Patents Examined by Floyd D. Nigel
  • Patent number: 4992558
    Abstract: Novel disperse dyes particularly suitable for dyeing textile material made of polyester fibers, said dyes being of the formula ##STR1## wherein X is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or halogen,Y is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkoxy-C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy-C.sub.1 -C.sub.4 alkoxy,R is hydrogen, C.sub.1 -C.sub.12 alkyl, C.sub.2 -C.sub.12 alkenyl or phenyl, or Y and R, when taken together with the nitrogen atom and the two carbon atoms linking them, form a 5- or 6-membered ring,B is straight-chain or branched C.sub.2 -C.sub.6 alkylene,A is a radical of formula ##STR2## in which W is C.sub.1 -C.sub.9 alkyl, C.sub.5 -C.sub.7 cycloalkyl, phenyl, halogen or C.sub.1 -C.sub.4 alkoxy,n is 0, 1, 2, or 3,Q is hydrogen or C.sub.1 -C.sub.4 alkyl,V is halogen, andm is 0, 1, 2, 3 or 4.
    Type: Grant
    Filed: July 7, 1989
    Date of Patent: February 12, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Peter Liechti, Antoine Clement
  • Patent number: 4963659
    Abstract: Reactive dyes which are particularly suitable for the dyeing or printing of cellulose-containing fiber materials by the exhaust process or by the continuous process and give, at a high color yield, dyeings and prints having good fastness properties, having the formula ##STR1## in which D.sub.1 and D.sub.2, independently of one another, are each a radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide dye; R.sub.1, R.sub.2, B.sub.1 and B.sub.2, independently of one another, are hydrogen or alkyl having 1 to 4 carbon atoms, which is unsubstituted or substituted by halogen, hydroxyl, cyano, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkoxycarbonyl, carboxyl, sulfamoyl, sulfo or sulfato; X is fluorine, chlorine, bromine, sulfo, C.sub.1 -C.sub.
    Type: Grant
    Filed: March 14, 1989
    Date of Patent: October 16, 1990
    Assignee: Ciba-Geigy Corporation
    Inventor: Athanassios Tzikas
  • Patent number: 4929720
    Abstract: Isothiazole dyes of the formula ##STR1## where X is substituted or unsubstituted C.sub.1 -C.sub.8 -alkyl or substituted or unsubstituted phenyl,Y is hydrogen, cyano, chlorine or bromine,R.sup.1 is hydrogen, C.sub.1 -C.sub.4 -alkyl or phenyl,R.sup.2 is hydrogen, cyano, carbamoyl, C.sub.1 -C.sub.4 -monoalkyl- or -dialkyl-carbamoyl, C.sub.1 -C.sub.6 -alkanoyl, C.sub.1 -C.sub.6 -alkoxycarbonyl or 2-(C.sub.1 -C.sub.4 -alkoxy)-ethoxycarbonyl andR.sup.3 is hydrogen, C.sub.1 -C.sub.8 -alkyl which may be substituted and/or interrupted by one or two oxygen atoms, or is C.sub.5 -C.sub.7 -cycloalkyl, C.sub.3 -C.sub.6 -alkenyl or phenyl, are useful for dyeing synthetic fibers.
    Type: Grant
    Filed: November 10, 1988
    Date of Patent: May 29, 1990
    Assignee: Basf Aktiengesellschaft
    Inventors: Guenter Hansen, Ernst Schefczik, Helmut Reichelt
  • Patent number: 4929721
    Abstract: Compounds of the formula: ##STR1## wherein Q is a polymerizable olefin substituent;Ar is an aromatic moiety;C.sup..alpha. is the .alpha. carbon;R.sup.1 and R.sup.2 are independently hydrogen or aliphatic groups; andZ is a halogen, oxygen-containing, nitrogen-containing or sulfur-containing substituent complying with one of the formulae: --X, --OR, --SR or --NR.sub.2, wherein X is a halogen and each R is independently a hydrogen atom or an aliphatic moiety;contain azo groups which are stable with respect to thermal decomposition at high temperature (180.degree. to 240.degree. C. and beyond) in the absence of moderate light, so that such compounds may be polymerized and processed at ordinary polystyrene process temperatures. However, the azo group in those compounds or in polymers made from them decomposes to initiate free radical polymerization at temperature of 100.degree. C. to 120.degree. C. or less in the presence of moderate light.
    Type: Grant
    Filed: June 29, 1988
    Date of Patent: May 29, 1990
    Assignee: The Dow Chemical Company
    Inventors: Richard A. Wolf, Paul V. Grosso
  • Patent number: 4923970
    Abstract: A substituted 1-(2-chloroethyl)-3-acyl-3-alkyltriazene of the formula: ##STR1## in which R.sub.1 is 1-oxoalkyl containing from two to eight carbon atoms, fluorinated 1-oxoalkyls containing from two to eight carbon atoms and substituted with up to three fluorine atoms, benzoyl, phenylacetyl, carboalkoxy containing from two to eight carbon atoms, fluorinated carboalkyl containing from two to eight carbon atoms and up to three fluorine atoms, carbophenoxy, N-phenyl aminocarbonyl, N-alkyl aminocarbonyl containing from two to eight carbon atoms, thiocarbamoyl, N-alkylthiocarbamoyls with from two to eight carbon atoms, N-phenylthiocarbamoyl, dialkylphosphonates in which the alkyl groups can be the same or different and each contains from one to seven carbon atoms, phenylsulfonyl, and meta or para-substituted phenylsulfonyl in which the meta or para substituent is methyl, ethyl, methoxy, ethoxy, fluoro and chloro; and R.sub.
    Type: Grant
    Filed: March 28, 1988
    Date of Patent: May 8, 1990
    Assignee: Bionetics Research, Inc.
    Inventors: Christopher J. Michejda, Richard H. Smith, Jr.
  • Patent number: 4904767
    Abstract: Asymmetric 1:2-chrome complex dyes of the formula: ##STR1## wherein A is the radical of 1-hydroxynaphthalene or 2-hydroxynaphthalene,R.sub.1 is hydrogen, chlorine or methyl,R.sub.2 is hydrogen, nitro or chlorine, andKa.sup.+ is a cation, and of the substituents X.sub.1, X.sub.2 and X.sub.3 one is an SO.sub.3 group, and the other two are hydrogen, X.sub.3 being hydrogen when R.sub.1 is chlorine and R.sub.2 is hydrogen,give blue shades on leather and other polyamides, which shades are lightfast and fast to wet processing.
    Type: Grant
    Filed: June 29, 1987
    Date of Patent: February 27, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Fabio Beffa, Alois Puntener, Peter Loew
  • Patent number: 4876347
    Abstract: Methine dyes (I) which conform in one of their tautomeric forms to the general formula ##STR1## where Y.sup.1 is in both or either case an electron-attracting group and the other Y.sup.1 is hydrogen,Y.sup.2 is in each case, independently of the others, hydrogen, --CN, halogen, C.sub.1 -C.sub.6 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, phenyl, pyridyl or together with a further Y.sup.2 a five- or six-membered ring which may have a fused-on benzene ring,R is hydrogen, C.sub.1 -C.sub.20 -alkyl, C.sub.7 -C.sub.10 -aralkyl or .beta.
    Type: Grant
    Filed: March 24, 1988
    Date of Patent: October 24, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Ewald Daltrozzo, Werner Sulger
  • Patent number: 4861765
    Abstract: A 21-substituted thiosteroid represented by the general formula ##STR1## wherein R.sup.1 represents an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 5 or 6 carbon atoms, a phenyl group, or a benzyl group which may have a substituent on the benzene ring,R.sup.2 represents an alkanoyl group having 2 to 6 carbon atoms,R.sup.3 represents a hydrogen atom or a methyl group,X represents a hydrogen or halogen atom, andthe dotted line between 1- and 2-positions represents an optional bond. These compounds are useful an anti-inflammatory agents.
    Type: Grant
    Filed: June 23, 1986
    Date of Patent: August 29, 1989
    Assignee: Jouveinal
    Inventors: Morihiro Mitsukuchi, Tomoyuki Ikemoto, Yoshiaki Watanabe, Kaoru Sota
  • Patent number: 4859796
    Abstract: The present invention relates to a process for the preparation of an N-dialkylaminoalkyl(meth)acrylamide of formula: ##STR1## in which: R.sub.1 is a methyl radical or a hydrogen atom,R.sub.2 is a straight-chain or branched alkyl group containing at most 10 carbon atomsR.sub.3 and R.sub.4, which are identical or different, may be:either two aliphatic alkyl groups containing from 1 to 4 carbon atoms,or R.sub.3 is an aliphatic alkyl group containing from 1 to 4 carbon atoms and R.sub.4 is an alicyclic group containing from 5 to 6 carbon atoms,or R.sub.3 and R.sub.4 are two alicyclic groups containing from 5 to 6 carbon atoms,or R.sub.3 and R.sub.4 form, together with the nitrogen atom to which they are chemically linked, a heterocycloaliphatic group.This process is characterized in that a (meth)acrylic anhydride of formula: ##STR2## is reacted with a diamine of formula: ##STR3## in the presence of a polymerization inhibitor.
    Type: Grant
    Filed: November 26, 1986
    Date of Patent: August 22, 1989
    Assignee: Norsolor
    Inventors: Patrice Hurtel, Denis Laurent
  • Patent number: 4841031
    Abstract: A novel reactive monoazo dye, capable of giving cellulose fiber materials a deep orange to scarlet color and superior in build-up and chlorine fastness properties, represented by a free acid of the formula, ##STR1## wherein R.sub.1 is hydrogen, methyl or ethyl; R.sub.2 is an alkyl having 1 to 4 carbons that is either unsubstituted or substituted with hydroxy, cyano, alkoxy, halogen, carboxy, alkoxycarbonyl or sulfonic acid; Z is hydrogen or sulfonic acid; A is phenylene and is either unsubstituted or substituted with 1 or 2 substituents selected from the group consisting of methyl, ethyl, methoxy, ethoxy, chlorine, bromine and sulfonic acid, or natphthylene that is either unsubstituted or substituted with sulfonic acid; X is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Y in which Y is a group that is splittable by alkalis; and m is an integer of 1 to 3.
    Type: Grant
    Filed: September 7, 1984
    Date of Patent: June 20, 1989
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Yutaka Kayane, Katsumasa Otake, Yasuo Tezuka
  • Patent number: 4237048
    Abstract: Azo dyestuff having the formula ##STR1## in which A is an aromatic carbocyclic radical containing a CN substituent in the o-position to the azo group and K is the radical of a coupling component as well as the process for their production are disclosed. The process involves cyano exchange between a metal cyanide, e.g. CuCN and the corresponding dyestuff containing Cl or Br instead of CN, in an organic solvent particularly polar aprotic organic solvents, e.g. dimethyl sulfoxide. The dyestuffs are suitable for dyeing a variety of fiber material such as cotton, wool, silk as well as synthetic materials such as polyamide and polyethylene terephthalate to give dyeings which are characterized by great clearness and good general fastness properties.
    Type: Grant
    Filed: January 15, 1976
    Date of Patent: December 2, 1980
    Assignee: Bayer Aktiengesellschaft
    Inventors: Alois Gottschlich, Klaus Leverenz