Abstract: A process for the preparation of neutralized, clear, stable solutions by acid catalyzed reaction of urea and aldehydes where the aldehydes are either acetaldehyde or mixtures of not more than 3 moles of propionaldehyde to 1 mole of acetaldehyde, at reaction pH's of from about 3.1 to 4.5 at temperatures from about 30.degree. C. to 75.degree. C. and the mole ratio of urea to aldehydes is about 1.3:1 to 2.5:1. The products of the process are useful as sprayable sources of nitrogen which are non phytotoxic and have prolonged fertilizer activity.
Abstract: An improvement in a process for the preparation of neutralized urea aldehyde polmeric dispersions by acid catalyzed reaction of urea with formaldehyde plus a higher aldehyde having from two to four carbon atoms wherein the improvement comprises reacting urea with formaldehyde and a polyfunctional aldehyde selected from the group consisting of a dialdehyde of from 2 to 5 carbon atoms or a polymer of formaldehyde such as a hydroxyaldehyde or polysaccharide which has a reactive, reducible aldehyde group wherein the mole ratio of formaldehyde to the polyfunctional aldehyde is at least 3:1. The products are useful as long term, sprayable fertilizers, especially for grasses.
Type:
Grant
Filed:
December 10, 1982
Date of Patent:
October 2, 1984
Assignee:
W. A. Cleary Chemical Corporation
Inventors:
Paul Sartoretto, Prathivadibhayankaram S. Sampathkumar
Abstract: A process for the preparation of neutralized, urea aldehyde polymeric dispersions by acid catalyzed reaction of urea and formaldehyde plus a higher aldehyde, having from two to four carbon atoms, wherein the mol ratio of formaldehyde to the higher aldehyde is at least 2:1 and the function of the higher aldehyde is to act as an inhibitor of further polymerization. The dispersions are further stabilized against settling by the addition of thickener-suspending agents. The products of the process are useful as sources of nitrogen which continue to fertilize plants, especially grasses for long periods of time after applied by means of conventional spraying equipment.
Abstract: A process for the preparation of neutralized, urea aldehyde polymeric dispersions by acid catalyzed reaction of urea and formaldehyde plus a higher aldehyde, having from two to four carbon atoms, wherein the mol ratio of formaldehyde to the higher aldehyde is at least 2:1 and the function of the higher aldehyde is to act as an inhibitor of further polymerization. The dispersions are further stabilized against settling by the addition of thickener-suspending agents. The products of the process are useful as sources of nitrogen which continue to fertilize plants, especially grasses for long periods of time after applied by means of conventional spraying equipment.