Abstract: A method is disclosed for producing a flexographic printing plate from a flexographic printing original plate provided with a photosensitive resin layer comprising a photosensitive resin composition containing at least (A) a hydrophobic polymer comprising a water-dispersible latex, (B) a photopolymerizable compound and (C) a photopolymerization initiator, wherein the method comprises a main exposure step, a development step and a post-exposure step, characterized in that a treatment solution containing a first amino-modified silicone having an amine equivalent of 1000 g/mol or less and a second amino-modified silicone having an amine equivalent of 3000 g/mol or more in a mass ratio of from 2.5:1 to 1:6 is contacted with the whole surface of the flexographic printing plate.
Abstract: Disclosed is a liquid crystal compound. The compound has a general structural formula as shown by formula I. Such a compound has good thermal and UV stability, large positive dielectric anisotropy ??, and can achieve a low threshold voltage when used in optics, thereby having great significance to the fast response of display devices, and therefore being very suitable for formulating a liquid crystal mixture. A liquid crystal mixture containing such a liquid crystal unit can be applied to various display devices, and is especially suitable for TN-TFT and STN display devices, but can also be used in IPS (in-plane switching) and VA (vertically aligned) display devices.
Abstract: A method of making a lithographic printing plate includes the steps of a) image-wise exposing a lithographic printing plate precursor, including a support including a hydrophilic surface or a hydrophilic layer and, thereon, a light or heat sensitive coating including a photopolymerizable composition, b) processing the precursor, consecutively, with a first solution and a second solution, to remove the coating from the support in the non-printing areas, wherein the first and second solutions are provided by a cascade system, the second solution overflows into the first solution and the first solution overflows into a container to be treated as waste, and the second solution is regenerated by adding a replenishing solution or a mixture of replenishing solutions at a rate of at least 5 ml/m2 of treated precursor and at most 100 ml/m2 of treated precursor.
Type:
Grant
Filed:
January 7, 2014
Date of Patent:
May 31, 2016
Assignee:
AGFA GRAPHICS NV
Inventors:
Peter Hendrikx, Jan Sinnesael, Roberto Carbonini, Sam Verbrugghe
Abstract: Disclosed is a lithographic printing plate allowing for high running performance of the developer, wide water window and high printing durability. The lithographic printing plate precursor comprises a photosensitive layer on a support, wherein the photosensitive layer comprises (A) a polymerizable compound, (B) a polymerization initiator, (C) a polyvinyl acetal binder containing at least one kind of repeat units represented by general formula (I-c), general formula (I-b) and general formula (I-a), and (D) an acrylic resin binder.
Abstract: A photocurable relief image printing element is described. The photocurable relief image printing element comprises (a) a support layer; (b) one or more photocurable layers disposed on the support layer, wherein the one or more photocurable layers comprise: (i) a binder; (ii) one or more monomers; (iii) a photoinitiator; and (iv) an additive selected from the group consisting of phosphites, phosphines, thioether amine compounds, and combinations of one or more of the foregoing; (c) a laser ablatable masking layer disposed on the one or more photocurable layers, the laser ablatable masking layer comprising a radiation opaque material; and (d) optionally, a removable coversheet. The photocurable relief image printing element provides improved surface cure in digital relief image printing elements.
Abstract: A negative-working lithographic printing plate precursor includes a coating containing a photopolymerizable layer and optionally an intermediate layer between the photopolymerizable layer and the support, wherein the coating further includes a polysiloxane, the polysiloxane being present in the photopolymerizable layer and/or in the optional intermediate layer, and the polysiloxane is obtained by reacting at least one organosilicon compound represented by the general Formula (I) and at least one organosilicon compound represented by the general Formula (II):
Type:
Grant
Filed:
March 20, 2013
Date of Patent:
May 3, 2016
Assignee:
AGFA GRAPHICS NV
Inventors:
Johan Loccufier, Marin Steenackers, Sam Verbrugghe
Abstract: Lithographic printing plates are provided by imagewise exposing negative-working lithographic printing plate precursors having a negative-working radiation-sensitive imageable layer, followed by contacting with a processing solution that has a pH of at least 7 and up to and including 11. This processing solution also includes component (1) that is a nitrogen-containing base having an atmospheric pressure melting point of at least 40° C.; component (2) that is a non-ionic surfactant that independently has an atmospheric pressure melting point, glass transition temperature, or pour point of at least 40° C.; component (3) that is a hydroxy-containing solution promoter; and component (4) that is a hydrophilic surface protective compound. The method is carried out in a manner such that the exposed and processed precursor is not further treated with any liquid (such as gumming or rinsing solution) between processing and mounting onto a printing press.
Type:
Grant
Filed:
September 12, 2014
Date of Patent:
May 3, 2016
Assignee:
EASTMAN KODAK COMPANY
Inventors:
Christopher D. Simpson, Harald Baumann, Michael Flugel, Saija Werner, Oliver Piestert, Udo Dwars
Abstract: A photoinitiator composition comprising a combination of aminoalkyl phenone, thioxanthone and multifunctional amino benzoate synergist for use in printing inks and coatings that are curable using UV radiation, particularly from LED lamps.
Abstract: An apparatus comprises: (a) a rotatable drum configured to have a UV-curable printing plate with an ablatable layer thereon, placed thereon; (b) at least one laser beam to image the plate on the drum by ablating some of the ablatable layer according to image data to form an imaged plate; (c) an unloading area onto which a plate is movable when unloaded; and (d) a plurality of UV LEDs configured to cure UV-curable material on at least an imaged portion of the plate during the imaging process, such that imaging of one part of the plate and curing of an imaged portion of the plate occur simultaneously. In another embodiment, the plurality of LEDs are to apply UV radiation to the back of the UV-curable plate or to both the front and back of the UV-curable plate during or after the unloading of the imaged plate.
Abstract: A thermally-sensitive, positive-working lithographic printing plate precursor can be used to prepare lithographic printing plates using high pH, silicate-free processing solutions. The precursor has a grained an anodized aluminum-containing substrate including a poly(vinyl phosphonic acid) interlayer. A first ink receptive layer, and optionally a second ink receptive layer, is disposed directly on the poly(vinyl phosphonic acid) interlayer. This first ink receptive layer comprises an aromatic acid dye that comprises at least two aromatic groups in an amount of least 0.5 weight %. In addition, the precursor comprises an infrared radiation absorber in one of the layers.
Type:
Grant
Filed:
June 5, 2014
Date of Patent:
April 12, 2016
Assignee:
EASTMAN KODAK COMPANY
Inventors:
Gerhard Hauck, Dietmar Frank, Celin Savariar-Hauck
Abstract: Negatives, and laminates containing negatives, for exposing liquid photopolymers in UV flexographic plate making are created by printing opaque images directly onto the protective or release cover films used in plate making processes. Combining negatives and cover films in this way eliminates two layers and two interfaces in the exposure process, reducing cost and improving quality. By bringing the negative images as close as possible to the liquid photopolymer, printed dots of “digital quality” are created.
Abstract: The present invention relates to a curable jettable fluid for making a flexographic printing master characterized in that the jettable fluid has a viscosity measured at jetting temperature of less than 15 mPa·s and comprises at least 50 wt. % of a mixture of a cyclic monofunctional (meth)acrylate monomer, a monofunctional urethane acrylate oligomer and a difunctional (meth)acrylate monomer.
Abstract: A method of making a relief image printing element from a photosensitive printing blank is provided. The method comprising the steps of: 1) providing a photosensitive printing blank comprising a backing layer, at least one layer of photoresin on top of the backing layer and a removable coversheet on top of the at least one layer of photoresin; 2) imaging the photosensitive printing blank through the removable coversheet using a laser to create a relief image therein; and 3) removing the removable coversheet.
Abstract: A liquid crystal composition has a nematic phase, and contains a specific tricyclic compound having a large dielectric anisotropy as a first component and a specific bicyclic compound having a small viscosity as a second component, and may contain a specific compound having a high maximum temperature or a large dielectric anisotropy as a third component, and a specific compound having a high maximum temperature or a small viscosity as a fourth component, and a liquid crystal display device includes the composition.
Abstract: The present invention provides a rinse solution for lithography and a pattern formation method using the solution. They can improve the pattern collapse, surface roughness and surface defects. The solution contains at least a sulfonic acid a nonionic surfactant having an alkyleneoxy group and water.
Type:
Grant
Filed:
March 22, 2012
Date of Patent:
March 29, 2016
Assignee:
MERCK PATENT GMBH
Inventors:
Xiaowei Wang, Georg Pawlowski, Yuriko Matsuura
Abstract: A method of controlling surface roughness of a flexographic printing element during thermal processing is provided. An imaged and exposed relief image printing element is thermally developed to remove the portions of at least one layer of photopolymer that are not crosslinked and cured by using a blotting material. The blotting material is separated from the at least one layer of photopolymer. Thereafter, a smooth material is inserted between the surface of the at least one layer of photopolymer and the blotting material, applying pressure and heat. In the alternative, after the relief image printing element is removed from the thermal processor, a polymeric film is laminated onto the relief image printing element using heat and pressure. The surface roughness of the relief image printing element is reduced, allowing for increased solid ink density on solid areas printed using the relief image printing element.
Abstract: A developing solution for photolithography in which tetrabutylammonium hydroxide (TBAH) is used as an alkaline agent of the developing solution and deposition of TBAH is suppressed. A method for producing a developing solution for photolithography capable of suppressing TBAH deposition when producing the developing solution by diluting a concentrated developing solution containing TBAH and a production apparatus used for the production method. The developing solution includes tetrabutylammonium hydroxide and at least one of a water-soluble organic solvent, a surfactant, and a clathrate compound. The temperature of the liquid is maintained at 27° C. or higher during dilution.
Type:
Grant
Filed:
February 19, 2015
Date of Patent:
March 22, 2016
Assignee:
Tokyo Ohka Kogyo Co., Ltd.
Inventors:
Tomoya Kumagai, Naohisa Ueno, Jun Koshiyama
Abstract: To provide a liquid crystal compound having a high stability to light, a high clearing point, a low minimum temperature of a liquid crystal phase, a small viscosity, a suitable optical anisotropy, a large dielectric anisotropy, a suitable elastic constant and an excellent solubility in other liquid crystal compounds.
Abstract: A method of making a relief image printing element from a photosensitive printing blank is described. The photosensitive printing blank comprises a laser ablatable mask layer disposed on at least one photocurable layer and the laser ablatable mask layer is selectively laser ablated to create an in situ mask and uncover portions of the at least one photocurable layer. The method includes a) pushing the photosensitive printing blank through a nip formed by a textured roller and a backing roller, wherein the textured roller contacts the in situ mask and the uncovered portions of the at least one photocurable layer; and b) exposing the at least one photocurable layer to at least one source of actinic radiation through the in situ mask to selectively cross link and cure the portions of the at least one photocurable layer not covered by the in situ mask. A defined topographical pattern is transferred from the textured surface of the roller to the at least one photocurable layer.
Type:
Grant
Filed:
February 19, 2014
Date of Patent:
February 9, 2016
Inventors:
Timothy Gotsick, Laurie A. Bryant, David A. Recchia
Abstract: A developing method including a developing step in which, while a wafer horizontally held by a spin chuck is being rotated, the wafer is developed by supplying a developer onto a surface of the wafer, wherein provided before the developing step is a pre-wetting step in which, simultaneously with the developer being supplied from a first nozzle that is located on a position near a central part of the surface of the rotating wafer, a deionized water as a second liquid is supplied from a second nozzle that is located on a position nearer to an outer peripheral part of the wafer than the first nozzle, to thereby spread out the developer in the rotating direction of the wafer by a wall that is formed by the deionized water flowing to the outer peripheral side of the wafer with the rotation of the wafer.