Abstract: This invention relates to a polyolefin composition comprising one or more of the following formulae: wherein the PO is the residual portion of a vinyl terminated macromonomer (VTM) having had a terminal unsaturated carbon of an allylic chain and a vinyl carbon adjacent to the terminal unsaturated carbon; X is attached to the terminal portion of the VTM to provide PO—X or at the vinylidene carbon of the VTM to provide PO—CHXCH3; and X is Cl, Br, I, or F.
Type:
Grant
Filed:
September 23, 2013
Date of Patent:
May 10, 2016
Assignee:
ExxonMobil Chemical Patents Inc.
Inventors:
Man Kit Ng, Donna J Crowther, Hong Cheng, Patrick Brant
Abstract: The present invention provides a composition which does not cause the problem of use at high temperature in the mounting process of electronic device. The present invention relates to an underfill sealant composition comprising (a) a (meth)acrylic compound and (c) an isocyanuric acid having an allyl group.
Type:
Grant
Filed:
March 7, 2014
Date of Patent:
May 10, 2016
Assignee:
Henkel AG & Co. KGaA
Inventors:
Yusuke Horiguchi, Mieko Sano, Kenichiro Sato
Abstract: Disclosed are polymer resins, including polymer resin sheets, having good electroconductivity and a method for manufacturing the same. The polymer resins exhibit flexibility and show electroconductivity on their surface as well as along their thickness, and thus can be used as electromagnetic wave-shielding materials having impact- and vibration-absorbing properties as well as conductivity.
Type:
Grant
Filed:
January 29, 2015
Date of Patent:
May 10, 2016
Assignee:
3M Innovative Properties Company
Inventors:
Jeongwan Choi, Un Nyoung Sa, Won-Sik Kim
Abstract: The invention is related to the metal complexes of the general formula (1). The invention is related also to the use of metal complexes of the formula 1 as (pre)catalysts for the olefin metathesis reactions, as well as to the process for carrying out the olefin metathesis reaction.
Abstract: Provided are a sulfur-modified chloroprene rubber with reduced exothermicity, a molding thereof, and a production method therefor. A sulfur-modified chloroprene rubber modified at the polymer terminals with at least one compound selected from tetramethylthiuram disulfide, tetraalkylthiuram disulfides with alkyl groups having a carbon number of 2 to 7 and dialkyldithiocarbamic acid salts with alkyl groups having a carbon number of 1 to 7, wherein there are peak tops at 3.55 to 3.61 ppm and at 3.41 to 3.47 ppm in 1H-NMR spectrum, as determined in deuterochloroform solvent, wherein the ratio (A/B) of the peak area (A) at 3.55 to 3.61 ppm to the peak area (B) at 4.2 to 6.5 ppm is 0.05/100 to 0.50/100, and the extract with ethanol/toluene azeotropic mixture, as specified by JIS K 6229, is 3.0 to 9.0 mass %.
Abstract: A method of making a contact lens comprising the steps of reacting in a mold a polymerizable formulation comprising at least one fluorine-containing silicone monomer at least one non-fluorine-containing silicone monomer and at least one hydrophilic monomer to form a contact lens, subjecting the contact lens to one or more solvent extraction steps to remove impurities, oligomers and unreacted monomers and hydrate the contact lens, wherein all of the solvent extraction steps are undertaken using an aqueous solvent.
Type:
Grant
Filed:
May 15, 2015
Date of Patent:
April 26, 2016
Assignee:
CooperVision International Holding Company, LP
Abstract: Disclosed is a method of preparing terminally functionalized telechelic polymers using a cationic living polymer product or a terminal tert-chloride chain end of a carbocationic quasiliving polymer product, which comprises quenching the polymer product with a functionalized N-substituted pyrrole to thereby introduce the functionalized N-substituted pyrrole at the terminal reactive polymer chain end(s). A method is also disclosed whereby the N-substituent may be derivatized to a basic amine containing functional group. Also disclosed are the terminal functionalized polyisobuyl N-substituted pyrrole compounds where the polyisobutyl group is substituted at the 2 and 3 position of the N-substituted pyrrole.
Type:
Grant
Filed:
September 27, 2013
Date of Patent:
April 19, 2016
Assignees:
Chevron Oronite Company LLC, The University of Southern Mississippi
Inventors:
Robson F. Storey, Casey D. Stokes, James J. Harrison, Nemesio Martinez-Castro
Abstract: The invention provides novel polymer compositions and methods for preparing such compositions. The invention also provides methods for polymerizing various unsaturated monomers, including naturally occurring or plant biomass-derived renewable acrylic monomers. The monomers can be rapidly polymerized using various organic catalysts or organometallic catalysts, as described herein. In one embodiment, nearly perfectly isotactic polymers (mmmm>99%) can be prepared using a C2-symmetric zirconocenium catalyst.
Type:
Grant
Filed:
August 26, 2013
Date of Patent:
April 12, 2016
Assignee:
Colorado State University Research Foundation
Inventors:
Eugene Y. Chen, Yangjian Hu, Yuetao Zhang
Abstract: The present invention relates to a thickeners that are the polymerization product of a monomer mixture comprising: (a) at least one C3 to C30 olefin; (b) at least one monomer that contains at least one carboxylic acid group; (c) at least one ethylenically unsaturated ester monomer; and (d) one or more crosslinking compounds. Optionally, the above multi-purpose polymer compositions can further include any combination of one or more of: (e) at least one functional monomer; (f) at least one associative hydrophobic monomer; and/or (g) at least one chain transfer agent (CTA) and/or at least one polymeric stabilizer. The thickeners of the present invention are useful in a variety of products including, but not limited to, personal care products, health care products, household care products, institutional and industrial care products, and industrial applications.
Type:
Grant
Filed:
November 1, 2012
Date of Patent:
April 5, 2016
Assignee:
Lubrizol Advanced Materials, Inc.
Inventors:
Krishnan Tamareselvy, Robert J. Pafford, IV, Libin Du
Abstract: The present invention relates to a method for producing a cationic surface sizing agent, and contains a first step of obtaining a copolymer (A) by solution-polymerizing a monomer mixture which contains a monomer having a tertiary amino group (a) in the amount of 15 to 45% by weight, a (meth)acrylic acid ester (b) in the amount of 15 to 85% by weight, and styrenes (c) in the amount of 0 to 70% by weight in the presence of a chain transfer agent; a second step of obtaining a copolymer (B) by polymerizing the copolymer (A) and a nonionic hydrophilic monomer (d); a third step of obtaining a copolymer (C) by polymerizing the copolymer (B) and a hydrophobic monomer (e) in the absence of a surfactant; and a fourth step of obtaining a quaternary ammonium salt of the copolymer (C) by quaternizing a tertiary amino group present in the copolymer (C).
Abstract: Provided is an optical fiber which is provided with heat resistance and productivity and in which a transmission loss is suppressed even in a high-temperature environment. It has, on an outer periphery of a glass fiber composed of a core part and a cladding part, a coating layer made by crosslinking an energy-curable resin composition containing a silicon compound, in which the silicon compound contained in the energy-curable resin composition of the coating layer as an outermost layer has a specified structure having a cyclic silicone site having an epoxy group and a linear silicone site, with the content of the cyclic silicone site in the compound being from 10 to 30% by mass.
Type:
Grant
Filed:
May 10, 2012
Date of Patent:
March 29, 2016
Assignees:
SUMITOMO ELECTRIC INDUSTRIES, LTD., ADEKA CORPORATION
Abstract: The present invention relates to a method for the preparation of a controlled release system and especially to a method for entrapment of compounds in polymer carriers for controlled release of active ingredients, preferably bioactive ingredients, such as drugs. This method results in a system for controlled release of active ingredients and especially for controlled drug delivery. In accordance with the present invention, the term “controlled release” encompasses all kinds of controlled release, including slow release, sustained and delayed release. Particularly, the present invention results in active ingredients, entrapped in or otherwise incorporated in or coupled to polymer carriers or polymeric devices, such as micelles, nanoparticles, microspheres and other types of polymer devices for controlled release; the active ingredients are covalently bonded to the polymer carriers or polymeric devices.
Type:
Grant
Filed:
February 20, 2014
Date of Patent:
March 22, 2016
Assignee:
CRISTAL DELIVERY B.V.
Inventors:
Cristianne Johanna Ferdinand Rijcken, Wilhelmus Everhardus Hennink, Cornelis Franciscus Van Nostrum
Abstract: A polyether compound containing oxirane monomer units in an average number per molecule of 5 to 200, wherein the polyether compound has a cationic group and cross-linkable group in the oxirane monomer units, and a cross-linkable composition containing this polyether compound and a cross-linking agent which enables cross-linking of the cross-linkable groups of the polyether compound are provided.
Abstract: Provided is a thioepoxide functional polymerizable composition comprising a reaction product of thiourea and an epoxide functional, polymerizable composition. The epoxide functional, polymerizable composition comprises a reaction product prepared from a reaction mixture comprising: (a) a monomer comprising at least one ethylenically unsaturated ester functional monomer having an epoxide functional group; and (b) a compound having two or more thiol groups. The reactants (a) and (b) are reacted via a Michael addition reaction in the presence of a base to form an epoxide functional reaction product. Also provided are methods of preparing an optical article using the polymerizable compositions.
Abstract: Amphiphilic macromolecules having structural units to adjust molecular weight and molecular weight distribution and charging property effects, high stereo-hindrance structural units, and having amphiphilic structural units. The Amphiphilic macromolecules are suitable for fields such as oil field well drilling, well cementation fracturing, oil gathering and transfer, sewage treatment, sludge treatment and papermaking, etc., and can be used as an oil-displacing agent for enhanced oil production, a heavy oil viscosity reducer, a fracturing fluid, a clay stabilizing agent, a sewage treatment agent, a papermaking retention and drainage aid or a reinforcing agent, etc.
Abstract: Polymerizable resin compositions and microstructures comprising the reaction product of such polymerizable resin compositions are described. The microstructures comprise the reaction product of a polymerizable resin composition comprising an organic portion having a refractive index of at least 1.56 wherein the polymerizable resin composition comprises a fluorene-containing monomer.
Abstract: Amphiphilic macromolecules having repeating structural units: structural units to adjust molecular weight and molecular weight distribution and charging property effects, high stereo-hindrance structural units, and amphiphilic structural units, and are suitable for fields such as oil field well drilling, well cementation, fracturing, oil gathering and transfer, sewage treatment, sludge treatment and papermaking, etc., and can be used as an oil-displacing agent for enhanced oil production, a heavy oil viscosity reducer, a fracturing fluid, a clay stabilizing agent, a sewage treatment agent, a papermaking retention and drainage aid or a reinforcing agent, etc.
Abstract: Amphiphilic macromolecules having structural units to adjust molecular weight and molecular weight distribution and charging property effects, high stereo-hindrance structural units, and amphiphilic structural units, are suitable for fields such as oil field well drilling, well cementation fracturing, oil gathering and transfer, sewage treatment, sludge treatment and papermaking, etc., and can be used as an oil-displacing agent for enhanced oil production, a heavy oil viscosity reducer, a fracturing fluid, a clay stabilizing agent, a sewage treatment agent, a papermaking retention and drainage aid or a reinforcing agent, etc.
Abstract: Provided are an organic semiconductor compound, a method for preparing same, a polymer compound having the organic semiconductor compound of the present invention as a monomer, and an organic semiconductor device containing the polymer compound. Said organic semiconductor compound has side chains in the chemical structure thereof, and is highly soluble in a solvent, and therefore the organic semiconductor compound can be effectively used in solution-based processes. The organic semiconductor device containing the polymer compound according to the present invention yields high manufacturing efficiency.
Type:
Grant
Filed:
April 26, 2012
Date of Patent:
January 12, 2016
Inventors:
Sang Jin Moon, Jong Cheol Lee, Won Suk Shin, Sang Kyu Lee
Abstract: Presently described are methods of making coating comprising aqueous fluoropolymer latex dispersions, aqueous fluoropolymer coating compositions, coated substrates, and (e.g. backside) films of photovoltaic cells. In one embodiment, the film comprises at least one fluoropolymer comprising repeat units derived from VF, VDF, or a combination thereof; inorganic oxide nanoparticles; and a compound that reacts with the repeat units derived from VF and VDF to crosslink the fluoropolymer and/or couple the fluoropolymer to the inorganic oxide nanoparticles. In another embodiment, the backside film comprises at least one fluoropolymer comprising repeat units derived from VF, VDF, or a combination thereof; and an amino-substituted organosilane ester or ester equivalent crosslinking compound.
Type:
Grant
Filed:
November 14, 2012
Date of Patent:
December 29, 2015
Assignee:
3M Innovative Properties Company
Inventors:
Naiyong Jing, Mark W. Muggli, Larry S. Hebert, Kevin M. Hamer, Thomas J. Blong, Michael Juergens, George Van Dyke Tiers, Zhigang Yu, Yaming Wang, Yiwen Chu