Patents Examined by Hubert C. Lorin
  • Patent number: 5032338
    Abstract: A method to prepare high strength high modulus polyolefin shaped articles comprising forming a heated solution of the polyolefin from particles of which about 75 to 100% by weight have a particle size of from about 100 to about 400 microns and having a weight average molecular weight of from about 300,000 to 7,000,000, then shaping the heated soltion then cooling the shaped solution. To further increase the strength of the article it can be stretched.
    Type: Grant
    Filed: May 22, 1989
    Date of Patent: July 16, 1991
    Assignee: Allied-Signal Inc.
    Inventors: Gene C. Weedon, Thomas Y. Tam, Jim C. Sun
  • Patent number: 5032326
    Abstract: An improved process for flash-spinning plexifilamentary film-fibril strands is provided. A 5 to 30 and preferably 10 to 20 percent solution of polymer, preferably linear polyethylene, is formed in a spin fluid that consists essentially of 50 to 90 weight percent methylene chloride and 10 to 50 percent of a halocarbon, which preferably is chlorodifluoromethane, 1,1,1,2-tetrafluoroethane, 1,1-difluoroethane, 1,1,1,2-tetrafluoro-2-chloroethane or 1,1-difluoro-1-chloroethane. The solution is then flash-spun to form high quality plexifilamentary strands. The process avoids the use of halocarbon solvents that could be ozone-depletion hazards.
    Type: Grant
    Filed: July 14, 1989
    Date of Patent: July 16, 1991
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Hyunkook Shin
  • Patent number: 5028369
    Abstract: A process for the discontinuous or (preferably) continuous production of dry spun hydrophilic acrylic fibers and threads with a core/sheath structure which have improved color fastness properties, more uniform cross-sections and better processing characteristics. By employing a new after-treatment combination of more intensive counterflow washing, stretching in steam, fixing in steam and careful drying of the fibers as staple fibers, improved hydrophilic fibers with a water retention capacity above 30% can be obtained from spinning solutions which have a much lower non-solvent content than is necessary in the present-state of the art for obtaining a high water retention capacity of the order indicated above.
    Type: Grant
    Filed: September 20, 1989
    Date of Patent: July 2, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Ulrich Reinehr, Gunter Turck, Egon Kunzel, Dieter Paulini, Dieter Heinkes
  • Patent number: 5024797
    Abstract: Processes for the production of mono- and multifilaments and also staple fibers of multifilaments based on polyarylene sulfides by melt spinning, multistage stretching and setting. As a result of the treatment by blowing of air onto the stabilized spun filaments in the first stretching stages at temperatures .ltoreq.100.degree. C., the chain molecules are oriented; the orientation and crystallinity required for high strengths is achieved by afterstretching at elevated temperature. The residence times in the first stage required for effective stretching can only be varied within relatively narrow limits in order subsequently to achieve the calculated orientations and effects. Overly long residence times at temperatures above 100.degree. C. result in elongation of the material with no additional orientation and hence with an inadequate increase in strength.
    Type: Grant
    Filed: May 11, 1990
    Date of Patent: June 18, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wolfgang Anderheggen, Michael Kraemer, Roland Vogelsgesang, Wolfram Wagner, Wolfgang Olges, Thomas Dragovic
  • Patent number: 5023231
    Abstract: A method for preparing a superconductive fiber or film of improved critical current density. The method involves spinning an aqueous solution optionally containing a mixture of metal salts corresponding to the superconductive YBa.sub.2 Cu.sub.3 O.sub.x and a water soluble polymer. This method produces a more dense superconductive material upon firing.
    Type: Grant
    Filed: February 15, 1989
    Date of Patent: June 11, 1991
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Che-Hsiung Hsu
  • Patent number: 5023034
    Abstract: The invention is a process for the production of solid aromatic polyamic acid and polyimide fibers from a wet gel or coagulation bath wet get using N,N-dimethylacetamide (DMAc) solutions of the polyamic acid derived from aromatic dianhydrides such as 3,3',4,4'-benzophenonetetracarboxylic dianhydride (BTDA) and aromatic diamines such as 4,4'-oxydianiline (4,4'-ODA). By utilizing the interrelationship between coagulation medium and concentration, resin inherent viscosity, resin % solids, filament diameter, and fiber void content, it is possible to make improved polyamic acid fibers. Solid polyimide fibers, obtained by the thermal cyclization of the polyamic acid precursor, have increased tensile properties compared to fibers containing macropores from the same resin system.
    Type: Grant
    Filed: June 26, 1990
    Date of Patent: June 11, 1991
    Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: William E. Dorogy, Jr., Anne K. St. Clair
  • Patent number: 5023037
    Abstract: Blocks with a casing composed of upper and lower parts are produced by inserting the upper and lower parts in an inserting device above and below pushing elements between upper and lower pressing dies of a press, displacing by the pushing elements the lower part in a chamber of a mold towards the lower pressing die and the upper part towards the upper pressing die with self-releasable holding on the latter, withdrawing the inserting device from a pressing region between the upper and lower pressing dies, and cyclically repeating these steps in synchronism with a working stroke of the press.
    Type: Grant
    Filed: April 17, 1989
    Date of Patent: June 11, 1991
    Assignee: Bucher-Guyer AG Maschinenfabrik
    Inventor: Heinz Zullig
  • Patent number: 5023025
    Abstract: An improved process is provided for flash-spinning plexifilamentary film-fibril strands of fiber-forming polyolefin from a small group halocarbon liquids that, if released to the atmosphere, present a greatly reduced ozone depletion hazard, as compared to the halocarbon currently-used commercially for making the strands. The preferred halocarbon for this purpose is 1,1-dichloro-2,2,2-trifluoroethane.
    Type: Grant
    Filed: February 27, 1990
    Date of Patent: June 11, 1991
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Hyunkook Shin
  • Patent number: 5023035
    Abstract: A process is disclosed for preparing high tenacity, high modulus, para-aramid fibers by application of cyclic tensioning forces to such fibers in the newly-spun, wet, state before they have been dried.
    Type: Grant
    Filed: February 21, 1989
    Date of Patent: June 11, 1991
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Hung H. Yang
  • Patent number: 5019316
    Abstract: A system for producing a drawn yarn having a durable mechanical and thermal stability in practical use from a fiber-forming polymer by means of a single continuous process is disclosed. A yarn extruded from a spinneret is first introduced into a liquid bath for cooling and subsequently to a hot chamber filled with a pressurized steam for heat-treatment, in which the yarn is drawn against a resistance caused by the liquid bath. The vessel of the liquid bath is provided with a yarn exit path adapted to allow the passage of the yarn but inhibit the leakage of the liquid and to remove a concomitant liquid from the yarn. The hot chamber is provided with inlet and outlet paths for the yarn also adapted to allow the passage of the yarn but inhibit the leakage of the steam. The system is suitable for producing for industrial use a yarn composed of thicker individual filaments.
    Type: Grant
    Filed: July 24, 1989
    Date of Patent: May 28, 1991
    Assignee: Toray Industries, Inc.
    Inventors: Kunihiko Ueda, Katsumi Hasegawa, Nobuyuki Kuriyama
  • Patent number: 5015428
    Abstract: A process for dry spinning of synthetic polymers, in particular PAN threads containing more than 85 wt. % acrylonitrile in the PAN (co)polymer, with high spinning chimney capacities of at least 20 kg PAN solid per spinning chimney and hour, using superheated steam as the spinning gas and with in-chimney finishing with water or aqueous finishes.
    Type: Grant
    Filed: September 18, 1989
    Date of Patent: May 14, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Ulrich Reinehr, Gunter Turck, Rolf B. Hirsch, Hermann-Josef Jungverdorben
  • Patent number: 5013506
    Abstract: Melt-spun polyester fibers are taken up in the absence of heat at a speed of 5,000 to 6,000 m/min under conditions that satisfy the following relations (IX) and (X), subsequently heat-treating the fibers for a period of from 0.01 to 0.05 seconds with a heating roller while the length of the melt-spun fibers is held constant with no drawing step being provided between the taking up and heat treatment steps, and finally winding up the heated fibers0.04.ltoreq.L/(SSxd).ltoreq.0.08 (IX)1.0.ltoreq.To.ltoreq.1.5 (X)where L is the distance (cm) between the spinneret and the convergence point, SS is the speed (m/min) of a take up roller, To is the spinning tension (g/d) at a point immediately after the convergence point and D is the filament fineness (d) of the fiber wound up and is within the range of from 1 to 3 d.
    Type: Grant
    Filed: July 25, 1989
    Date of Patent: May 7, 1991
    Assignee: Unitika Ltd.
    Inventors: Shigemitsu Murase, Kouji Kakumoto, Shouji Miyazaki, Masaru Sugawa, Mikio Ide
  • Patent number: 5013516
    Abstract: A method for manufacturing a cover for a can-like container providing improved peelability of a handle. The cover is made by forming a second resin layer by injection molding or compression forming on a multi-layer sheet which oxygen, water, and the like cannot permeate. A thermally weldable first resin layer is provided on the upper surface of the multi-layer sheet. The handle is formed by the second resin layer. A treatment is carried out for allowing the handle to be easily peeled off the multi-layer sheet to all or part of a region of the multi-layer sheet in contact with the underside of the handle.
    Type: Grant
    Filed: May 25, 1984
    Date of Patent: May 7, 1991
    Assignee: Showa Denko K.K.
    Inventors: Takashi Suzuki, Tetsuo Yasuda, Otohiko Miyauchi, Junji Yotsuyanagi
  • Patent number: 5013504
    Abstract: A process for the dry spinning of synthetic polymers, in particular polyacylonitrile fibres, from solutions in high polar solvents, such as dimethylformamide, which are heated to 100.degree.-150.degree. C. shortly upstream of the spinneret and spun there by spinnerets having a certain shape, and in the spinning cell the specific energy supply is at least 0.090 kWh per m.sup.2 of heated cell area, the cell is charged with at least 70 m.sup.3 (S.T.P.) of hot air per hour, and the filaments are treated in the lower part of the cell with water or aqueous preparations, so that the temperature of the filaments which leave the cell is decreased below 110.degree. C. Under these conditions, the unexpectedly high spinning cell outputs of at least 20 kg of PAN solid per spinning cell per hour can be achieved without yellowing or self-ignition of the filaments occurring.
    Type: Grant
    Filed: September 22, 1989
    Date of Patent: May 7, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Ulrich Reinehr, Gunter Turck, Rolf B. Hirsch, Hermann-Josef Jungverdorben
  • Patent number: 5013502
    Abstract: A process for the production of crimped filaments and fibers of acrylonitrile polymers of copolymers containing at least 40% by weight acrylonitrile units, by dry spinning from highly polar solvents, where the filaments are brought to extremely low solvent contents in the actual spinning tube by a minimum of superheated steam prepared in the absence of water at very high spinning tube temperatures and spinning gas temperatures, but are cooled to low filament temperatures in the spinning tube by application of water or aqueous finishes in a quantity equivalent to more than 10% by weight moisture. In this way, spun PAN filaments of good natural color are safely obtained, in which there is no washing stage and no drying stage. Acrylic fibers and filaments combining a vacuolestable structure with a very high degree of whiteness and gloss are thus obtained with densities of at least 1.180 g/cm.sup.3, giving shrinkage-free to high-shrinkage fibers, depending on the aftertreatment applied.
    Type: Grant
    Filed: September 19, 1989
    Date of Patent: May 7, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Ulrich Reinehr, Rolf-Burkhard Hirsch, Hermann Josef Jungverdorben, Joachim Dross
  • Patent number: 5011645
    Abstract: Nylon staple fiber (and precursor continuous filaments in the form of a tow) of high load-bearing capacity is prepared by an improved process of first drawing the tow between multiple feed and draw rolls, followed by both heating and cooling the draw filaments to anneal them under a controlled tension.
    Type: Grant
    Filed: May 4, 1989
    Date of Patent: April 30, 1991
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Alfred H. Thompson, Jr.
  • Patent number: 5011643
    Abstract: A process for making oriented, shaped articles of para-aramid/thermally-consolidatable polymer blends by orienting spinnable dopes containing 10 to 25% by weight fiber-forming polymers being at least about 55% and less than about 80% para-aramid and at least about 20% and less than about 45% thermally consolidatable polymer in a common solvent and removing the solvent.
    Type: Grant
    Filed: April 13, 1989
    Date of Patent: April 30, 1991
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Hung H. Yang
  • Patent number: 5011644
    Abstract: A process for producing a gel fiber comprises a step (N) of spinning a solution containing at least one polymer having at least one monomer unit as a constituent component for a gel to solidify the solution into a fiber, and step (M) of effecting crosslinking of the fiber to form a gel which can be swelled or shrunk reversibly by a thermal action in the presence of a liquid.
    Type: Grant
    Filed: April 24, 1989
    Date of Patent: April 30, 1991
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masahiro Haruta, Hirohide Munakata, Satoshi Yuasa, Yoko Yoshinaga
  • Patent number: 5009829
    Abstract: A single-step process by which HMLS industrial yarns may be manufactured, in which (a) the solid PETP has a relative viscosity (determined as described below) in the range of 1.8 to 2.1; (b) before spinning, the PETP is mixed with 0.1-0.8% by weight of a bis-(kenenimine); (c) the molten PETP is drawn off from the spinneret orifices at a speed in the range of 1500 to 4000 m/min; and (d) the spun product formed is drawn without intermediate winding at a draw ratio of 1.5 to 4.0, the draw ratio being selected such that the final speed of the yarn is not higher than 6000 m/min.
    Type: Grant
    Filed: June 29, 1989
    Date of Patent: April 23, 1991
    Assignee: Akzo N.V.
    Inventor: Antonius Roos
  • Patent number: 5009830
    Abstract: A process for simultaneously drying and heat treating wet spun fibers of greater than 20 percent water based on weight of dry fiber material supplied continuously in multiple wraps around a pair of rolls in a heated zone, at a tension of 0.2 to 6 grams per denier at the beginning of the zone, with gas jets extending around each of the rolls for about 45 to 180 to direct turbulent gas at a temperature of 200 to 660 C against the fibers under tension in the zone until the residual moisture in the fibers is from 0.5 to 10 percent water based on weight of dry fiber material.
    Type: Grant
    Filed: March 20, 1989
    Date of Patent: April 23, 1991
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Terry S. Chern