Abstract: A method of releasing particulates from a solid matrix is provided. The method is effected adding to the solid matrix a degrading enzyme capable of degrading the solid matrix, to thereby release the particulates from the solid matrix.
Type:
Grant
Filed:
March 22, 1999
Date of Patent:
February 6, 2001
Assignees:
CBD Technologies, LTD, Yissum R&D Company of the Hebrew University
Abstract: An improved process for the manufacture of aromatic dicarboxylic acids and derivatives thereof is described. The process is based on the reaction of a corresponding aromatic hydrocarbon in a liquid phase oxidation with an oxygen-containing gas in the presence of a phase-transfer catalyst (a) a transition metal salt (b) and traces of a polar solvent, such as water, the molar ratio between (a) and (b) being in the range of between 0.25:1 to 1.5:1. The phase-transfer catalyst is selected from the quaternary ammonium and phosphonium salts having a total carbon atoms in the range of 17 to 58, the anion bound thereto being selected from Br.sup.-, F.sup.-, Cl.sup.-, OH.sup.-, CH.sub.3 COO.sup.- and HSO.sub.4. Among the aromatic dicarboxylic acids and derivatives thereof the following are mentioned: terephthalic acid; isophthalic acid and methyl terephthalate. The process is characterized by the very high conversion of the respective aromatic hydrocarbon reaching even 100%.
Type:
Grant
Filed:
November 3, 1988
Date of Patent:
August 1, 1989
Assignees:
Gadot Petrochemical Industries, Ltd., Yissum R & D Company of the Hebrew University of Jerusalem