic antioxidant and an ashless dithiocarbamate. Additionally, the formulated oil may contain a dispersant poly(meth)acrylate, in addition to the PAMA VI improver, to reduce the amount of traditional succinimide dispersants.Type: GrantFiled: June 5, 2013Date of Patent: June 13, 2017Assignee: VANDERBILT CHEMICALS, LLCInventors: Carl K. Esche, Glenn A. Mazzamaro, Thorsten Bartels, David B. Gray
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Patent number: 9637704Abstract: A lubricant composition comprises as a lubricant base, an oil soluble polyalkylene glycol suitable for use as a lubricant in an industrial oil, grease or metal working fluid; and an additive comprising (1) alkylated phenyl-?-naphthylamine; and (2) 2,2,4-trialkyl-1,2-dihydroquinoline.Type: GrantFiled: February 4, 2015Date of Patent: May 2, 2017Assignee: VANDERBILT CHEMICALS, LLCInventors: Junbing Yao, Steven G. Donnelly
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Publication number: 20170081608Abstract: A low-phosphorus lubricating composition having less than 600 ppm phosphorus, comprising at least 85 weight % of a lubricating base blend, and an additive comprising the following, as weight % of the total composition: (1) an organomolybdenum component comprising: (a) an organomolybdenum complex, and (b) a molybdenum dithiocarbamate, the organomolybdenum component being present at an amount which provides about 400-800 ppm Mo; (2) (iso-octyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate), at about 0.25-1.5%; (3) a dithiocarbamate component comprising (a) methylene-bis-dialkyldithiocarbamate and (b) said molybdenum dithiocarbamate, at a total dithiocarbamate component of about 0.6-1.2%; and (4) an alkylated diphenyl amine, at about 0.5-1.5%.Type: ApplicationFiled: December 2, 2016Publication date: March 23, 2017Applicant: VANDERBILT CHEMICALS, LLCInventors: Glenn A. MAZZAMARO, Steven G. DONNELLY, Ronald J. HIZA
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Publication number: 20170044457Abstract: A lubricating composition for use in heavy duty diesel engines which is formulated to allow the use of organo-molybdenum compounds but which overcomes the issue of Cu and/or Pb corrosion and also maintains elastomer seal compatibility. The lubricant is characterized by having a composition comprising (A) an organo-molybdenum compound, (B) an alkylated diphenylamine derivative of triazole, (C) base oil, and optionally (D) one or more additives selected from the group including antioxidants, dispersants, detergents, anti-wear additives, extreme pressure additives, friction modifiers, rust inhibitors, corrosion inhibitors, seal swell agents, anti-foaming agents, pour point depressants and viscosity index modifiers.Type: ApplicationFiled: August 2, 2016Publication date: February 16, 2017Applicant: VANDERBILT CHEMICALS, LLCInventors: Mihir K. PATEL, Vincent J. GATTO
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Publication number: 20170044455Abstract: An antioxidant composition which comprises: (a) methylenebis(di-n-butyldithiocarbamate); and (b) an alkylated diphenylamine derivative of triazole wherein the alkyl group on at least one of the phenyl groups is C8 or higher. Lubricating compositions containing the antioxidant composition are also contemplated.Type: ApplicationFiled: August 2, 2016Publication date: February 16, 2017Applicant: VANDERBILT CHEMICALS, LLCInventor: Vincent J. GATTO
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Publication number: 20170044456Abstract: A lubricating composition for use in heavy duty diesel engines which is formulated to allow the use of organomolybdenum compounds but which overcomes the issue of Cu and/or Pb corrosion. The lubricant is characterized by having a synergistic additive composition comprising (A) a sulfur-free organo-molybdenum compound, (B) a sulfur-containing organo-molybdenum compound and (C) a triazole derivative prepared by reacting 1,2,4-triazole, a formaldehyde source and an amine; (A), (B) and (C) being present in an amount sufficient to allow the lubricating composition to pass the High Temperature Corrosion Bench Test ASTM D 6594 with respect to Cu and/or Pb corrosion.Type: ApplicationFiled: August 2, 2016Publication date: February 16, 2017Applicant: VANDERBILT CHEMICALS, LLCInventors: Mihir K. PATEL, Vincent J. GATTO
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Publication number: 20170044113Abstract: Novel compounds are described, being alkylated diphenylamine derivatives of triazole, wherein the alkyl group on at least one of the phenyl groups is C8 or higher, in an amount ranging from 0.001 to 5.0% by weight of the lubricating composition. In particular, the derivatives may be 1-[di-(4-octylphenyl)aminomethyl]triazole; 1-[di-(4-nonylphenyl)aminomethyl]triazole; 1-[(4-octylphenyl)(4-butylphenyl)aminomethyl]triazole; and 1-[(4-octylphenyl)(phenyl)aminomethyl]triazole. A lubricating composition comprising the novel derivatives is also disclosed.Type: ApplicationFiled: August 2, 2016Publication date: February 16, 2017Applicant: VANDERBILT CHEMICALS, LLCInventors: Vincent J. GATTO, Frank CHENG, Shubhada DANTALE
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Patent number: 9550952Abstract: A method for reducing aqueous phase separation of an emulsion comprising ethanol-based fuel and a lubricating oil comprising molybdenum ester amide complex, comprising the step of adding to the lubricating oil a dispersant polyalkyl (meth) acrylate (DPMA) in an amount from about 0.01 to about 0.5% by weight of the lubricating oil, such that the weight ratio of molybdenum to DPMA is about 2.05 or less.Type: GrantFiled: September 9, 2014Date of Patent: January 24, 2017Assignee: VANDERBILT CHEMICALS, LLCInventors: Mihir K. Patel, Ronald J. Hiza
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Patent number: 9546339Abstract: 1-[di(4-octylphenyl)aminomethyl]tolutriazole is prepared in a mineral oil and blended with a liquid alkylated diphenylamine. The liquid product shows increased storage stability with respect to crystallization of the 1-[di(4-octylphenyl)aminomethyl]tolutriazole when the amine is added. This blend product can be stored for a prolonged period of time, and then utilized in a lubricant composition as an antioxidant and corrosion inhibitor.Type: GrantFiled: May 16, 2014Date of Patent: January 17, 2017Assignee: VANDERBILT CHEMICALS, LLCInventors: Steven G. Donnelly, Kevin J. Chase, William T. Wallack
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Patent number: 9546340Abstract: A low-phosphorus lubricating composition has less than 600 ppm phosphorus, comprising at least 85 weight % of a lubricating base blend, and an additive comprising the following, as weight % of the total composition: (1) an organomolybdenum compound at an amount which provides about 0.1-800 ppm Mo; (2) a hindered phenol at about 0.1-2%; and (3) a dithiocarbamate at about 0.1-2%; with a first proviso that where the dithiocarbamate does not comprise a metal dithiocarbamate, the additive additionally comprises: (4) an alkylated diphenylamine at about 0.1-2%, and with a second proviso that where the organomolybdenum compound comprises molybdenum dithiocarbamate, it is considered a metal dithiocarbamate for purposes of the first proviso, but is considered an organomolybdenum compound for the purposes of calculation of the amount present in the total composition.Type: GrantFiled: September 22, 2015Date of Patent: January 17, 2017Assignee: VANDERBILT CHEMICALS, LLCInventors: Glenn A. Mazzamaro, Steven G. Donnelly, Ronald J. Hiza
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Publication number: 20160326451Abstract: A lubricant composition is provided which mitigates the negative effect of zinc in ZDDP with respect to wear on timing chains by using in contact with the timing chain a lubricant composition comprising an ashless zinc-free organophosphorus compound and optionally zinc dialkyldithiophosphate, together providing about 50 to about 1000 ppm phosphorus, preferably about 300-800 ppm phosphorus, and more preferably about 500-750 ppm phosphorus; less than about 350 ppm to lower than <1 ppm zinc from ZDDP; and at least about 100 ppm molybdenum from an organomolybdenum compound (preferably molybdate ester); wherein the Mo:Zn ratio is at least about 0.2:1 and the Zn:P ratio is lower than or equal to about 1.1:1; or in the alternative an organomolybdenum compound providing between about 300-700 ppm molybdenum, in combination with ZDDP providing zinc between about 200-800 ppm zinc, wherein the ratio of Mo:Zn ratio is at least about 0.4:1 to about 3:1.Type: ApplicationFiled: May 3, 2016Publication date: November 10, 2016Applicant: VANDERBILT CHEMICALS, LLCInventors: Carl K. ESCHE, Glenn A. MAZZAMARO
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Patent number: 9481775Abstract: An additive composition for inhibiting scorch in a polyurethane foam composition, the additive comprising a derivatized hydroquinone; a derivatized lactone; and a derivatized phenolic compound. A polyurethane foam composition contains the additive composition.Type: GrantFiled: April 21, 2015Date of Patent: November 1, 2016Assignee: VANDERBILT CHEMICALS, LLCInventor: John M. DeMassa
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Patent number: 9315760Abstract: A lubricant composition with improved antioxidant capability is provided by way of an additive composition containing a metal free sulfur-containing compound, an aromatic amine, and a hindered amine. Particularly effective metal-free sulfur-containing compounds include ashless dithiocarbamates, such as methylenebis(dibutyldithiocarbamate), and sulfurized fatty acids.Type: GrantFiled: November 3, 2014Date of Patent: April 19, 2016Assignee: VANDERBILT CHEMICALS, LLCInventors: Kevin J. Chase, Brian W. Stunkel
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Publication number: 20160083671Abstract: A lubricant composition comprises as a lubricant base, an oil soluble polyalkylene glycol suitable for use as a lubricant in an industrial oil, grease or metal working fluid; and an additive comprising (1) alkylated phenyl-?-naphthylamine; and (2) 2,2,4-trialkyl-1,2-dihydroquinoline.Type: ApplicationFiled: February 4, 2015Publication date: March 24, 2016Applicant: VANDERBILT CHEMICAL, LLCInventors: JUNBING YAO, STEVEN G. DONNELLY
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Publication number: 20160068781Abstract: A lubricating composition comprising at least 90% by weight of a base oil, and an antioxidant composition comprising the components, set forth as weight % of the lubricating composition: (1) solid alkylated-phenyl-alpha-naphthylamine at 0.01-0.3%, (2) an alkylated diphenylamine derivative of triazole, tolutriazole or benzotriazole, at 0.01-0.3%, and (3) methylenebis(di-n-butyldithiocarbamate), at 0.01-0.4%.Type: ApplicationFiled: August 14, 2015Publication date: March 10, 2016Applicant: VANDERBILT CHEMICALS, LLCInventors: JUNBING YAO, VINCENT GATTO
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Publication number: 20160024415Abstract: A low-phosphorus lubricating composition has less than 600 ppm phosphorus, comprising at least 85 weight % of a lubricating base blend, and an additive comprising the following, as weight % of the total composition: (1) an organomolybdenum compound at an amount which provides about 0.1-800 ppm Mo; (2) a hindered phenol at about 0.1-2%; and (3) a dithiocarbamate at about 0.1-2%; with a first proviso that where the dithiocarbamate does not comprise a metal dithiocarbamate, the additive additionally comprises: (4) an alkylated diphenylamine at about 0.1-2%, and with a second proviso that where the organomolybdenum compound comprises molybdenum dithiocarbamate, it is considered a metal dithiocarbamate for purposes of the first proviso, but is considered an organomolybdenum compound for the purposes of calculation of the amount present in the total composition.Type: ApplicationFiled: September 22, 2015Publication date: January 28, 2016Applicant: Vanderbilt Chemicals, LLCInventors: GLENN A. MAZZAMARO, STEVEN G. DONNELLY, RONALD J. HIZA
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Patent number: 9228150Abstract: A lubricating oil composition comprising a zinc dithiocarbamate fraction, for use in a gasoline or diesel engine equipped with fluoroelastomer seals, wherein said zinc dithiocarbamate fraction consists essentially of zinc dithiocarbamate molecules per Formula I: having alkyl groups R1, R2, R3, and R4, wherein the weighted total average for carbon chain lengths for all molecules together is 9 or more:Type: GrantFiled: April 2, 2012Date of Patent: January 5, 2016Assignee: VANDERBILT CHEMICALS, LLCInventors: Gaston A. Aguilar, Francis S. Cheng, Kevin J. Chase
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Patent number: 9200228Abstract: A lubricating composition comprises a major amount of a base oil, and an additive comprising a polyoxo Lindqvist ion of formula [M1aM2bQ1cQ2d]q, wherein M1 and M2 may be the same or different and are chosen from Group 3-12 transition metals, the Lindqvist ion being solvated with a hydrocarbyl substituted amine, the Lindqvist ion optionally containing bound organic ligands containing electron donating groups, the additive being present in amount to provide about 0.2-3 moles of metal from the Lindqvist ion per megagram of lubricating composition.Type: GrantFiled: December 16, 2013Date of Patent: December 1, 2015Assignee: VANDERBILT CHEMICALS, LLCInventor: David M. Boudreau