Abstract: The invention is ink pigment grinding resins for water-based printing inks which are produced by the esterification of fortified rosin with styrene-allyl alcohol copolymer and various polyols. The resulting rosin resin may be employed over a wide range of pH values to produce stable low viscosity grind bases.
Abstract: The saponified product of an ethylene-vinyl acetate copolymer is mixed with an oxidation catalyst to provide a resin composition having improved oxygen barrier quality. For better formability, the composition may be mixed or laminated with another thermoplastic resin such as a polyester.
Abstract: A melt-molded article such as water soluble fibers, a laminate and a container for waste matter, the article having biodegradability. The melt molded article is produced by melt-molding a composition comprising an oxyalkylene group-containing vinyl alcohol copolymer and starch or a starch-derived macromolecular substance.
Abstract: A composition including an oil and particles of a solid, water soluble flocculant polymer substantially immiscible with the oil provides ready dispersibility of the polymer in aqueous fluids. Desirably, the composition is substantially free of surfactants, the polymer particles have a mean particle size less than about 100 microns and preferably less than about 20 microns and the polymer particles are substantially dry.
Abstract: A polyvinyl chloride-free plastisol comprisesa) 5 to 50% by weight of a methyl methacrylate-homopolymer or coplymerb) 10 to 50% by weight of a plasticiser,c) 20 to 70% by weight of a fillerd) 2 to 30% by weight of a blocked poly isocyanate, ande) 0.2 to 5% by weight of a polyamine. The plastisol is particularly useful for sealing spot welded joints in, for example, motor vehicle manufacture.
Type:
Grant
Filed:
December 22, 1988
Date of Patent:
October 13, 1992
Assignee:
Dr. Alois Stankiewicz GmbH
Inventors:
Karl-Heinz Krummel, Ernst Lohmar, Thomas Stankiewicz
Abstract: The instant invention involves a process for forming a low formaldehyde, essentially color-free coating composition by applying the composition preferably to a wood substrate and curing. The composition comprises a blend of a polyhydroxy-containing polymer, an hexaalkoxymethylolmelamine, a polyacetal having the formula: ##STR1## wherein R is C.sub.1 -C.sub.3 and A is C.sub.1 -C.sub.20 allyl or aryl and an acid catalyst. The coating compositions of the instant invention exhibit extremely low color and give off a significantly reduced amount of formaldehyde when cured in comparison to conventional prior art, acid catalyzed melamine/formaldehyde cured coatings.
Type:
Grant
Filed:
January 14, 1992
Date of Patent:
October 13, 1992
Assignee:
Akzo Coatings, Inc.
Inventors:
Paul R. Baukema, Milton J. Kaelin, Donald W. Waltrip, Kenneth M. Znidersic
Abstract: A cationic polyvinyl alcohol binder additive is prepared suitable for addition in the wet-end of a paper making process by reacting a blocked glyoxal resin, a cationic water-soluble aldehyde reactive polymer and a polyvinyl alcohol polymer.
Abstract: This invention is directed to a method for reducing the carboxylester content of an emulsion-polymerized addition polymer by contacting the aqueous emulsion polymer with a carboxylesterase enzyme and a reduced carboxylester content emulsion-polymerized addition polymer so prepared.
Abstract: New ketocarboxylated polymers which comprise an ester of a ketodiacid precursor, and part of all of the hydroxy or thiol groups of a polymer having one or more pendant hydroxy or thiol groups, are useful as adhesives, coatings, membranes and the like.
Abstract: Water wet nitrocellulose, butyl acrylate/methyl methacrylate monomers and phosphate surfactant are emulsified into an oil-in-water emulsion and polymerized to produce a nitrocellulose/acrylic latex emulsion with a particle size below 0.25 microns. Wood finishing lacquers produced from this latex emulsion are equivalent in performance to solvent lacquers while lowering VOC to below 2.3 lb/gal.
Abstract: Aqueous polymer composition for application to synthetic polymeric materials to improve wettability of same by polymer matrices and bond strength therebetween, which includes a polymer containing vinyl groups, in at least one and preferably two fluorocarbon surfactants and water. The composition also optionally, and preferably includes a copolymerizable surfactant and ethoxy silicone. Synthetic polymeric materials treated with the aqueous polymer composition are disclosed primarily as reinforcing materials in structural composites, either alone or in conjuction with other reinforcing materials. Composites utilizing the pretreated reinforcing materials are also included.
Abstract: An improved blister resistant paper coating polymer latex for paper coating comprising an aliphatic conjugated diene monomer, monoethylenic monomers and an ethylenically unsaturated carboxylic acid monomer and including a molecular weight modifier such as an organosulfur compound and a base.
Abstract: A method of preparing a polyvinyl alcohol hydrogel contains the steps of charging an aqueous solution of a polyvinyl alcohol having a degree of hydrolysis of not less than 95 mol % and an average polymerization degree of not less than 500 into a container, the aqueous solution containing the polyvinyl alcohol in a concentration of not less than 5 wt. %, cooling the aqueous solution of the polyvinyl alcohol at a temperature of from - (minus) 9.degree. C. to - (minus) 3.degree. C., subjecting the aqueous solution of the polyvinyl alcohol to physical stimulation, and then maintaining the aqueous solution of the polyvinyl alcohol at a temperature of from - (minus) 5.degree. C. to + (plus) 5.degree. C. The polyvinyl alcohol hydrogel may be contained in a plastic container. An MRI phanton is composed of the plastic container containing such polyvinyl alcohol hydrogel.
Abstract: Aqueous polymer composition for application to synthetic polymeric materials to improve wettability of same by polymer matrices and bond strength therebetween, which includes a polymer containing vinyl groups, in at least one and preferably two fluorocarbon surfactants and water. The composition also optionally, and preferably includes a copolymerizable surfactant and ethoxy silicone. Synthetic polymeric materials treated with the aqueous polymer composition are disclosed primarily as reinforcing materials in structural composites either alone or in conjunction with other reinforcing materials. Composites utilizing the pretreated reinforcing materials are also included.
Abstract: A method for extruding polyvinyl alcohol which comprisesadding sufficient energy to the polyvinyl alcohol to both melt it and essentially eliminate the crystallinity in the melt, andsimultaneously removing energy from the melt at a rate sufficient to avoid decomposition of the polyvinyl alcohol.Rapidly cooling the extruded melt reduces the heat history and improves the resulting color of the extrudable polyvinyl alcohol.
Type:
Grant
Filed:
September 1, 1989
Date of Patent:
August 11, 1992
Assignee:
Air Products and Chemicals, Inc.
Inventors:
F. Lennart Marten, Amir Famili, James F. Nangeroni
Abstract: Sheet for safety glazings made of: a) polyvinyl butyral internally plasticized by the presence in the polymer of C.sub.7 to C.sub.15 aliphatic aldehyde groups and b) an external plasticizer in amount sufficient to provide a sheet glass transition temperature of about 25.degree. to 30.degree. C.
Type:
Grant
Filed:
September 30, 1991
Date of Patent:
August 11, 1992
Assignee:
Monsanto Company
Inventors:
Arijit M. DasGupta, Donald J. David, Roland J. Tetreault
Abstract: Non-formaldehyde emitting binders for nonwoven cellulosic materials comprise a solution copolymer of an olefinically unsaturated organic compound having at least one carboxylate group conjugated with the olefinic linkage, which is reacted with a hydroxyalkyl ester of an olefinically unsaturated carboxylic acid. The product of said reaction is admixed with a non-formaldehyde containing latex carrier to produce a binder composition which will reach substantially fully cured wet strength in 8 seconds or less.
Abstract: A water soluble packaging film containing a predominant amount of partially acetalized product of polyvinyl alcohol by benzaldehyde derivatives.
Abstract: Permanently flexible and non-tacky coating mastic and caulking compositions having improved heat-age stability contain (a) at least one polymer having a T.sub.g of about -50.degree. C. to about -10.degree. C. and pendant functional groups attached to the polymer backbone and having the formula: ##STR1## in which R.sub.1 is a divalent organic radical at least 3 atoms in length, and X is organoacyl or cyano; (b) a zinc-containing pigment (e.g. zinc oxide); and (c) a polyphosphate anion in an amount effective for increasing the wet adhesion of the compositions, particularly of aged compositions. The mastics and caulks typically have total non-volatile matter concentrations of about 60 to about 90 weight percent of which about 15 to about 75 weight percent comprises the described polymer and about 25 to about 85 weight percent is the zinc-containing pigment and other non-volatile solid matter other than the polymer such as fillers, other pigments, etc.
Abstract: A cationic aqueous pigment dispersion comprising a pigment, a dispersing agent and an aqueous medium, in which the dispersing agent is a water-solubilized or water-dispersed product of a copolymer obtained by copolymerization of(A) 3 to 90 parts by weight of a modified vinylic unsaturated monomer having a fatty acid residue with at least 8 carbon atoms at the molecular terminal,(B) 2 to 90 parts by weight of a nitrogen-containing macromonomer having at least one radical-polymerizable functional group selected from acryloyloxy, methacryloyloxy, allyloxy and an aromatic vinyl group at one end,(C) 1 to 50 parts by weight of at least one vinylic monomer selected from aminoalkyl (meth)acrylates, aminoalkyl-(meth)acrylamides and glycidyl group-containing vinylic unsaturated monomers,(D) 0 to 91 parts by weight of an unsaturated monomer having a nitrogen-containing heterocyclic ring, and(E) 0 to 91 parts by weight of an alpha,beta-ethylenically unsaturated monomer other than (A), (B), (C) and (D) above.