Abstract: A method of bonding two substrates at least one of which is a rubbery polymeric material having carbon-carbon double bonds on the polymer backbone, the method comprising:
a) applying an aqueous polyurethane dispersion adhesive composition to at least one of the substrates, the adhesive compostion further comprising an epoxy resin;
b) allowing the composition to dry; and then
c) joining the substrates with heating to activate the adhesive. The substrates are suitably footwear materials such as a molded rubber outer sole which has been first primed with a chlorinating primer, and a foam midsole of a material such as a lightly crosslinked ethylene vinyl acetate. The process results in bonded assemblies having improved humidity resistance.
Type:
Grant
Filed:
December 8, 1998
Date of Patent:
September 11, 2001
Assignee:
H. B. Fuller Licensing & Financing, Inc.
Inventors:
Yuduo Zhu, Robert J. Duff, Peter Gottschalk, Brian L. Marty
Abstract: An automobile exterior component, having good balance between impact resistance and fluidity and being excellent in coating heat resistance and rigidity, which is prepared by performing urethane coating or melamine coating on a molded article obtained by molding a resin composition which comprises a polyamide resin (A); a grafted polymer (B) prepared by graft polymerizing an aromatic vinyl monomer and a vinyl cyanide monomer in the presence of a diene rubber;
an unsaturated carboxylic acid-modified copolymer (C) which has a reduced viscosity of 0.2 to 0.5 dl/g and is prepared by polymerizing an unsaturated carboxylic acid monomer, an aromatic vinyl monomer and a vinyl cyanide monomer;
a copolymer (D) prepared by polymerizing an aromatic vinyl monomer and a vinyl cyanide monomer; and
talc, wherein the amount ratio of (A), (B), (C) and (D) is in a specific range.
Type:
Grant
Filed:
January 21, 2000
Date of Patent:
August 14, 2001
Assignees:
Nippon A & L Incorporated, Honda Giken Kogyo KA
Abstract: A coated substrate is provided which includes an outer coating formed from a film-forming composition which includes a crosslinkable, non-gelled acrylic polymer and a crosslinking material capable of reacting with the acrylic polymer to form a crosslinked outer coating. The acrylic polymer is the reaction product of a polyoxyalkylene acrylate monomer comprising a terminal alkoxy group containing about 1 to about 6 carbon atoms and a copolymerizable ethylenically unsaturated monomer different from the polyoxyalkylene acrylate monomer. A multi-component composite coating composition is also provided.
Type:
Grant
Filed:
June 10, 1999
Date of Patent:
August 7, 2001
Assignee:
PPG Industries Ohio, Inc.
Inventors:
Shanti Swarup, Walter Metzger, Giancarlo Cirani, Debra L. Singer, Richard J. Sadvary, Robyn E. McMillan, James E. Reddy, Dieter Eiss
Abstract: A polyurethane material comprising a hexamethylene diisocyanate (HDI) trimer and a polyol is disclosed. Content of oligomer, which is equal to or higher than a pentamer, in said HDI trimer is restricted to 0 to 50% by weight, and 3 to 10% by weight of monool is added to said HDI trimer. The polyurethane material is high in breaking elongation, superior in flexural resistance, and not subject to cracks or breaking.
Abstract: A write-erase article formed of a substrate coated on one surface with a cured epoxy coating composition, and coated on another surface with an adhesive. The epoxy-coated surface is markable with dry wipe inks without causing permanent discernible distortion of the substrate. The epoxy-coated surface after marking is substantially fully erasable. The article may be adhered via the adhesive to a support.
Type:
Grant
Filed:
February 25, 2000
Date of Patent:
July 24, 2001
Assignee:
Honeywell International Inc.
Inventors:
Jayesh C. Shah, Lance R. Altizer, Insuk Chung, David J. Gibboni
Abstract: A coated electronic assembly comprises an electronic assembly, and a single-layer conformal coating overlying at least a portion of the electronic assembly. The conformal coating has a volume electrical resistivity of from about 108 to about 1014 ohm-centimeter. The conformal coating is formed of an organic polymeric binder, and a plurality of electrically semiconductive metal oxide filler particles dispersed in the binder. The binder and the filler particles have substantially the same visible-light refractive index. The binder may be a heat-curable or UV-curable urethane, and the particles may be doped (Al,Mg,Zn)3O4 or doped ZnO.
Abstract: The invention relates to a self-adhesive powder composition with improved resistance to creep, based on thermoplastic and/or heat-curable resins and acicular calcium carbonate. The composition is applied in powder form onto a metal substrate and then a creep-resistant coating is obtained by melting the powder.
Type:
Grant
Filed:
October 29, 1999
Date of Patent:
June 26, 2001
Inventors:
Patrick Douais, Didier Juhue, Olivier Julien, Michael Werth
Abstract: An improved heat transfer release finish on cookware is formed by coating the cookware interior (sidewall and flat bottom) with a mixture of fluoropolymer and magnetic flakes and magnetically orienting said flakes to run in the thickness direction of the coating, followed by baking the coating. Advantageously, the coating mixture also contains compatibilizing polymer which enables the flakes to be so-oriented without creating minute fissures in the coating.
Abstract: A vibration-isolating laminar rubber structure including highly rigid hard plates and rubber layers which are alternately laminated on each other, wherein the rubber layers are formed of a rubber composition comprising 1-50 parts by weight of at least one kind of material selected from among asphalt materials (e.g., natural asphalt), tar materials and pitch materials, per 100 parts by weight of a rubber material (natural rubber and/or diene-based synthetic rubber). The rubber composition preferably further comprises 10-150 parts by weight of carbon black and/or 1-50 parts by weight of a plasticizer having a freezing point of not higher than −30° C, per 100 parts by weight of the rubber material.
Abstract: A thermoplastic olefin elastomer molded article has a sealant contact portion coming into contact with a urethane sealant and is substantially made of thermoplastic olefin elastomer. At least the sealant contact surface of the sealant contact portion is made of a polyvinyl chloride layer or a thermoplastic polyurethane layer. At least the portion of the molded article adjoining the polyvinyl chloride layer or the thermoplastic polyurethane layer is made of a chlorinated thermoplastic olefin elastomer which is obtained by replacing part or the whole of the non-rigid phase of a thermoplastic olefin elastomer with chlorinated polyethylene and is capable of thermal fusion bonding to the polyvinyl chloride layer or the thermoplastic polyurethane layer.
Abstract: A thermoplastic laminate film containing a thermoplastic substrate film and a layer formed from a resin composition containing a polyester graft copolymer (A) and a resin (B), the layer being formed on at least one side of the thermoplastic substrate film, the polyester graft copolymer (A) being obtained by grafting at least one polymerizable unsaturated monomer, which contains an acid anhydride having a double bond, to a hydrophobic polyester resin, and the resin (B) containing at least one member selected from the group consisting of a polyurethane resin, an acrylic resin and a vinyl resin. The adhesion improving layer of the inventive thermoplastic laminate film shows superior adhesion strength in a broad range of applications.
Type:
Grant
Filed:
May 25, 1999
Date of Patent:
February 27, 2001
Assignee:
Toyo Boseki Kabushiki Kaisha
Inventors:
Masayoshi Satoh, Chikao Morishige, Shinya Higashiura, Hiroshi Taki
Abstract: The leather has a finish on a buffed surface. The finish layer is formed in a plurality of layers including an outer layer with a given hardness and a particular surface effect preformed in a hot substrate having a structure corresponding to the particular surface effect the outer layer being formed of a solidified, cross-linked, hydrolysis-resistant, lightfast, polyurethane-containing dispersion, and having a thickness of between 0.01 and 0.08 mm, and an inner layer bonded to the buffed surface leather and comprising a solidified, highly crosslinked, hydrolysis-resistant, lightfast, polyurethane-containing dispersion and having a hardness less than a hardness of the outer layer.
Abstract: A multilayer coating film which comprises:
a cationic electrodeposition coat formed from an epoxy-based cationic electrocoating composition containing 5 to 300 millimoles of sulfonium group and 50 to 2,000 millimoles of carbon-carbon unsaturated bond per 100 g of the resin solid content, with carbon-carbon triple bond accounting for at least 15% of said carbon-carbon unsaturated bond; and
a top coat formed thereon.
Abstract: A coating composition is provided comprising hyaluronic acid or a salt thereof and a blocked polyisocyanate in a solvent comprising water. A method is provided for preparing the coating on a substrate comprising forming a coating mixture of hyaluronic acid or a salt thereof and a blocked polyisocyanate in a solvent comprising water; applying the coating mixture to the substrate; and curing the coating.
Type:
Grant
Filed:
September 30, 1998
Date of Patent:
December 12, 2000
Assignee:
Medtronic AVE, Inc.
Inventors:
Chirag B. Shah, John A. Hudson, Eugene Tedeschi
Abstract: A roller for electrophotography is made from a mixture of polyurethane, polydiene, polyether diol, a first conductive filler and a second conductive filler which catalyzes oxidation of the polydiene. The first conductive filler comprises hexahalogenated acetylacetonates. The roller has a very high outer surface electrical resistance from baking the roller to oxidize the polybutadiene. The charge roller is achieved at low production cost and functions well with charging by a DC potential and AC overlay.