Abstract: Provided is method of producing graphene-embraced anode particulates for a lithium battery, the method comprising: (A) providing anode active material-decorated carbon or graphite particles, wherein the carbon or graphite particles have a diameter or thickness from 500 nm to 50 ?m and the anode active material, in a form of particles or coating having a diameter or thickness from 0.5 nm to 2 ?m, is bonded to surfaces of the carbon or graphite particles; and (B) embracing the anode active material-decorated carbon or graphite particles with a shell comprising multiple graphene sheets to produce the graphene-embraced anode particulates.

Abstract: A lithium-ion secondary battery positive electrode active material complex, a lithium-ion secondary battery positive electrode, and a lithium-ion secondary battery using the lithium-ion secondary battery positive electrode containing the lithium-ion secondary battery positive electrode active material complex are provided so that a lithium-ion secondary battery having high output properties, excellent durability, and a high energy density can be attained. A positive electrode active material for a lithium-ion secondary battery contains a complex in which a surface of a first positive electrode active material made of a lithium transition metal complex oxide containing nickel is covered with a covering layer containing an olivine type second positive electrode active material on a surface of which carbon is carried and a carbon nanotube.

Abstract: Provided is a nickel-based active material precursor for a lithium secondary battery, including: a secondary particle including a plurality of particulate structures, wherein each of the particulate structures includes a porous core portion and a shell portion including primary particles radially arranged on the porous core portion, and in 50% or more of the primary particles constituting a surface of the secondary particle, a major axis of each of the primary particles is aligned along a normal direction of the surface of the secondary particle. When the nickel-based active material precursor for a lithium secondary battery is used, it is possible to obtain a nickel-based active material which intercalates and deintercalates lithium and has a short diffusion distance of lithium ions.

Abstract: Provided is anode active material for use in a lithium ion battery, wherein the anode active material is capable of reversibly storing lithium ions therein up to a maximum lithium storage capacity Cmax during a charge or discharge of the battery and the anode active material comprises an amount of solid-electrolyte interphase (SEI) on a surface or in an internal structure of the anode active material wherein the SEI is pre-formed prior to incorporating the anode active material in an anode electrode of the battery. Also provided is a method of producing the pre-formed SEI substances in the anode material; e.g. through repeated lithiation/delithiation procedures.

Abstract: Articles and methods related to electrochemical cells and/or electrochemical cell components (such as electrodes) comprising species comprising a conjugated, negatively-charged ring comprising a nitrogen atom and/or reaction products of such species are generally provided. The electrochemical cell may comprise an electrode (e.g., a cathode) comprising a protective layer comprising a species comprising a conjugated, negatively-charged ring comprising a nitrogen atom and/or a reaction product thereof.

Abstract: Self-charging electrochemical cells, including self-charging batteries that incorporate such self-charging electrochemical cells, the electrochemical cells including a cathode including a cathode active material, an electrolyte including a solvent and a salt dissolved in the solvent, the electrolyte being in contact with the cathode, where the cathode active material is transformed into a discharge product during or after a discharge of the self-charging electrochemical cell and a solubility of the cathode active material in the electrolyte is less than a solubility of the discharge product in the electrolyte.

Abstract: A positive electrode material for a secondary battery, including a first positive electrode active material and a second positive electrode active material, wherein the first positive electrode active material and the second positive electrode active material consist of a lithium composite transition metal oxide including at least two or more transition metals selected from the group consisting of nickel (Ni), cobalt (Co) and manganese (Mn) are provided. The average particle size (D50) of the first positive electrode active material is two or more times larger than that of the second positive electrode active material, and the first positive electrode active material has a concentration gradient in which at least one of Ni, Co or Mn contained in the lithium composite transition metal oxide has a concentration difference of 1.5 mol % or more between the center and the surface of a particle of the lithium composite transition metal oxide.

Abstract: This application provides a positive active material, a positive electrode plate, an electrochemical energy storage apparatus, and an apparatus. The positive active material is LixNiyCozMkMepOrAm, or LixNiyCozMkMepOrAm with a coating layer on its surface; and the positive active material is single crystal or quasi-single crystal particles, and a particle size Dn10 of the positive active material satisfies: 0.3 ?m?Dn10?2 ?m. In this application, particle morphology of the positive active material and an amount of micro powder in the positive active material are properly controlled, to effectively reduce side reactions between the positive active material and an electrolyte solution, decrease gas production of the electrochemical energy storage apparatus, and improve storage performance of the electrochemical energy storage apparatus without deteriorating an energy density, cycle performance, and rate performance of the electrochemical energy storage apparatus.

Abstract: The present invention provides a nonaqueous electrolytic solution capable of improving electrochemical characteristics in the case of using an energy storage device at a high temperature and at a high voltage and further capable of inhibiting the gas generation while maintaining a capacity retention rate after storage at a high temperature and at a high voltage and also provides an energy storage device using the same. Disclosed is a nonaqueous electrolytic solution having an electrolyte salt dissolved in a nonaqueous solvent, the nonaqueous electrolytic solution containing a carboxylic acid ester compound represented by the following general formula (I). In the formula, each of R1 and R2 independently represents a hydrogen atom, a —C(?O)—OR4 group, or the like, and R1 and R2 may be bonded to each other to form a ring structure. R3 represents a hydrogen atom or the like, and n represents an integer of 1 to 3.

Abstract: An anode active material for a lithium secondary battery and a lithium secondary battery are provided. The anode active material includes a carbon-based particle including pores formed in at least one of an inside of the particle and a surface of the particle and having a pore size of the carbon-based particle is 20 nm or less, and silicon formed at an inside of the pores of the carbon-based particle or on the surface of the carbon-based particle. A peak intensity ratio in a Raman spectrum of silicon defined as I(515)/I(480) is 1.2 or less. Difference between volume expansion ratios of carbon and silicon can be reduced to improve life-span property of the secondary battery.

Abstract: The invention provides a lithium ion battery comprising: an anode comprising an anode active material layer on an anode current collector, the anode active material layer having a mass load higher than 60 g/m2; a cathode comprising a cathode active material layer on a cathode current collector, the cathode active material layer having a mass load higher than 80 g/m2; and an electrolytic solution comprising an imide anion based lithium salt and LiPO2F2, wherein at least one of the anode and cathode active material layers comprises a spacer comprising silicone ball.

Abstract: A novel and environmentally preferable method is provided for preparing solid electrolyte particles capable of making dense, flexible, Li+ conducting electrolyte thin films. Methods are also provided for using the solid electrolyte particles and/or thin films in manufacturing safer and more efficient lithium-based batteries. In particular, the method uses inorganic precursors instead of using organic precursors in preparing an aerosol and then convert the aerosol to solid powders to provide the solid electrolyte particles. The solid electrolyte particles prepared have a cubic polymorph and have a desired particle size range, and are capable of making a solid electrolyte film with a thickness less than 50 ?m.

Abstract: An improved process for forming a lithium metal phosphate cathode material, a precursor to the cathode material and a battery comprising the cathode material is described. The process comprising: forming an first aqueous solution comprising a first molar concentration of Li+and a second molar concentration of PO43?; forming a second aqueous solution comprising organic acid or a salt of an organic acid and a metal selected from the group consisting of Fe, Ni, Mn and Co wherein said metal is present in a third molar concentration; allowing a precipitate to form; drying the precipitate; and calcining the precipitate thereby forming the lithium metal phosphate cathode material having a formula represented by LiMPO4/C wherein the lithium metal phosphate cathode material comprises up to 3 wt % carbon.

Abstract: A lithium cobalt-based oxide cathode active material powder comprising particles having a median particle size D50 of greater than or equal to 20 ?m, preferably 25 ?m, and less than or equal to 45 ?m, said particles having an averaged circularity of greater than or equal to 0.85 and less than or equal to 1.00, said particles having a general formula Li1+aCo1-x-y-zAlxM?yMezO2, wherein M? and Me comprise at least one element of the group consisting of: Ni, Mn, Nb, Ti, W, Zr, and Mg, with ?0.01?a?0.01, 0.002?x?0.050, 0?y?0.020 and 0?z?0.050, said lithium cobalt-based oxide particles having a R-3m structure and (018) diffraction peak asymmetry factor AD(018) of greater than or equal to 0.85 and less than or equal to 1.15, said diffraction peak asymmetry factor being obtained by a synchrotron XRD spectrum analysis with an emission wavelength ? value equal to 0.825 ?.

Abstract: A negative electrode sheet and a manufacturing method thereof and a battery are provided in the disclosure. The negative electrode sheet includes a conductive fiber cloth, a support layer, and an active material layer. The conductive fiber cloth serves as a current collector of the negative electrode sheet. The support layer is formed on a surface of the conductive fiber cloth and includes multiple protruding units, where each of the multiple protruding units includes multiple needle-shaped protrusions, and the multiple needle-shaped protrusions of each protruding unit are arranged radially. The active material layer includes multiple active portions, where each of the multiple active portions is formed on a surface of one of the multiple needle-shaped protrusions, and different active portions are formed on surfaces of different needle-shaped protrusions.

Abstract: The present invention relates to lithium rechargeable battery cathode materials. More specifically, the cathode materials are compositionally gradient nickel-rich cathode materials produced using single-source composite precursor materials containing inorganic and/or metalorganic salts of lithium, nickel, manganese, and cobalt. Methods and systems for manufacturing the cathode materials by a combined spray pyrolysis/fluidized bed process are also disclosed.

Abstract: A conductive material dispersion containing a conductive material containing carbon fibers, a dispersant, and a dispersion medium, in which the dispersant contains a copolymer A containing a nitrile group-containing structural unit and an aliphatic hydrocarbon structural unit, and a Mooney viscosity (ML1+4, 100° C.) of the copolymer A is 40 to 70, and the conductive material dispersion has a phase angle of 19° or greater at a frequency of 1 Hz.

Abstract: A standalone lithium ion-conductive solid electrolyte including a freestanding inorganic vitreous sheet of sulfide-based lithium ion conducting glass is capable of high performance in a lithium metal battery by providing a high degree of lithium ion conductivity while being highly resistant to the initiation and/or propagation of lithium dendrites. Such an electrolyte is also itself manufacturable, and readily adaptable for battery cell and cell component manufacture, in a cost-effective, scalable manner.

Abstract: A lithium ion-conductive solid electrolyte including a freestanding inorganic vitreous sheet of sulfide-based lithium ion conducting glass is capable of high performance in a lithium metal battery by providing a high degree of lithium ion conductivity while being highly resistant to the initiation and/or propagation of lithium dendrites. Such an electrolyte is also itself manufacturable, and readily adaptable for battery cell and cell component manufacture, in a cost-effective, scalable manner.

Abstract: The cathode active material for a lithium secondary battery according to embodiments of the present invention includes a lithium-transition metal composite oxide particle including a plurality of primary particles, and the lithium-transition metal composite oxide particle includes a lithium-sulfur-containing portion formed between the primary particles. Thereby, it is possible to improve life-span properties and capacity properties by preventing the layer structure deformation of the primary particles and removing residual lithium.