Abstract: A method of treating fibers to improve resistance to high temperatures and relative humidity includes providing poly(p-phenylene-2,6-benzobisoxazole) (PBO) fibers, exposing the PBO fibers to an atmosphere of supercritical CO2 saturated with an epoxy silane, i.e. 3-glycidoxypropyl methyldimethoxysilane. The PBO fibers are subjected to a first pressurizing and heating stage at a first temperature (50° C.) for a first period of time. The PBO fibers are then subjected to a second pressurizing and heating stage including increasing the temperature to a second temperature (110° C.) and holding at the second temperature for an additional period of time. The PBO fibers include 2-5 wt % of 3-glycidoxypropyl methyldimethoxysilane after diffusing the CO2 out of the PBO fibers. The fibers are particularly useful in making lightweight body armor system components.
Type:
Grant
Filed:
April 11, 2013
Date of Patent:
March 8, 2016
Assignee:
Battelle Memorial Institute
Inventors:
Jay R Sayre, Vince McGinniss, C Byron Tolbert, Kelly J Jenkins, Jeffrey L Ellis, Tim B Hutson, Sundee Angel, Rachel Thurston
Abstract: The present invention is directed to self-assembled nanoparticle arrays, methods of making the nanoparticle arrays, and methods of using the nanoparticle arrays in spectroscopic methods for detecting targets of interest. The present invention is also directed to a fabrication method for surface-enhanced Raman scattering (SERS) substrates that possess a unique combination of three highly desirable attributes: (a) the SERS substrates can be tuned to match the laser wavelength of operation and maximize the enhancement factor for the particular Raman instrument and analyte in use; (b) the SERS substrates have a highly reproducible enhancement factor over macroscopic sampling areas; and (c) the fabrication method is achieved without resorting to expensive, slow nano-lithography tools.
Type:
Grant
Filed:
May 1, 2013
Date of Patent:
March 8, 2016
Assignee:
University of Maryland, College Park
Inventors:
Woonjoo Lee, Seung Yong Lee, Oded Rabin, Robert M. Briber, Xin Zhang
Abstract: A coating composition for application to a subsea component or structure has cellulose acetate an amount of approximately 47% by weight of the total composition, diisooctyl phthalate in an amount of approximately 17% by weight of the total composition, a fatty acid ester in an amount of approximately 23% by weight of the total composition, a vegetable oil in an amount of approximately 8% by weight of the total composition, a stabilizer and a silica amorphous in which the stabilizer and the silica amorphous are in amount of approximately 5% by weight of the total composition. The stabilizer can be either titanium dioxide or aluminum dioxide. The vegetable oil is canola oil.
Abstract: A method of treating a plurality of fines of a dusting material to prevent emanation of dust from the dusting material is described. An aqueous solution comprising a mixture of soluble non-ionic cellulose ether, a plasticizer, and a surfactant is provided. The aqueous solution is applied to a dusting material comprising a plurality of fines. The dusting material is transferred during the applying step from a first location to a second location as the aqueous solution is applied to the plurality of fines. The dusting material is mixed with the aqueous solution to coat the plurality of fines with the aqueous solution. The treated dusting material is accumulated into a mass of the material subsequent to the applying step wherein the aqueous solution is substantially evenly distributed throughout an interior portion of the mass of the treated dusting material.
Abstract: The present invention relates to a method for functionalizing a solid material surface with self assembling or self aggregating cyclodextrins, said method comprising the steps of: providing an adsorption solution comprising at least one modified cyclodextrins and at least one solvent; and contacting a solid material surface with the adsorption solution.
Type:
Grant
Filed:
April 20, 2011
Date of Patent:
February 16, 2016
Assignee:
Aalborg Universitet
Inventors:
Kim Lambertsen Larsen, Ronnie Nielsen, Karen Østergaard Styrbæk
Abstract: The present invention relates to a method of coating the surface of inorganic powder particles with a silicon-carbon composite and to inorganic powder particles coated by the method. More specifically, the invention relates to a method of coating the surface of inorganic powder particles with a silicon-carbon composite by mixing inorganic powder particles with a solid organic silicon polymer and heating the mixture, and to inorganic powder particles coated by the method.
Type:
Grant
Filed:
July 25, 2012
Date of Patent:
December 29, 2015
Assignee:
Research & Business Foundation Sungkyunkwan University
Inventors:
Young Dok Kim, Kwang Dae Kim, Myoung Geun Jung, Hyun Ook Seo, Dong Chan Lim, Chae Won Sim, Jong Won Nam, Dong Wun Kim
Abstract: Provided is a method for producing a good epoxy resin composition for obtaining fiber-reinforced plastics. A production method for obtaining a fiber-reinforced composite material by impregnating a fiber assembly with an epoxy resin composition and then curing the epoxy resin composition, wherein the epoxy resin composition contains a component [A], a component [B] and a component [C] respectively satisfying the conditions described below. When the blending amount of the component [B] is set to b parts by mass and the blending amount of the component [C] is set to c parts by mass relative to 100 parts by mass of the component [A] contained in the epoxy resin composition, formula (2) is satisfied within the range of formula (1), formula (4) is satisfied within the range of formula (3), and formula (6) is satisfied within the range of formula (5).
Abstract: A method and device for producing crystalline active ingredient particles. The active ingredient is crystallized from a supersaturated solution on the surface of particles of the active ingredient. A suspension of active ingredient particles is subjected to wet grinding in a supersaturated solution of the active ingredient in a first module. At least a part of the suspension is fed from the first module into the second module where it is cooled and simultaneously subjected to ultrasound. The suspension is fed back into the first module after cooling and being subjected to ultrasound. Active ingredient solution and optionally antisolvent are added to the suspension and active ingredient particles and liquid phase are extracted. A relative supersaturation of the active ingredient in the liquid phase of the suspension, relative to the entire liquid phase, is ?90%, and the extracted active ingredient particles comprise a mean particle size of 10-500 ?m.
Abstract: Surface treatment agent with high photocatalytic and sanitary effects based on TiO2 nanoparticles comprising 10 to 500 g of TiO2 nanoparticles per 1 liter of water, and binding ingredient A, which is an inorganic binder selected from the group comprising ZnO, MgO, CaO, Ca(OH)2, Mg(OH)2, CaCO3, MgCO3, Na2CO3, K2CO3 in the amount of 0.1 to 10% by weight related to the N weight of TiO2. Agent for treatment of surfaces for application on surfaces, which comprise a minimum of 50% of substances selected from the group formed by CaCO3, MgCO3 ZnO, MgO, CaO, Ca(OH)2, Mg(OH)2 or their mixtures, where the agent contains 10 to 500 g of TiO2 nanoparticles per 1 liter of water, and optionally contains a minimum of 0.1 wt % H2CO3 related to the weight of TiO2.
Abstract: A method for processing of granules, by forming at least one injection zone in a fluidized bed where a feed stream of seed particles is contacted or coated by a liquid product by simultaneous injection of the feed stream of the seed particles and a feed stream of the liquid product, forming at least one granulation zone in the fluidized bed where the contacted or coated seed particles may be at least one of dried, shaped, and cooled to form granules, extracting the granules from the at least one granulation zone and sorting the extracted granules into undersize granules, on-size granules, and oversize granules, passing the on-size granules to post-processing treatment, removing the oversize granules, and passing the undersize granules back into the feed stream of the seed particles, wherein the extracted granules are made to pass through at least one classifier located in the at least one granulation zone.
Type:
Grant
Filed:
April 28, 2009
Date of Patent:
December 1, 2015
Assignee:
YARA INTERNATIONAL ASA
Inventors:
Francois Ledoux, Luc Vanmarcke, Howard Volke, Peter de Bakker, Remco de Fouw, Roeland Elderson
Abstract: The present invention relates to multi-phase self-stratifying coating systems, and in particular, to multi-phase self-stratifying coating systems having a substantially homogeneous composition of polymeric binder components that upon application and cure generates a multi-phase stratified coating wherein each phase is rich in a different polymeric binder component and wherein individual phases are separated by a diffuse interface, such that the stratified coating exhibits a gradient behavior wherein a given interface exhibits the attributes of the polymeric binder component that is rich at that interface, and wherein at least one phase is rich in a polymeric binder having a telechelic resin with reactive internal groups, reactive end groups, and an alkoxide oligomer, and at least one other phase is rich in a polymeric binder having a fluorinated polymer derived from fluorinated vinyl-based monomers.
Abstract: A method for producing a substrate having dispersed particles of a dendrimer compound on the surface thereof, the method including: an application step including dissolving a phenyl azomethine dendrimer compound in a solvent to prepare a solution, and applying the solution on the surface of a substrate; and a volatilization step including volatilizing the solvent from the solution applied on the surface of the substrate, the phenyl azomethine dendrimer compound included in the solution having a concentration of no greater than 5 ?mol/L is employed.
Type:
Grant
Filed:
August 6, 2012
Date of Patent:
November 24, 2015
Assignees:
TOKYO OHKA KOGYO CO., LTD., TOKYO INSTITUTE OF TECHNOLOGY
Abstract: Reactive nanocomposites comprising a metal nanoparticle functionalized with one or more layers of self-assembled protein cages and methods of making the same. The reactive nanocomposites according to the present invention demonstrate improved reaction kinetics and enhanced exothermic behavior.
Type:
Grant
Filed:
December 28, 2012
Date of Patent:
November 17, 2015
Assignee:
THE UNITED STATES OF AMERICA AS REPRESENTED BY THE SECRETARY OF THE AIR FORCE
Inventors:
Joseph M Slocik, Christopher A Krouse, Rajesh R Naik
Abstract: A method of fabricating a cathodic portion of a field emission display includes the steps of producing an array of substantially parallel carbon nanotubes attached at one end to a substantially planar substrate. Then, embedding the nanotubes in a polymer matrix that extends to a plane of attachment of the nanotubes to the planar substrate, wherein the polymer matrix allows an end of the nanotubes distal from the ends attached to the planar substrate, uncovered by the polymer matrix in order to allow electrical contact with each other and with an attached conductor. Next, detaching the array from the planar substrate, thus producing a surface having the formerly attached ends of the nanotubes substantially in a plane, and then attaching the conductor to the array of nanotube ends, uncovered by the polymer matrix and distal to the plane.
Abstract: The invention relates to a method for preparing sols of metal oxides, with an aqueous component, which are stable over time and which notably allow the making of thin films having both remarkable optical and abrasion resistance properties. This method comprises: (i) replacing with water all or part of the alcohol or of the alcohols present in an alcoholic sol of a metal oxide, with a neutral or basic pH, and optionally (ii) adjusting the pH of the thereby obtained aqueous or partly aqueous sol to a value of at least 8. The invention also relates to a method for making films from these sols and, in particular, thin films with optical properties and resistant to abrasion. Applications: making optical components for power lasers, making optical fibers, cathodic tubes, etc.
Type:
Grant
Filed:
November 24, 2011
Date of Patent:
October 13, 2015
Assignee:
COMMISSARIAT À L'ÉNERGIE ATOMIQUE ET AUX ÉNERGIES ALTERNATIVES
Inventors:
Philippe Belleville, Philippe Prene, Xavier Le Guevel
Abstract: Processes for producing polycrystalline silicon by thermal decomposition of dichlorosilane are disclosed. The processes generally involve thermal decomposition of dichlorosilane in a fluidized bed reactor operated at reaction conditions that result in a high rate of productivity relative to conventional production processes.
Abstract: A method for preparing a plurality of coated binder units wherein each of the coated binder units comprises a core of a binder coated with a layer of coating material, which method comprises the steps of: (a) providing a coated binder which comprises a core of a binder coated with a layer of coating material; and (b) dividing the coated binder into the plurality of the coated binder units by means of a system which comprises a first and a second loop that engage over part of their lengths and rotate in opposite directions, the first loop comprising a first repeating sequence of interlinked molds and the second loop comprising a second repeating sequence of interlinked molds, whereby the coated binder units are formed by welding edges of the coating and cutting the extrudate into pieces in a region where the first and the second loops engage. The invention further relates to said system.
Type:
Grant
Filed:
December 2, 2010
Date of Patent:
October 13, 2015
Assignee:
Shell Oil Company
Inventors:
João Miguel De Amorim Novais Da Costa Nóbrega, Eurico Filipe Dias Pessoa, José António Colaço Gomes Covas, Sophie Nigen-Chaidron
Abstract: A block copolymer film having a line pattern with a high degree of long-range order is formed by a method that includes forming a block copolymer film on a substrate surface with parallel facets, and annealing the block copolymer film to form an annealed block copolymer film having linear microdomains parallel to the substrate surface and orthogonal to the parallel facets of the substrate. The line-patterned block copolymer films are useful for the fabrication of magnetic storage media, polarizing devices, and arrays of nanowires.
Type:
Grant
Filed:
May 25, 2012
Date of Patent:
October 13, 2015
Assignees:
THE UNIVERSITY OF MASSACHUSETTS, THE REGENTS OF THE UNIVERSITY OF CALIFORNIA, UNIST ACADEMY-INDUSTRY RESEARCH CORPORATION
Inventors:
Thomas P. Russell, Sung Woo Hong, Doug Hyun Lee, Soojin Park, Ting Xu
Abstract: Provided herein are methods and materials for the production of hydrophobic coatings, which may be thermally treated to produce binary hydrophobic-hydrophilic regions.
Type:
Grant
Filed:
July 15, 2013
Date of Patent:
September 22, 2015
Assignee:
THE BOARD OF TRUSTEES OF THE UNIVERSITY OF ILLINOIS
Inventors:
Constantine M. Megaridis, Thomas M. Schutzius, Ilker S. Bayer
Abstract: Disclosed are coating material compositions comprising at least one polyhydroxyl group-containing compound (A), at least one polyisocyanate group-containing compound (B) having free and/or blocked isocyanate groups, at least one catalyst (D) based on a zinc-amidine complex which comprises the reaction product of 1.0 moles of at least one zinc(II) biscarboxylate with more than 2.0 moles of at least one amidine where R5=hydrogen and R1, R2, R3, and R4 are each identical or different radicals, R1 and R3 being hydrogen or an alkyl radical or an aryl radical, and R2 and R4 being an alkyl radical or an aryl radical, and at least one monomeric aromatic, optionally substituted carboxylic acid (S) whose carboxyl group is in conjugation with a ?-electron system.
Type:
Grant
Filed:
January 30, 2012
Date of Patent:
September 22, 2015
Assignee:
BASF Coatings GmbH
Inventors:
Elke Westhoff, Peter Hoffmann, Bernadette Moeller, Benedikt Schnier