Abstract: A chromium salt such as ammonium chromate or ammonium dichromate, which is normally insoluble in nonaqueous solvents which do not easily rehydrate the silica surface is solubilized, for instance by treating it with a crown ether, and impregnated onto a particulate support from a nonaqueous solvent which does not easily rehydrate the silica. The resulting composition is then activated in an oxygen ambient such as air in a conventional manner and then utilized as a catalyst for polymerization reactions such as the production of polyolefins.

Abstract: Gas streams containing SO.sub.x and/or NO.sub.x compounds are treated in an absorption-regeneration process for removal of the SO.sub.x and/or NO.sub.x compounds. The process in one embodiment removes SO.sub.x compounds from a stack gas or other feed gas stream by (1) absorbing the SO.sub.x into a novel aqueous liquid absorbent comprising formic acid and an alkanolamine containing a tertiary amine functional group and (2) regenerating the absorbent when spent by subjecting the spent absorbent to an elevated temperature above that utilized for absorption of said SO.sub.x, said elevated temperature being sufficient to convert a substantial proportion of the dissolved SO.sub.x to elemental sulfur and/or H.sub.2 S. If NO.sub.x compounds are present in the stack gas stream, they may also be removed, NO.sub.2 being removed without modification of the process for removing SO.sub.

Abstract: Multi-purpose in-line direct heat treating equipment for hot-rolled steel wire rod has, in combination, a front stage transport conveyor portion and a holding furnace both positioned on a front traveling skid carriage, a quenching tank and a holding tank both positioned on a rear traveling skid carriage, each of the traveling skid carriages being able to travel in direction transverse to the direction of conveying of the hot-rolled steel wire rod emerging from a hot rolling mill for the purpose of direct heat treating the wire rod by taking advantage of the heat retained in the wire rod.

Abstract: The process and apparatus described seeks to prevent NO.sub.x emissions after an emergency shutdown in a process for manufacturing nitric acid by catalytic combustion of ammonia, compression of the nitrous combustion gases and subsequent absorption. Immediately on shutdown the intake nitrous gas supply to the compressor is interrupted, the residual intake side nitrous gases are conveyed to the delivery side, the delivery side gas volume is shut off, the gas on the delivery side is expanded to the intake side and then exhausted into a vacuum system. Subsequently the acid charged with NO.sub.x in the absorption stages is drawn off, degassed acid is circulated through the absorption stages until equilibrium is established, the pressure of the shutoff section is released and cooled acid is admitted to the absorption stages.

Abstract: Zirconium is selectively precipitated from aqueous solutions containing zirconium and uranium by treatment with a precipitant consisting of tartaric acid or a tartrate.

Abstract: An apparatus and method for removing used refractory lining or slag or both from the inner wall of an elongated vessel. The apparatus includes a cutting disc movably mounted on a guide mechanism which may be fixably located within the vessel. In accordance with the inventive technique, one or more recesses is formed within the lining extending from the surface thereof to the wall of the vessel.

Abstract: A process for the selective reduction of nitrogen oxide in a combustion effluent gas stream is disclosed wherein the gas stream is contacted with sulfur at a temperature of about 445.degree. C. to 2000.degree. C., therein converting the NO to N.sub.2 and the sulfur to SO.sub.2.

Abstract: A process for removing sulfur dioxide from an off-gas and converting it to elemental sulfur wherein steam is introduced into a sulfur dioxide-containing off-gas, and the composite is passed through a reactor containing a mixture of fresh and recycled coal.

Abstract: The chlorides of elements of Groups III, IV and V of the Periodic Table, such as, boron trichloride, silicon tetrachloride, zirconium tetrachloride and vanadium tetrachloride are prepared by heating activated carbon particles having a supported aqueous solution of compounds of the elements of Groups III, IV and V of the Periodic Table thereon at a temperature of from 300.degree. through 1000.degree. C. and, then, reacting the resultant activated carbon particles with chlorine.

Abstract: A method for making water-soluble potassium formate substantially free of water-insoluble salts selectively and in high yield at temperatures at or below about 100.degree. C., includes contacting potassium sulfate, potassium carbonate or a mixture of potassium and sodium carbonate and potassium and sodium sulfate with calcium formate, forming water-soluble potassium formate and water-insoluble calcium sulfate, calcium carbonate, or mixtures thereof, thus permitting recovery of substantially potassium-free calcium sulfate, calcium carbonate or both, and substantially calcium sulfate-free calcium carbonate-free potassium formate from the aqueous media.

Abstract: Nitrous oxide can be produced by reacting nitric oxide and carbon monoxide in the presence of a catalyst in an anhydrous system. The preferred catalyst is a mixture of PdCl.sub.2, CuCl.sub.2 and LiCl, which is dissolved in anhydrous methanol.

Abstract: A method for removing nitric oxide from gas streams containing same. The nitric acid is removed by contacting the nitric oxide with elemental iron in the presence of water. The nitric oxide is believed to be reduced to nitrogen gas. The method has particular applications to removal of nitric oxide from gas streams produced during combustion of carbonaceous materials.

Abstract: A hydrogen sulfide removal and conversion method in which a hydrogen sulfide-containing gas stream is contacted with a regenerable washing solution containing solubilized vanadium thiocyanate ions, a carboxylate complexing agent and one or more water-soluble quinones capable of solubilizing tetravalent vanadium. The molar ratio of vanadium to quinone(s) in the washing solution is selected to substantially reduce or eliminate the formation of contaminant sulfate salts. The absorbed hydrogen sulfide is converted to elemental sulfur which, after oxidative regeneration of the washing solution, is separated from the regenerated solution.

Abstract: Method of reducing NO.sub.x in fuel rich combustion effluents is provided comprising introducing urea at temperatures in excess of about 1900.degree. F. in the presence of excess fuel, wherein said urea is introduced either as a solid or solution in amounts sufficient to reduce the NO.sub.x concentration.

Abstract: A pre-heating assembly to be used for pre-heating ingots being transported to a melting furnace, which includes an inner cylinder constituting a main passage for exhaust gas discharged from a flue of the melting furnace, an outer cylinder which is positioned around the inner cylinder to leave a subsidiary passage for the exhaust gas between the two cylinders, an ingot supplying passage spirally provided along the outermost circumference of the inner cylinder, in which the ingots, each having a spherical configuration like a ball, roll down the passage in succession so that each ingot is pre-heated prior to its introduction into the melting furnace, and a connector support member, on which both cylinders are mounted and the bottom portion of the connector support member is coupled to the outlet of the flue.

Abstract: A tellurium component is separated from a tellurium-antimony-containing metal oxide catalyst by heating the catalyst at a temperature of about 900.degree. C. to about 1,000.degree. C. in a non-reducing atmosphere.

Abstract: Boron and calcium are removed from brines with use of a mixture of from about 0.8 to 15 volume percent of an .alpha.-hydroxy oxime extractant having the general formula: ##STR1## where R and R' are hydrocarbon radicals and R" is hydrogen or a hydrocarbon radical, from 0 to 10 volume percent of a 7 to 12 carbon alcohol, balance diluent.

Abstract: A rectangular-solid packaged catalyst assembly made up of a plurality of rectangular-solid unit catalysts stacked and assembled together, the unit catalysts having a honeycomb structure with a multiplicity of gas passages each. Heat-resistant packings are used to cover at least the vertices and the neighboring areas of the faces of the unit catalysts other than the gas-passage faces and also to cover the edges of the gas-passage faces surrounding the gas passages, the packings being integrally secured to the unit catalysts and packaged together in a rectangular-solid housing. Retaining strips are placed over the packings on the edges of the gas-passage faces on at least either the gas inlet or outlet ends of the unit catalysts and are securely attached to the housing.

Abstract: Novel sorbents comprising (a) an alumina component comprising alumina of the surface area of at least 20 and preferably 100 square meters per gram, and (b) a salt, or mixtures of salts, of an alkali or alkaline earth metal, especially oxides, hydroxides, carbonates, nitrates, acetates or aluminates of sodium and potassium, are outstandingly effective for the removal of nitrogen oxides and sulfur oxides from waste gas streams.

Abstract: A process for fabricating aluminum nitride needles, the process utilizing moderate furnace temperatures (950.degree. C.-1000.degree. C.) and low toxicity reactants (i.e. NH.sub.3 and Al). Argon gas and ammonia gas are mixed and flowed over the heated aluminum and the aluminum nitride needles grow at the upstream end of the hot zone of the furnace.